GB489157A - Improvements in and relating to the preservation of rubber - Google Patents
Improvements in and relating to the preservation of rubberInfo
- Publication number
- GB489157A GB489157A GB5444/38A GB544438A GB489157A GB 489157 A GB489157 A GB 489157A GB 5444/38 A GB5444/38 A GB 5444/38A GB 544438 A GB544438 A GB 544438A GB 489157 A GB489157 A GB 489157A
- Authority
- GB
- United Kingdom
- Prior art keywords
- naphthylamine
- phenyl
- phenoxy
- rubber
- oxidants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The deterioration of rubber is retarded by the addition of an aryloxy substitued diarylamine of the general formula R-O-R1-NH-R2, in which R, R1 and R2 represent aromatic radicals. In preferred forms of the invention R and R2 are phenyl, tolyl, xylyl, diphenyl, naphthyl and anthracyl radicals, and R1 is a phenylene, toluylene xylylene, naphthylene and diphenylene radical. Compounds mentioned as being particularly suitable for use according to the present invention are 4-phenoxy-phenyl-b -naphthylamine, 4-phenoxy-diphenylamine, 4-p-cresoxy-phenyl-b -naphthylamine, 2 - phenoxy - phenyl - b - naphthylamine, 4 - b - naphthoxy - phenyl - b -naphthylamine, 4 - phenoxy - 41 -methoxydiphenylamine, and 4 : 41-diphenoxy-diphenylamine. In examples: (1) 4-amino-diphenyl ether and b -naphthol are reacted in the presence of iodine for five hours at 225-260 DEG C. to yield 4-phenoxy-phenyl-b -naphthylamine; (2) 4 - amino - diphenyl - ether and aniline hydrochloride are reacted as in example (1) to give 4-phenoxy-diphenyl-amine; (3) 4-amino-41-methyl diphenyl ether is reacted as in example (1) with beta-naphthol to give 4-para-cresoxy-phenyl-beta-naphthylamine; (4) 2-amino-diphenyl ether is reacted as in example (1) with beta naphthol to give 2-phenoxyphenyl-beta-naphthylamine; (5) 4-amino-phenyl alpha-naphthyl ether is reacted as in example (1) with beta naphthol to give 4-alpha-naphthoxy-phenyl-beta naphthylamine. The anti-oxidants of the present invention may be used either alone or in combination with other anti-oxidants. The term "rubber" includes caoutchouc, both natural and synthetic, reclaimed rubber, balata, guttapercha and rubber isomers. Tables are given to show the efficiency of the anti-oxidants of the present invention when used in a standard rubber mix.ALSO:The deterioration of rubber is retarded by the addition of an aryloxy substituted diarylamine of the general formula R-O-R1-NH-R2 in which R, R1 and R2 represent aromatic radicals. In preferred forms of the invention R and R2 are phenyl, tolyl, xylyl, diphenyl, naphthyl and anthracyl radicals, and R1 is a phenylene, toluylene, xylylene, naphthylene and diphenylene radical. Compounds mentioned as being particularly suitable for use according to the present invention are 4-phenoxy-phenyl-b -naphthylamine 4-phenoxy-diphenylamine, 4-p-cresoxyphenyl-b -naphthylamine, 2-phenoxyphenyl-b -naphthylamine, 4-a -naphthoxyphenyl - b - naphthylamine, 4 - phenoxy - 41 - methoxy - diphenylamine and 4 - 41 - diphenoxy - diphenylamine. Examples are given to show methods of preparation of the invention. The anti-oxidants may be used either alone or in combination with other anti-oxidants. The term rubber includes caoutchouc, both natural and synthetic, reclaimed rubber, balata, guttapercha, and rubber isomers. Tables are given to show the efficiency of the anti-oxidants of the present invention when used in a standard rubber mix.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US489157XA | 1937-02-25 | 1937-02-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB489157A true GB489157A (en) | 1938-07-20 |
Family
ID=21957127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5444/38A Expired GB489157A (en) | 1937-02-25 | 1938-02-21 | Improvements in and relating to the preservation of rubber |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB489157A (en) |
-
1938
- 1938-02-21 GB GB5444/38A patent/GB489157A/en not_active Expired
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