GB422353A - Improvements in the production of metallic catalysts by electrolytic methods - Google Patents

Improvements in the production of metallic catalysts by electrolytic methods

Info

Publication number
GB422353A
GB422353A GB1955233A GB1955233A GB422353A GB 422353 A GB422353 A GB 422353A GB 1955233 A GB1955233 A GB 1955233A GB 1955233 A GB1955233 A GB 1955233A GB 422353 A GB422353 A GB 422353A
Authority
GB
United Kingdom
Prior art keywords
cage
nickel
employed
per cent
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1955233A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KENNETH ALAN WILLIAMS
TECHNICAL RES WORKS Ltd
Original Assignee
KENNETH ALAN WILLIAMS
TECHNICAL RES WORKS Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KENNETH ALAN WILLIAMS, TECHNICAL RES WORKS Ltd filed Critical KENNETH ALAN WILLIAMS
Priority to GB1955233A priority Critical patent/GB422353A/en
Publication of GB422353A publication Critical patent/GB422353A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

In the production or re-activation of hydrogenating or dehydrogenating catalysts by surface anodic oxidation of nickel, copper or their alloys or mixtures thereof and subsequent reduction, the metal is treated in the form of wire, turnings, gauze, perforated discs, shot or the like, preferably within a cage, and the current density is maintained below 0,05 amps per square inch of a smooth surface externally bounding the metallic mass. In an example, a perforated or gauze cage of nickel or the metal known under the Registered Trade Mark "Monel" 3,5 ft. in length and 6 inches in diameter is filled with 35 lbs. of nickel turnings packed so as to occupy not more than 10--15 per cent of the volume. A canvas sheet is disposed between the cage and the cathode. A solution of sodium carbonate of strength 1--5 per cent, preferably 3 per cent, free from chlorides is employed as electrolyte and is stirred continuously or at intervals, e.g. by rotation of the cage. A current of 40 amps at 3,5--4 volts is employed. Alternatively a horizontal cage may be employed, being preferably so disposed in the cell that gas bubbles formed do not travel through the mass of metal more than twelve inches in rising to the surface of the electrolyte.
GB1955233A 1933-07-10 1933-07-10 Improvements in the production of metallic catalysts by electrolytic methods Expired GB422353A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1955233A GB422353A (en) 1933-07-10 1933-07-10 Improvements in the production of metallic catalysts by electrolytic methods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1955233A GB422353A (en) 1933-07-10 1933-07-10 Improvements in the production of metallic catalysts by electrolytic methods

Publications (1)

Publication Number Publication Date
GB422353A true GB422353A (en) 1935-01-10

Family

ID=10131284

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1955233A Expired GB422353A (en) 1933-07-10 1933-07-10 Improvements in the production of metallic catalysts by electrolytic methods

Country Status (1)

Country Link
GB (1) GB422353A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2627531A (en) * 1947-12-15 1953-02-03 Vogt Hans Porous electrode

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2627531A (en) * 1947-12-15 1953-02-03 Vogt Hans Porous electrode

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