GB489026A - Processes for the condensation of organic metal derivatives with acylated compounds - Google Patents

Processes for the condensation of organic metal derivatives with acylated compounds

Info

Publication number
GB489026A
GB489026A GB27946/36A GB2794636A GB489026A GB 489026 A GB489026 A GB 489026A GB 27946/36 A GB27946/36 A GB 27946/36A GB 2794636 A GB2794636 A GB 2794636A GB 489026 A GB489026 A GB 489026A
Authority
GB
United Kingdom
Prior art keywords
sodium
acetylated
castor oil
fatty acid
oil fatty
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27946/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHEMISCHE FABRIEK SERVO NV
MEINDERT DANIUS ROZENBROEK
Original Assignee
CHEMISCHE FABRIEK SERVO NV
MEINDERT DANIUS ROZENBROEK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHEMISCHE FABRIEK SERVO NV, MEINDERT DANIUS ROZENBROEK filed Critical CHEMISCHE FABRIEK SERVO NV
Priority to GB27946/36A priority Critical patent/GB489026A/en
Publication of GB489026A publication Critical patent/GB489026A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/185—Saturated compounds having only one carboxyl group and containing keto groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/235—Saturated compounds containing more than one carboxyl group
    • C07C59/305—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Abstract

Esters of aliphatic carboxylic acids having four or less carbon atoms in the molecule are heated with alcoholates, phenolates or organic metal compounds in which a hydrogen atom attached to carbon is substituted by the metal whereby condensation occurs, the metal salt of the lower aliphatic carboxylic acid being split off. According to a modification, hydroxy fatty acids acylated at the hydroxy group with aliphatic, aromatic, alicyclic or heterocyclic carboxylic acids are condensed with alcoholates or organic metal compounds in which a hydrogen atom attached to carbon is substituted by the metal. The metal compounds may contain reactive groups such as carboxyl, carbonyl or sulphonic groups or other groups containing sulphur or nitrogen. In examples: (1) sodium butylate is heated with acetylated octanol-2, acetylated ricinoleic acid and terpenylacetate; (2) sodium amylate is heated with acetylated cetyl alcohol; (3) sodium is dissolved in butyl alcohol and reacted with terpineol and the resulting sodium compound heated with terpenylacetate; (4) the sodium compound of glycerine is heated with acetylated wool fat alcohol and with acetylated hydroquinone; (5) acetylated castor oil fatty acid is heated with the sodium compound of malonic ester, sodium phenolate and with the sodium compound of glycerol; (6) the ether-fatty acid obtained from acetylated castor oil fatty acid and sodium butylate is saponified, condensed with glycolchlorhydrin or glycerol chlorhydrin and sulphonated to give a wetting agent. The sodium soaps of the ether-fatty acids may themselves be sulphonated and the carboxylic group esterified. The ether-fatty acids may also be condensed with hydroxyethane sulphonic acid or taurine to give textile assistants. The condensation of sodium malonic ester with acetylated cellulose, starch and glucose is mentioned. Samples have been furnished under Sect. 2 (5) of products obtained by condensing the following components; (a) diethyloxalate and sodium butylate; (b) acetylated castor oil fatty acid and sodium malonic acid ester; (c) terpenyl acetate and sodium oleylate; (d) the sodium compound of fenchyl alcohol and oleylacetate; (e) cetyl acetate and sodium malonic acid ester; (f) bornyl acetate and sodium malonic acid ester; (g) butyl acetate and sodium acetyl acetic acid; (h) phenylacetate and sodium benzylate; (i) benzoylated castor oil fatty acid and sodium ethylate; (j) sodium butylate and the lactic acid ester of castor oil fatty acid; (k) sodium butylate and acetylated secondary octyl alcohol; (l) sodium compound of glycerol and acetylated castor oil fatty acid; (m) sodium butylate and acetylated castor oil fatty acid; (n) sodium phenolate and acetylated castor oil fatty acid.
GB27946/36A 1936-10-14 1936-10-14 Processes for the condensation of organic metal derivatives with acylated compounds Expired GB489026A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB27946/36A GB489026A (en) 1936-10-14 1936-10-14 Processes for the condensation of organic metal derivatives with acylated compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB27946/36A GB489026A (en) 1936-10-14 1936-10-14 Processes for the condensation of organic metal derivatives with acylated compounds

Publications (1)

Publication Number Publication Date
GB489026A true GB489026A (en) 1938-07-14

Family

ID=10267815

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27946/36A Expired GB489026A (en) 1936-10-14 1936-10-14 Processes for the condensation of organic metal derivatives with acylated compounds

Country Status (1)

Country Link
GB (1) GB489026A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0541152A2 (en) * 1991-11-04 1993-05-12 Quest International B.V. Ethers for aromatizing purposes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0541152A2 (en) * 1991-11-04 1993-05-12 Quest International B.V. Ethers for aromatizing purposes
EP0541152A3 (en) * 1991-11-04 1993-06-30 Quest International B.V. Ethers for aromatizing purposes
US5313002A (en) * 1991-11-04 1994-05-17 Unilever Patent Holdings B.V. Ethers for aromatizing purposes
US5432154A (en) * 1991-11-04 1995-07-11 Unilever Patent Holdings B.V. Ethers for aromatizing purposes

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