GB408952A - Improved manufacture of organic cellulose ester moulding powders - Google Patents

Improved manufacture of organic cellulose ester moulding powders

Info

Publication number
GB408952A
GB408952A GB20333/32A GB2033332A GB408952A GB 408952 A GB408952 A GB 408952A GB 20333/32 A GB20333/32 A GB 20333/32A GB 2033332 A GB2033332 A GB 2033332A GB 408952 A GB408952 A GB 408952A
Authority
GB
United Kingdom
Prior art keywords
acetate
added
cellulose
solution
toluene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20333/32A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kodak Ltd
Original Assignee
Kodak Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kodak Ltd filed Critical Kodak Ltd
Publication of GB408952A publication Critical patent/GB408952A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B3/00Preparation of cellulose esters of organic acids
    • C08B3/22Post-esterification treatments, including purification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

A granular finely divided powder suitable for moulding purposes is prepared by dissolving an organic ester of cellulose in an inert solvent in the proportion of at least three parts by weight of solvent to one part of ester, and precipitating it by adding an organic precipitant. Any plasticizer may be added to the ester solution before precipitation. The mixture of solvent and precipitant may be removed from the precipitated ester by filtration or by evaporation. Organic esters specified are the acetate, acetate - propionate, propionate, butyrate, acetate - butyrate, and acetate - stearate. Examples of precipitants for cellulose acetate are benzene, toluene, xylene, carbon tetrachloride, methyl and ethyl alcohols, gasoline, kerosene, butane, propane, pentane, hexane, n-butyl alcohol, amyl acetate, trichlorethylene, butoxy-ethyl alcohol, and propylene chloride; for cellulose acetate - propionate there are mentioned carbon tetrachloride, toluene, trichlorethylene, butyl alcohol, iso-propyl ether, and butoxy-ethyl alcohol. Iso-propyl ether precipitates all organic esters of cellulose from solution. The drawings (not shown) show a curve which indicates that for a cellulose acetate-acetone (1 : 4) solution, using toluene as precipitant, the lower the temperature of precipitation, the smaller the particle size obtained. This result is said to be general for cellulose organic esters. The following examples are given: (1) Cellulose acetate is dissolved in six parts of acetone and one part of water is added; this does not produce precipitation. Toluene is then added with thorough agitation to precipitate the ester. (2) Toluene is added to a solution of cellulose acetate obtained as in (1) to produce a jelling of the acetate. A small quantity of water is then added, followed by further additions of toluene, with or without water. (3) Cellulose is dissolved in acetone (4 parts) together with dimethyl or diethyl phthalate as plasticizers. Toluene is then added to precipitate the acetate. (4) Cellulose acetate-stearate is dissolved in six parts of acetone, and precipitated by means of methyl alcohol. (5) Cellulose acetatepropionate is dissolved in 8 parts of acetone, and 36 parts of carbon tetrachloride are added. To the jelled material is then added more carbon tetrachloride to complete the precipitation. (6) The solution of example (5) is treated with butyl alcohol, and the precipitate filtered and washed. (7) The solution of example (5) is precipitated by means of iso-propyl ether. (8) To the solution of example (5) there is first added trichlorethylene to produce a gel, followed by further quantities of trichorethylene to precipitate the cellulose acetate-propionate. Specifications 275,558 and 285,829, [both in Class 70], are referred to. The Specification as open to inspection under Sect. 91 refers in general to a process for dissolving an organic ester of cellulose in a solvent therefor and precipitating it from solution by the addition of an organic precipitant. This subject-matter does not appear in the Specification as accepted.ALSO:A granular finely divided powder suitable for moulding purposes is prepared by dissolving an organic ester of cellulose in an inert solvent in the proportion of at least three parts by weight of solvent to one part of ester, and precipitating it by adding an organic precipitant. Any plasticizer may be added to the ester solution before precipitation. The mixture of solvent and precipitant may be removed from the precipitated ester by filtration or by evaporation. Organic esters specified are the acetate, acetate-propionate, propionate, butyrate, acetate - butyrate, and acetate - stearate. Examples of precipitants for cellulose acetate are benzene, toluene, xylene, carbon tetrachloride, methyl and ethyl alcohols, gasoline, kerosene, butane, propane, pentane, hexane, n-butyl alcohol, amyl acetate, trichlorethylene, butoxy-ethyl alcohol, and propylene chloride; for cellulose acetate-propionate there are mentioned carbon tetrachloride, toluene, trichlorethylene, butyl alcohol, isopropyl ether, and butoxy-ethyl alcohol. Iso-propyl ether precipitates all organic esters of cellulose from solution. The drawings (not shown) show a curve which indicates that for a cellulose acetate-acetone (1 : 4) solution, using toluene as precipitant, the lower the temperature of precipitation, the smaller the particle size obtained. This result is said to be general for cellulose organic esters. The following examples are given:-(1) Cellulose acetate is dissolved in six parts of acetone and one part of water is added; this does not produce precipitation. Toluene is then added with thorough agitation to precipitate the ester. (2) Toluene is first added to a solution of cellulose acetate obtained as in (1) to produce a jelling of the acetate. A small quantity of water is then added, followed by further additions of toluene, with or without water. (3) Cellulose is dissolved in acetone (4 parts) together with dimethyl or diethyl phthalate as plasticizer. Toluene is then added to precipitate the acetate. (4) Cellulose acetate-stearate is dissolved in six parts of acetone, and precipitated by means of methyl alcohol. (5) Cellulose acetate-propionate is dissolved in 8 parts of acetone, and 36 parts of carbon tetrachloride are added. To the jelled material is then added more carbon tetrachloride to complete the precipitation. (6) The solution of example (5) is treated with butyl alcohol, and the precipitate filtered and washed. (7) The solution of example (5) is precipitated by means of iso-propyl ether. (8) To the solution of example 5 there is first added trichlorethylene to produce a gel, followed by further quantities of trichorethylene to precipitate the cellulose acetate-propionate. Specifications 275,558 and 285,829, [both in Class 70], are referred to. The Specification as open to inspection under Sect. 91 refers in general to a process for dissolving an organic ester of cellulose in a solvent therefor and precipitating it from solution by the addition of an organic precipitant. This subject-matter does not appear in the Specification as accepted.
GB20333/32A 1931-07-17 1932-07-18 Improved manufacture of organic cellulose ester moulding powders Expired GB408952A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US408952XA 1931-07-17 1931-07-17

Publications (1)

Publication Number Publication Date
GB408952A true GB408952A (en) 1934-04-18

Family

ID=21913571

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20333/32A Expired GB408952A (en) 1931-07-17 1932-07-18 Improved manufacture of organic cellulose ester moulding powders

Country Status (1)

Country Link
GB (1) GB408952A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009144373A1 (en) 2008-05-30 2009-12-03 Upm-Kymmene Oyj Process for producing a pigment product based on a cellulose ester

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009144373A1 (en) 2008-05-30 2009-12-03 Upm-Kymmene Oyj Process for producing a pigment product based on a cellulose ester
EP2291407A1 (en) * 2008-05-30 2011-03-09 UPM-Kymmene Oyj Process for producing a pigment product based on a cellulose ester
EP2291407A4 (en) * 2008-05-30 2013-04-10 Upm Kymmene Corp Process for producing a pigment product based on a cellulose ester

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