GB466968A - Manufacture of vat-dyestuffs and intermediates - Google Patents
Manufacture of vat-dyestuffs and intermediatesInfo
- Publication number
- GB466968A GB466968A GB437536A GB437536A GB466968A GB 466968 A GB466968 A GB 466968A GB 437536 A GB437536 A GB 437536A GB 437536 A GB437536 A GB 437536A GB 466968 A GB466968 A GB 466968A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloride
- products
- diphthaloylpyrene
- leuco
- pyrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Indole Compounds (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Vat dyes or intermediate products are made by reacting pyrene with at least 2\ba1/2\be mols. of an o-dicarboxylic acid anhydride, such as phthalic anhydride, in presence of a condensing agent and in a single stage. The products may be halogenated. Condensing agents specified are aluminium halides such as aluminium chloride or ferric chloride, and substances may be added which lower the melting point such as an alkali halide (sodium or potassium chloride or both). A preferred temperature is 120--150 DEG C. The products may be purified by recrystallization from solvents such as trichlorbenzene, by conversion to their salts with strong acids, or by treatment with oxidizing agents such as alkali hypochlorite. They may be converted to leuco-derivatives such as leuco - sulphuric acid esters, by known methods, and dye vegetable fibres yellow shades. In examples, pyrene is condensed with phthalic anhydride to give a diphthaloylpyrene, which is chlorinated with sulphuryl chloride or brominated. A final example describes the dyeing of cotton with the diphthaloylpyrene. Specification 366,472 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB437536A GB466968A (en) | 1936-02-13 | 1936-02-13 | Manufacture of vat-dyestuffs and intermediates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB437536A GB466968A (en) | 1936-02-13 | 1936-02-13 | Manufacture of vat-dyestuffs and intermediates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB466968A true GB466968A (en) | 1937-06-09 |
Family
ID=9775979
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB437536A Expired GB466968A (en) | 1936-02-13 | 1936-02-13 | Manufacture of vat-dyestuffs and intermediates |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB466968A (en) |
-
1936
- 1936-02-13 GB GB437536A patent/GB466968A/en not_active Expired
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