GB519437A - Process for the manufacture of dyestuff intermediates and of azo dyestuffs insoluble in water therefrom - Google Patents
Process for the manufacture of dyestuff intermediates and of azo dyestuffs insoluble in water therefromInfo
- Publication number
- GB519437A GB519437A GB2766938A GB2766938A GB519437A GB 519437 A GB519437 A GB 519437A GB 2766938 A GB2766938 A GB 2766938A GB 2766938 A GB2766938 A GB 2766938A GB 519437 A GB519437 A GB 519437A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- reacted
- reacting
- hydroxynaphthoic acid
- hydroxynaphthoic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/10—Monoazo dyes prepared by diazotising and coupling from coupling components containing hydroxy as the only directing group
- C09B29/18—Monoazo dyes prepared by diazotising and coupling from coupling components containing hydroxy as the only directing group ortho-Hydroxy carbonamides
- C09B29/20—Monoazo dyes prepared by diazotising and coupling from coupling components containing hydroxy as the only directing group ortho-Hydroxy carbonamides of the naphthalene series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
519,437. Dyestuff intermediates ; dyeing. KERSHAW, A., SAUNDERS, K. H., and IMPERIAL CHEMICAL INDUSTRIES, Ltd. Sept. 22, 1938, No. 27669. [Classes 2 (iii) and 15 (ii)] New arylamides for producing insoluble azo dyes on the fibre are made by interacting aminoarylpyridines with o-hydroxyaryl carboxylic acids, e.g., 2:3-hydroxynaphthoic acid, 6 - bromo - and 6 - methoxy - 2:3 - hydroxynaphthoic acids, 2:3-hydroxycarbazole carboxylic acid, 2:3-hydroxydiphenylene oxide carboxylic acid and 2:3-hydroxyanthracene carboxylic acid. In examples, (1) the mixture of isomeric 4-aminophehylpyridiries made by reacting pyridine with diazotised p-nitraniline and reducing (Specification 518,886) is reacted with 2:3-hydroxynaphthoic acid or 2-hydroxycarbazole-3-carboxylic acid in presence of phosphorus trichloride, (2) the mixture of isomeric 4 - amino - 3 - methylphenylpyridines made by diazotizing 1-amino-4-acetamino-3- methylbenzene, reacting with pyridine, and de-acetylating the product is reacted with 2:3-hydroxynaphthoic acid ; (3) the mixture of isomeric 4-aminophenyl-alpha-picolines made by reacting diazotized p-nitraniline with alpha-picoline and reducing is reacted with 2:3-hydroxynaphthoic acid, (4) the mixture of isomeric 2 - nitro - 4 - aminophenylpyridines made by nitrating the mixture of 4-aminopyridines made by the process of Specification 518,886, is reacted with 2:3-hydroxynaphthoic acid (5) the mixture of 2-methoxyaminophenylpyridines made by reacting pyridine with diazotized o-anisidine, nitrating, and reducing is reacted with 2:3-hydroxynaphthoic acid, and (6) 2:5-dichloraminophenylpyridine, made by reacting diazotized 2:5-dichloraniline with pyridine, nitrating, and reducing is reacted with 2:3-hydroxynaphthoic acid. In a further example, cotton is impregnated with the arylamide ' mixture obtained according to example (1) and immersed in a bath containing diazotized 5-nitro-2-aminoanisole ; bluish-red dyeings are obtained. The shades produced by developing with diazo compounds of ochloraniline, m-chloraniline, 4-chlor-2-aminoanisole, 5-chlor-2-aminotoluene, 2:5-dichloraniline, 4-benzoylamino-2:5-diethoxyaniline and 4-nitro-2-aminoanisole are tabulated.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2766938A GB519437A (en) | 1938-09-22 | 1938-09-22 | Process for the manufacture of dyestuff intermediates and of azo dyestuffs insoluble in water therefrom |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2766938A GB519437A (en) | 1938-09-22 | 1938-09-22 | Process for the manufacture of dyestuff intermediates and of azo dyestuffs insoluble in water therefrom |
Publications (1)
Publication Number | Publication Date |
---|---|
GB519437A true GB519437A (en) | 1940-03-27 |
Family
ID=10263348
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2766938A Expired GB519437A (en) | 1938-09-22 | 1938-09-22 | Process for the manufacture of dyestuff intermediates and of azo dyestuffs insoluble in water therefrom |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB519437A (en) |
-
1938
- 1938-09-22 GB GB2766938A patent/GB519437A/en not_active Expired
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