GB420386A - Improvements in or relating to the production of compositions comprising organic polysulphide plastics and synthetic resins - Google Patents
Improvements in or relating to the production of compositions comprising organic polysulphide plastics and synthetic resinsInfo
- Publication number
- GB420386A GB420386A GB1837333A GB1837333A GB420386A GB 420386 A GB420386 A GB 420386A GB 1837333 A GB1837333 A GB 1837333A GB 1837333 A GB1837333 A GB 1837333A GB 420386 A GB420386 A GB 420386A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- plastic
- polysulphide
- solution
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/14—Polysulfides
- C08G75/16—Polysulfides by polycondensation of organic compounds with inorganic polysulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/38—Block or graft polymers prepared by polycondensation of aldehydes or ketones onto macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Plastic compositions of organic polysulphide plastics, of the kind obtained by the reaction of reactive halogenized hydrocarbons with a polysulphide or thiosulphate of an alkali or alkaline earth metal, and synthetic resins of the phenol-aldehyde, polyhydric alcohol-polycarboxylic acid and aldehyde-arylamine types are manufactured by dissolving the organic polysulphide plastic in one of the parent substances for the resin and completing the formation of the latter after the addition of the remaining parent substance or substances. The process may be carried out by dissolving the plastic in an aromatic hydroxy compound or compounds, e.g. phenol, and reacting the solution with an aldehyde, e.g. formaldehyde or acetaldehyde, or a mixture of aldehydes, the aldehyde being, if desired, generated in situ; or by dissolving the plastic in a polybasic acid or anhydride or a mixture thereof, e.g. phthalic anhydride or a mixture thereof with an aliphatic dicarboxylic acid, and treating the solution with one or more polyhydric alcohols, e.g. glycerol or a mixture of glycerol and glycol; or by dissolving the plastic in an aromatic amine, e.g. aniline, or a mixture of amines, and reacting the solution with one or more aldehydes, e.g. acetaldehyde. The polysulphide plastics may be prepared by reacting di- or polyhalogenated saturated or unsaturated hydrocarbons with a polysulphide or thiosulphate of an alkali or alkaline earth metal, and in the latter case removing the metallic radicle by hydrolysis, oxidation or reduction. The products are suitable for addition to rubber for improving its impermeability and oil- and solvent-resistance. In examples: (1) diethylene tetrasulphide (obtained by refluxing a mixture of an alcoholic solution of ethylene dichloride and aqueous sodium thiosulphate and heating the product with hydrogen peroxide) is dissolved in molten phenol and the solution is treated with formalin in the presence of hydrochloric acid; the product may be added to a rubber mix containing sulphur, zinc oxide, mercaptobenzthiazole, stearic acid and carbon black, which is then vulcanized; (2) diethylene tetrasulphide is dissolved in molten phthalic anhydride and the mixture as heated with glycerol and succinic acid; (3) diethylene tetrasulphide is dissolved in molten phenol and the solution is heated with paracetaldehyde in the presence of sulphuric acid; (4) diethylene tetrasulphide is dissolved in hot aniline and the mixture is refluxed with aqueous formaldehyde.ALSO:The impermeability and oil- and solventresistance of rubber are improved by the addition of plastic compositions of organic polysulphide plastics, of the kind obtained by the reaction of reactive halogenized hydrocarbons with a polysulphide or thiosulphate of an alkali or alkaline earth metal, and synthetic resins of the phenol-aldehyde, polyhydric alcohol-polycarboxylic acid and aldehyde-arylamine types, obtained by dissolving the organic polysulphide plastic in one of the parent substances for the resin and completing the formation of the latter after the addition of the remaining parent substance or substances. In an example, a plastic composition produced by dissolving diethylene tetrasulphide in molten phenol and treating the solution with formalin is added to a rubber mix containing sulphur, zinc oxide, mercaptobenzthiazole, stearic acid, and carbon black, which is then vulcanized.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1837333A GB420386A (en) | 1933-06-28 | 1933-06-28 | Improvements in or relating to the production of compositions comprising organic polysulphide plastics and synthetic resins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1837333A GB420386A (en) | 1933-06-28 | 1933-06-28 | Improvements in or relating to the production of compositions comprising organic polysulphide plastics and synthetic resins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB420386A true GB420386A (en) | 1934-11-30 |
Family
ID=10111339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1837333A Expired GB420386A (en) | 1933-06-28 | 1933-06-28 | Improvements in or relating to the production of compositions comprising organic polysulphide plastics and synthetic resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB420386A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2646415A (en) * | 1948-02-11 | 1953-07-21 | Reconstruction Finance Corp | Copolymers of polythiols, phenols, and aldehydes |
US4211687A (en) | 1977-07-27 | 1980-07-08 | Hooker Chemicals & Plastics Corp. | Polymer blends with improved flame retardance |
EP0055212A1 (en) * | 1980-12-13 | 1982-06-30 | Ciba-Geigy Ag | Process for preparing dispersions which contain phenol resins, and their use as adhesives |
-
1933
- 1933-06-28 GB GB1837333A patent/GB420386A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2646415A (en) * | 1948-02-11 | 1953-07-21 | Reconstruction Finance Corp | Copolymers of polythiols, phenols, and aldehydes |
US4211687A (en) | 1977-07-27 | 1980-07-08 | Hooker Chemicals & Plastics Corp. | Polymer blends with improved flame retardance |
EP0055212A1 (en) * | 1980-12-13 | 1982-06-30 | Ciba-Geigy Ag | Process for preparing dispersions which contain phenol resins, and their use as adhesives |
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