GB428147A - Manufacture of organic bismuth compounds - Google Patents
Manufacture of organic bismuth compoundsInfo
- Publication number
- GB428147A GB428147A GB31142/33A GB3114233A GB428147A GB 428147 A GB428147 A GB 428147A GB 31142/33 A GB31142/33 A GB 31142/33A GB 3114233 A GB3114233 A GB 3114233A GB 428147 A GB428147 A GB 428147A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- endo
- methylene
- acids
- endomethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001622 bismuth compounds Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 15
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 4
- 229910000043 hydrogen iodide Inorganic materials 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 150000007513 acids Chemical class 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001621 bismuth Chemical class 0.000 abstract 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052740 iodine Inorganic materials 0.000 abstract 2
- 239000011630 iodine Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 238000006467 substitution reaction Methods 0.000 abstract 2
- CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical class CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 abstract 1
- 229930006739 camphene Natural products 0.000 abstract 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 abstract 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical class C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 230000001225 therapeutic effect Effects 0.000 abstract 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/12—Saturated polycyclic compounds
- C07C61/125—Saturated polycyclic compounds having a carboxyl group bound to a condensed ring system
- C07C61/13—Saturated polycyclic compounds having a carboxyl group bound to a condensed ring system having two rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Monoiodo - endomethylene - hexahydromethylbenzoic acid is obtained by adding hydrogen iodide to endomethylene-2 : 5- D <3>-tetrahydro-6-methyl-benzoic acid. By adding iodine to the parent acid the corresponding diiodo-acid is obtained. From the diiodo-acid hydrogen iodide may be split off to give a mono-iodo acid. Specification 374,818 is referred to.ALSO:Bismuth salts of therapeutic value which are insoluble in water, but soluble in ether, chloroform, and oils, are obtained by reacting a bismuth salt such as the nitrate with a wholly or partially hydrogenated endo-methylenebenzoic acid or a substitution product thereof. Salts of the formula R3Bi or R.BiO, where R is the acid radicle, may both be obtained. Acids specified for use are camphenilanic acid (obtainable by oxidation of camphene), the endo-methylene-benzoic acid obtainable by oxidation of b -pinene, endo-methylene-tetrahydro-methyl- or ethyl-benzoic acids obtainable by diene-synthesis from cyclopentadienes and crotonic acid, endo - methylene - hexahydrobenzoic acid, endo - methylene - hexahydromethylbenzoic acid, endo-methylene-hexahydroethylbenzoic acid, and camphene-carboxylic acids wherein the endo-methylene hydrogen atoms have been replaced by alkyl groups. Substituted acids include substitution products of hydroxycamphenilanic acid, monoiodo-endomethylene - hexahydromethyl - benzoic acid obtained by adding hydrogen iodide to endomethylene - 2 : 5 - D <3> - tetrahydro - 6 - methylbenzoic acid, the corresponding diiodo-acid obtainable by adding iodine to the same parent acid, the monoiodo-acid obtained by splitting off hydrogen iodide from the diiodoacid just described, and also nitrated partially or wholly hydrogenated endo-methylene-benzoic acids. In examples, the acids used are dissolved in water or alcohol in the presence of caustic soda and are reacted with a solution of bismuth nitrate in water and glycerine or mannite. Specification 374,818 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE428147X | 1932-11-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB428147A true GB428147A (en) | 1935-05-08 |
Family
ID=6477416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31142/33A Expired GB428147A (en) | 1932-11-08 | 1933-11-08 | Manufacture of organic bismuth compounds |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2058403A (en) |
| GB (1) | GB428147A (en) |
| NL (1) | NL37063C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5021598A (en) * | 1989-07-24 | 1991-06-04 | Mooney Chemicals, Inc. | Process for making bismuth carboxylates |
| JP2013147489A (en) * | 2011-12-22 | 2013-08-01 | Gc Corp | Agent for imparting fluorescence to ceramic |
-
0
- NL NL37063D patent/NL37063C/xx active
-
1933
- 1933-11-07 US US697078A patent/US2058403A/en not_active Expired - Lifetime
- 1933-11-08 GB GB31142/33A patent/GB428147A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2058403A (en) | 1936-10-27 |
| NL37063C (en) |
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