GB393317A - Improvements in or relating to the separation of ethylene from its homologues - Google Patents

Improvements in or relating to the separation of ethylene from its homologues

Info

Publication number
GB393317A
GB393317A GB3345931A GB3345931A GB393317A GB 393317 A GB393317 A GB 393317A GB 3345931 A GB3345931 A GB 3345931A GB 3345931 A GB3345931 A GB 3345931A GB 393317 A GB393317 A GB 393317A
Authority
GB
United Kingdom
Prior art keywords
tower
propylene
ethylene
gas
gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3345931A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3345931A priority Critical patent/GB393317A/en
Publication of GB393317A publication Critical patent/GB393317A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/11Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids

Abstract

<PICT:0393317/IV/1> Ethylene is separated from its homologues, for instance from industrial gases containing olefines such as oil cracking gases by absorbing the ethylene in an ammoniacal cuprous solution and recovering it therefrom by heating and/or reduced pressure. The gases before or after treatment with the cuprous solution may be treated with a solvent for propylene such as kerosene, and the propylene is recovered therefrom by heating or reduced pressure. The absorption of the ethylene and propylene may be effected under pressure preferably of the order of 20 atmospheres, and the recovery of the dissolved gases may be effected by reducing the pressure in stages. The cuprous solution may be made by dissolving cuprous oxide in aqueous formic acid, and adding ammonia. In an example, an oil cracking gas is washed in a tower 2, as shown in the Figure, with a counter-current of kerosene, the exit gas passing by a pipe 3 to a tower 4 in which it meets the cuprous solution. The kerosene from the tower 2 is passed through two "let down" vessels 5, 6 in which the pressure is successively reduced and then returns to the tower 2. The gas liberated in the vessel 5 which retains most of the ethylene that has dissolved with the propylene, is returned to the compresser 1 which supplies the raw gas to the tower 2. The gas liberated in the vessel 6 contains a high proportion of propylene and may be used as a source of propylene compounds. The cuprous solution from the tower 4 is passed through "let down" vessels 10, 11 in which the pressure is reduced in stages, and then through a heater 12 to a regenerating vessel 13 and is returned to the tower 4. The gas liberated in the vessel 10 is passed back to the compresser 1; the gas liberated in the vessels 11, 13 is the enriched ethylene which is the product of the process. Another modification is described in which the kerosene washing is applied subsequently to the cuprous solution washing. Particulars are given of the composition of the gases at the various stages of the process. Specification 390,863 is referred to.ALSO:<PICT:0393317/III/1> Ethylene is separated from its homologues, for instance, from industrial gases containing olefines such as oil cracking gases, by absorbing the ethylene in an ammoniacal cuprous solution and recovering it therefrom by heating and/or reduced pressure. The gases before or after treatment with the cuprous solution may be treated with a solvent for propylene such as kerosene, and the propylene is recovered therefrom by heating or reduced pressure. The absorption of the ethylene and propylene may be effected under pressure preferably of the order of 20 atmospheres, and the recovery of the dissolved gases may be effected by reducing the pressure in stages. The cuprous solution may be made by dissolving cuprous oxide in aqueous formic acid, and adding ammonia. In an example, an oil cracking gas is washed in a tower 2, as shown in the Figure, with a counter-current of kerosene, the exit gas passing by a pipe 3 to a tower 4 in which it meets the cuprous solution. The kerosene from the tower 2 is passed through two "let-down" vessels 5, 6 in which the pressure is successively reduced and then returns to the tower 2. The gas liberated in the vessel 5 which contains most of the ethylene that has dissolved with the propylene is returned to the compresser 1 which supplies the raw gas to the tower 2. The gas liberated in the vessel 6 contains a high proportion of propylene and may be used as a source of propylene compounds. The cuprous solution from the tower 4 is passed through letdown vessels 10, 11 in which the pressure is reduced in stages and then through a heater 12 to a regenerating vessel 13 and is returned to the tower 4. The gas liberated in the vessel 10 is passed back to the compresser 1; the gas liberated in the vessels 11, 13 is the enriched ethylene which is the product of the process. Another modification is described in which the kerosene washing is applied subsequently to the cuprous solution washing. Particulars are given of the composition of the gases at the various stages of the process. Specification 390,863, [Group IV], is referred to.
GB3345931A 1931-12-02 1931-12-02 Improvements in or relating to the separation of ethylene from its homologues Expired GB393317A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3345931A GB393317A (en) 1931-12-02 1931-12-02 Improvements in or relating to the separation of ethylene from its homologues

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3345931A GB393317A (en) 1931-12-02 1931-12-02 Improvements in or relating to the separation of ethylene from its homologues

Publications (1)

Publication Number Publication Date
GB393317A true GB393317A (en) 1933-06-02

Family

ID=10353237

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3345931A Expired GB393317A (en) 1931-12-02 1931-12-02 Improvements in or relating to the separation of ethylene from its homologues

Country Status (1)

Country Link
GB (1) GB393317A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1108204B (en) * 1957-02-26 1961-06-08 Hoechst Ag Process for decomposing the reaction mixtures of hydrocarbon splitting

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1108204B (en) * 1957-02-26 1961-06-08 Hoechst Ag Process for decomposing the reaction mixtures of hydrocarbon splitting

Similar Documents

Publication Publication Date Title
US2250925A (en) Process for the separation of acetylene from admixture with ethylene
US1897725A (en) Process for extracting carbon dioxid from gaseous mixtures and forming alkaline carbonates
US2785045A (en) Separation of carbon dioxide from ammonia
US2106446A (en) Removal of gaseous weak acids from gases containing the same
US1977659A (en) Process of recovering ethylene from gaseous olefine mixtures containing the same
DE2433423A1 (en) METHOD FOR CONCENTRATION AND PURIFICATION OF AETHYLENE OXYDE
US3232027A (en) Separation and recovery of components from gas mixtures
US2409441A (en) Production of glycols
GB1180100A (en) A process for Recovering Acrolein
US3139324A (en) Method for purifying gases
US3217466A (en) Recovery of ethylene oxide
GB1352759A (en) Processing of coke oven gas
US2830095A (en) Production of ethylene chlorohydrin
GB393317A (en) Improvements in or relating to the separation of ethylene from its homologues
US2238490A (en) Treatment of gas mixtures containing acetylene
JPS5919882B2 (en) Ammonia and acid gas separation and recovery method
GB725000A (en) Improvements in or relating to method for separating carbon dioxide and hydrogen sulphide from gas mixtures
US3554690A (en) Apparatus and method for removing carbon dioxide from process gases
US2288176A (en) Recovery of readily volatile bases
US2134482A (en) Process of recovering so from waste gases
US3006729A (en) Recovery of high concentration carbon monoxide from copper liquor used to purify ammonia synthesis gas
US2870232A (en) Acetylene removal from diolefin streams
US3296326A (en) Process for recovery of diethylene glycol monoalkyl ether in an acetylin recovery process
GB390863A (en) Improvements in the recovery of ethylene
GB1014477A (en) Process for the recovery of cobalt catalysts