GB438354A - A method for the desulphurisation of crude benzene, petroleum oils, shale oils and of other hydrocarbon oils containing sulphur - Google Patents

A method for the desulphurisation of crude benzene, petroleum oils, shale oils and of other hydrocarbon oils containing sulphur

Info

Publication number
GB438354A
GB438354A GB1108634A GB1108634A GB438354A GB 438354 A GB438354 A GB 438354A GB 1108634 A GB1108634 A GB 1108634A GB 1108634 A GB1108634 A GB 1108634A GB 438354 A GB438354 A GB 438354A
Authority
GB
United Kingdom
Prior art keywords
oils
hydrogen
sulphide
deposited
dibenzyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1108634A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INNA NICOLAEVNA TITZ
NICOLAI DMITRIEVITCH ZELINSKY
Original Assignee
INNA NICOLAEVNA TITZ
NICOLAI DMITRIEVITCH ZELINSKY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INNA NICOLAEVNA TITZ, NICOLAI DMITRIEVITCH ZELINSKY filed Critical INNA NICOLAEVNA TITZ
Priority to GB1108634A priority Critical patent/GB438354A/en
Publication of GB438354A publication Critical patent/GB438354A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Sulphur compounds are removed from petroleum and other oils by passing the oil vapours at normal pressure together with hydrogen or hydrogen-containing gas over a catalyst consisting of nickel deposited on aluminium hydroxide, or other metals of the 8th group of the periodic system, especially platinum or palladium, deposited in a finely dispersed state on carbon and heating to a temperature not exceeding 350 DEG C. The treatment of amyl sulphide in this manner yields isopentane, and dibenzyl sulphide yields toluene (mainly) with some dibenzyl.ALSO:Hydrocarbons such as petroleum, shale oil, or crude benzol are freed from sulphur compounds by passing the oil vapours at normal pressure together with hydrogen or hydrogen-containing gas over a catalyst consisting of nickel deposited on aluminium hydroxide, or other metals of the 8th group of the Periodic system deposited in a finely dispersed state on carbon, and heating to a temperature not exceeding 350 DEG C. Platinum or palladium deposited on active charcoal may be used. Sulphides, thiophene and thiophane are thereby eliminated with the formation of hydrogen sulphide. The catalyst may be regenerated after use by heating in a current of air. The treatment of amyl sulphide in this manner yields isopentane, and dibenzyl sulphide yields toluene (mainly) with some dibenzyl.
GB1108634A 1934-04-12 1934-04-12 A method for the desulphurisation of crude benzene, petroleum oils, shale oils and of other hydrocarbon oils containing sulphur Expired GB438354A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1108634A GB438354A (en) 1934-04-12 1934-04-12 A method for the desulphurisation of crude benzene, petroleum oils, shale oils and of other hydrocarbon oils containing sulphur

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1108634A GB438354A (en) 1934-04-12 1934-04-12 A method for the desulphurisation of crude benzene, petroleum oils, shale oils and of other hydrocarbon oils containing sulphur

Publications (1)

Publication Number Publication Date
GB438354A true GB438354A (en) 1935-11-12

Family

ID=9979776

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1108634A Expired GB438354A (en) 1934-04-12 1934-04-12 A method for the desulphurisation of crude benzene, petroleum oils, shale oils and of other hydrocarbon oils containing sulphur

Country Status (1)

Country Link
GB (1) GB438354A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2422875A (en) * 1942-08-17 1947-06-24 Johnson & Co A Process of refining hydrocarbons
US8016999B2 (en) 2004-05-31 2011-09-13 Agency For Science, Technology And Research Process for removing sulfur from fuels
US8372267B2 (en) 2008-07-14 2013-02-12 Saudi Arabian Oil Company Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil
US8491779B2 (en) 2009-06-22 2013-07-23 Saudi Arabian Oil Company Alternative process for treatment of heavy crudes in a coking refinery
US8632673B2 (en) 2007-11-28 2014-01-21 Saudi Arabian Oil Company Process for catalytic hydrotreating of sour crude oils
US9260671B2 (en) 2008-07-14 2016-02-16 Saudi Arabian Oil Company Process for the treatment of heavy oils using light hydrocarbon components as a diluent

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2422875A (en) * 1942-08-17 1947-06-24 Johnson & Co A Process of refining hydrocarbons
US8016999B2 (en) 2004-05-31 2011-09-13 Agency For Science, Technology And Research Process for removing sulfur from fuels
US8632673B2 (en) 2007-11-28 2014-01-21 Saudi Arabian Oil Company Process for catalytic hydrotreating of sour crude oils
US8372267B2 (en) 2008-07-14 2013-02-12 Saudi Arabian Oil Company Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil
US9260671B2 (en) 2008-07-14 2016-02-16 Saudi Arabian Oil Company Process for the treatment of heavy oils using light hydrocarbon components as a diluent
US8491779B2 (en) 2009-06-22 2013-07-23 Saudi Arabian Oil Company Alternative process for treatment of heavy crudes in a coking refinery

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