GB466345A - Improvements in the manufacture and production of nitrogenous products - Google Patents
Improvements in the manufacture and production of nitrogenous productsInfo
- Publication number
- GB466345A GB466345A GB825037A GB825037A GB466345A GB 466345 A GB466345 A GB 466345A GB 825037 A GB825037 A GB 825037A GB 825037 A GB825037 A GB 825037A GB 466345 A GB466345 A GB 466345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- products
- condensation
- acid
- sulphonic
- methylethyleneimine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Assistants useful in the textile, leather, lacquer, rubber, pharmaceutical and cosmetic industries are obtained when mono or polymeric 1 : 2-alkyleneimines are condensed with halogenated aromatic compounds or aromatic sulphonic acid halides. The treatment of monomeric ethyleneimine or N-methylethyleneimine with benzenesulphonic or toluene acid chloride in the presence of sodium hydroxide is, however disclaimed. The reaction may be combined with a condensation with aldehydes or ketones, (cf. Specification 466,346), or with other substances capable of condensation, e.g. urea, dimethylolurea, thiourea, phenols, cetylamine, octodecylamine, styrene, synthetic rubber or synthetic resins. The condensation may be effected in the presence of solvents or diluents such as water, alcohol, ether, cyclohexanone, toluene, carbontetrachloride or chlorbenzene. Acyl, sulphonic, sulphuric ester, carboxylic or phosphoric acid groups may be introduced into the products or into the reacting components. The products may be added in dyeing, printing, washing, dressing, stripping, fulling, levelling, tanning, dispersing and wetting processes. They may also be used in softening and flotation agents, and to increase the affinity of viscose and copper artificial silk for acid dyestuffs. They may be added to spinning solutions and the products obtained with the co-employment of aldehydes or ketones may be used for dressing textiles, leather, paper or straw and for rendering artificial silk crease- and slide-proof. Dispersing agents such as sulphuric esters of fatty alcohols and aliphatic sulphonic acids may be used with the products, which can also be employed in the form of salts with mineral or organic, e.g. fatty acids. The condensation products may be produced directly on the fibre, such as wool, cotton, cellulose acetate or viscose or copper artificial silk. In examples: (1) butyl ethyleneimine is condensed with 2 : 4-dinitro-1-chlorbenzene; the product as well as the diamino compound obtained by reduction may be used in the production of copper or viscose artificial silk; (2) polymeric ethylene imine is reacted with toluenesulphonic acid chloride or p-nitrobenzyl chloride; the product may be treated with chlorethanesulphonic acid or sulphonating agents. Further specified imines are methylethyleneimine, a : b -butyleneimine, o -chlor-a : b - butyleneimine and dodecyleneimine. Specification 466,344 also is referred to.ALSO:Products which may be added to preparations used as dispersing agents are obtained when mono or polymeric 1 : 2-alkyleneimines are condensed with halogenated aromatic compounds or aromatic sulphonic acid halides. The treatment of monomeric ethyleneimine or N-methylethyleneimine with benzenesulphonic or toluene acid chloride in the presence of sodium hydroxide is, however, disclaimed. The reaction may be combined with a condensation with aldehydes or ketones (cf. Specification 466,346), or with other substances capable of condensation, e.g. urea, dimethylolurea, thiourea, phenols, cetylamine, octodecylamine, styrene, synthetic rubber or synthetic resins. Acyl, sulphonic, sulphuric ester, carboxylic or phosphoric acid groups may be introduced into the products or into the reacting components. Dispersing agents such as sulphuric esters of fatty alcohols and aliphatic sulphonic acids may be used with the products, which can also be employed in the form of salts with mineral or organic, e.g. fatty, acids. In examples: (1) butylethyleneimine is condensed with 2 : 4-dinitro-1-chlorbenzene; (2) polymeric ethylene imine is reacted with toluenesulphonic acid chloride or p-nitrobenzyl chloride; the product may be treated with chlorethanesulphonic acid or sulphonating agents. Further specified imines are methylethyleneimine, a : b -butyleneimine, o -chlor-a : b -butyleneimine and dodecyleneimine. Specification 466,344 also is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB825037A GB466345A (en) | 1935-08-22 | 1935-08-22 | Improvements in the manufacture and production of nitrogenous products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB825037A GB466345A (en) | 1935-08-22 | 1935-08-22 | Improvements in the manufacture and production of nitrogenous products |
Publications (1)
Publication Number | Publication Date |
---|---|
GB466345A true GB466345A (en) | 1937-05-24 |
Family
ID=9848889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB825037A Expired GB466345A (en) | 1935-08-22 | 1935-08-22 | Improvements in the manufacture and production of nitrogenous products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB466345A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3203910A (en) * | 1962-04-13 | 1965-08-31 | Dow Chemical Co | Polymerization of alkylenimines |
US3345253A (en) * | 1963-08-30 | 1967-10-03 | Hoechst Ag | Process of forming cellulosic webs containing urea-alkyleneimine condensation products |
-
1935
- 1935-08-22 GB GB825037A patent/GB466345A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3203910A (en) * | 1962-04-13 | 1965-08-31 | Dow Chemical Co | Polymerization of alkylenimines |
US3345253A (en) * | 1963-08-30 | 1967-10-03 | Hoechst Ag | Process of forming cellulosic webs containing urea-alkyleneimine condensation products |
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