GB440364A - Cellulose derivative compositions - Google Patents
Cellulose derivative compositionsInfo
- Publication number
- GB440364A GB440364A GB19126/34A GB1912634A GB440364A GB 440364 A GB440364 A GB 440364A GB 19126/34 A GB19126/34 A GB 19126/34A GB 1912634 A GB1912634 A GB 1912634A GB 440364 A GB440364 A GB 440364A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- ethyl
- rancidity
- inhibitor
- hydroquinone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0021—Preserving by using additives, e.g. anti-oxidants containing oxygen
- C11B5/0035—Phenols; Their halogenated and aminated derivates, their salts, their esters with carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
Abstract
Cellulose derivative compositions suitable for use in the manufacture of artificial leather and the like comprise a fatty substance having a normal iodine number below 135 and, as a rancidity inhibitor for the fatty substance, a phenol with two aromatic nuclei separated in the ortho or para position by oxygen or carbon, or a monohydric phenol having one aromatic nucleus and not more than two reactive positions, such as a monoalkyl ether of hydroquinone, an o- or p-alkyl phenol, or a dialkyl phenol. The fatty substance may be castor oil, olive, rapeseed, cod-liver, corn, peanut, cocoa-nut, cottonseed, palm, lard, or neatsfoot oil, or butter fat, lard, beef tallow, or wool fat. The fatty substance is of the semi-drying or non-drying type. It may comprise fatty glycerides or other fatty esters such as those of ethyl, butyl, ethoxy-ethyl, or benzyl alcohol, or of ethylene glycol, propylene glycol, diethylene glycol, or pentaerythritol. The cellulose derivative may be cellulose acetate, nitrate, or propionate, or ethyl, benzyl, lauryl, or crotyl cellulose. The rancidity inhibitor may be present to the extent of 0,25--5 per cent of the weight of the oil. Coatings of white or pale blue colour are obtained by the addition of lithopone and ultramarine. The rancidity inhibitor may be diphenylolpropane, diphenylolethane, dihydroxy-o-tolyl dimethyl methane, ortho or para hydroxy diphenyl ether, diphenylol propane formaldehyde condensation product, phenol-dipentene condensation product or a similar product obtained from cresol or guaiacol, mono methyl ether of hydroquinone, ortho or para cyclohexyl phenol, o-cresol, carvacrol, 1 : 2 : 4-xylenol, or an ethyl, propyl, butyl, amyl, lauryl, or cyclohexyl ether of hydroquinone, or an ethyl, propyl, butyl, or heptyl phenol. The inhibitor may contain chlorine in the aromatic nuclei or it may be a naphthol derivative. In an example, a composition for making artificial leather comprises cellulose nitrate, ethyl alcohol, ethyl acetate, a pigment, castor oil, and a small proportion of rancidity inhibitor. A measure of the resistance to rancidity is obtained by placing a piece of fabric coated with the composition in a stoppered flask maintained at constant temperature and exposed to the light from a carbon are. The odour developed is compared with that from a piece of fabric coated with a composition not containing the rancidity inhibitor. The compositions are also resistant to the discolouring effect of light and moisture. The Specification as open to inspection under Sect. 91 comprises the application of the process to the manufacture of films and other materials. This subject-matter does not appear in the Specification as accepted.ALSO:For preventing semi-drying or non-drying fatty substances from going rancid there is mixed therewith a phenol with two aromatic nuclei separated in ortho or para position by oxygen or carbon, or a monohydric phenol having one aromatic nucleus and not more than two reactive positions, such as a mono-alkyl ether of hydroquinone, an o- or p-alkyl phenol, or a dialkyl phenol. The fatty substance is one having an iodine number below 135, e.g. castor, olive, rapeseed, cod-liver, corn, peanut, coconut, cottonseed, palm, lard, or neatsfoot oil, or butter fat, lard, beef tallow, or wool fat. It may be a glyceride or other fatty ester such as one from ethyl, butyl, ethoxy-ethyl, or benzyl alcohol, or ethylene glycol, propylene glycol, diethylene glycol, or pentaerythritol. The rancidity inhibitor may be diphenylol ethane or propane, dihydroxy-o-tolyl dimethyl methane, o- or p-hydroxy diphenyl ether, diphenylol propane formaldehyde, phenol-dipentene or similar condensation product from cresol or guaiacol, hydroquinone mono methyl ether, o- or p-cyclohexyl phenol, o-cresol, carvacrol, 1.2.4. xylenol, or an ethyl, propyl, butyl, amyl, lauryl, or cyclohexyl ether of hydroquinone, or an ethyl, propyl, butyl, or heptyl phenol. It may contain chlorine in the aromatic nuclei or it may be a naphthol derivative. The resistance to rancidity is measured by comparing the odour developed on exposure to carbon-arc light of coatings containing the fatty substance and inhibitor, with the odour developed under similar exposure by coatings containing the fatty substance without the rancidity inhibitor.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US440364XA | 1933-07-15 | 1933-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB440364A true GB440364A (en) | 1935-12-30 |
Family
ID=21930179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19126/34A Expired GB440364A (en) | 1933-07-15 | 1934-07-28 | Cellulose derivative compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB440364A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2617739A (en) * | 1949-11-10 | 1952-11-11 | Celanese Corp | Plasticized and stabilized lower fatty acid ester of cellulose |
US2617738A (en) * | 1949-11-10 | 1952-11-11 | Celanese Corp | Plasticized and stabilized cellulose propionate |
-
1934
- 1934-07-28 GB GB19126/34A patent/GB440364A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2617739A (en) * | 1949-11-10 | 1952-11-11 | Celanese Corp | Plasticized and stabilized lower fatty acid ester of cellulose |
US2617738A (en) * | 1949-11-10 | 1952-11-11 | Celanese Corp | Plasticized and stabilized cellulose propionate |
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