GB468208A - Electrical testing apparatus - Google Patents

Electrical testing apparatus

Info

Publication number
GB468208A
GB468208A GB29983/35A GB2998335A GB468208A GB 468208 A GB468208 A GB 468208A GB 29983/35 A GB29983/35 A GB 29983/35A GB 2998335 A GB2998335 A GB 2998335A GB 468208 A GB468208 A GB 468208A
Authority
GB
United Kingdom
Prior art keywords
resistance
grid
switch
battery
potentiometer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB29983/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAT TECHNICAL LAB
Original Assignee
NAT TECHNICAL LAB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAT TECHNICAL LAB filed Critical NAT TECHNICAL LAB
Publication of GB468208A publication Critical patent/GB468208A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416Systems
    • G01N27/4166Systems measuring a particular property of an electrolyte

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Measurement Of Resistance Or Impedance (AREA)

Abstract

468,208. Current and pressure meters; potentiometers. NATIONAL TECHNICAL LABORATORIES. Oct. 30, 1935, No. 29983. Convention date, Sept. 21. [Class 37] A testing - apparatus providing a range of positive and negative. potentials comprises a resistance 89b, Fig. 2, with a relatively movable sliding contact 87b, means such as a battery 91b for impressing a predetermined potential across the ends of the resistance, a pair of terminals for connection with an E.M.F. to be measured, one of the terminals being connected to the sliding contact 87b, and means for impressing a fixed reference potential on the other terminal, the said means including resistance elements 92b, 93b, shunting the resistance 89b, the other terminal being connected to a tapping between the resistances 92b and 93b. The invention is particularly applicable to the measurement of potentials in very high resistance circuits, such as those used in determining the pH values of solutions, and an arrangement for this purpose is shown in Fig. 1. A test cell 1 comprising a glass electrode 3 and a calomel electrode 5 immersed in the solution to be tested is connected by a conductor 9 to the front contact 11 of a transfer switch 13, the movable contact 15 of which is connected to the control grid 21 of a screen grid tube 23, with an anode 29 connected through a bias battery 37 to the grid 39 of a triode 41. The anode 45 of the latter is connected through a milliammeter 47 to the positive side of a battery 35, the anode 29 of the valve 23 being connected to the same side of the battery through a high resistance 33. The cathodes of the two tubes are connected in series with each other and a battery 49 through a control switch 51, the cathode 25 of the tube 23 being shunted by a resistance 53. The circuit from the grid 21 is completed back to the cathode 25 either through the front contact 11 of switch 15, the cell 3 and potentiometer 55 or through the back contact 17 of switch 13 and through a switch 67 to a grid return lead 72 which connects to a sliding tap 73 on a resistance 75 connected in series with a resistance 77 and a variable resistance 79, all three resistances being in shunt to the cathode 43 of tube 41. Another resistance 8 is shunted between the top 73 and the junction point of resistances 75 and 79. The arrangement enables a variable bias to be placed on the grid return lead to compensate for variations in the strengths of the batteries, the general circuit arrangements being similar to those described in Specification 468,138. The potentiometer 55 is adjusted until the milliammeter 47 gives the same reading in either position of the switch 13 ; the potentiometer then indicates the value of the potential of the cell 1. The battery 91 of the potentiometer is preferably a dry cell, and since the E.M.F. of this is greater than the total range of potentials required to be measured in determining the pH values, the battery 91 is connected to the resistance 89 through resistances 95, 97, the latter being variable. The potentiometer is standardized against a standard Weston cell 99 by means of the switch 67. The E.M.F. developed by a glass electrode-calomel electrode cell varies in general with the temperature of the solution, but is constant at the particular value pH = +0À1. The temperature effects may be compensated by connecting tapped resistances in series with the resistances 93 and 95, and adjusting the tappings simultaneously in accordance with the temperature. In the arrangement shown in Fig. 1, a tapped resistance 103 is connected in series with the resistance 95, and one end of the resistance 92 is connected to a tap 110 on a resistance 90 shunting the resistance 89, the tap 110 corresponding to the pH value of +0À1. A switch 106 is set to the tapping on the resistance 103 corresponding to the temperature of the solution. A mathematical analysis of the potentiometer is given in the Specification. In order to reduce the possibility of current leakage from the elements 3, 9, 11 and 15 the grid return lead 72 is grounded to the frame of the instrument instead of grounding the cathodes. Swinging of the needle of the milliammeter is reduced by connecting a condenser 131 across the grid circuit of the valve 43. Various methods for adjusting the sensitivity of the amplifier are described; in the arrangement shown a variable resistance 137 is connected in series with the screen grid 27 of the input tube 23. Errors resulting from grid current in the input tube are compensated by connecting a resistance 57, of approximately the same value as the resistance of the glass electrode 3, in series with the back contact 17 of the switch 13.
GB29983/35A 1935-09-21 1935-10-30 Electrical testing apparatus Expired GB468208A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US468208XA 1935-09-21 1935-09-21

Publications (1)

Publication Number Publication Date
GB468208A true GB468208A (en) 1937-06-30

Family

ID=21945569

Family Applications (1)

Application Number Title Priority Date Filing Date
GB29983/35A Expired GB468208A (en) 1935-09-21 1935-10-30 Electrical testing apparatus

Country Status (1)

Country Link
GB (1) GB468208A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE894455C (en) * 1938-08-26 1953-10-26 Hartmann & Braun Ag Device for displaying and recording a measured value which is dependent on two or more measured variables
CN113671012A (en) * 2021-09-27 2021-11-19 福州大学 Electrochemical analysis sensitivity self-adjusting method suitable for on-site rapid detection

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE894455C (en) * 1938-08-26 1953-10-26 Hartmann & Braun Ag Device for displaying and recording a measured value which is dependent on two or more measured variables
CN113671012A (en) * 2021-09-27 2021-11-19 福州大学 Electrochemical analysis sensitivity self-adjusting method suitable for on-site rapid detection

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