GB391444A - Improvements in or relating to the manufacture of acetaldehyde - Google Patents
Improvements in or relating to the manufacture of acetaldehydeInfo
- Publication number
- GB391444A GB391444A GB2968931A GB2968931A GB391444A GB 391444 A GB391444 A GB 391444A GB 2968931 A GB2968931 A GB 2968931A GB 2968931 A GB2968931 A GB 2968931A GB 391444 A GB391444 A GB 391444A
- Authority
- GB
- United Kingdom
- Prior art keywords
- perforated
- catalyst
- catalyst bed
- oxygen
- reactants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00123—Fingers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
<PICT:0391444/IV/1> <PICT:0391444/IV/2> In the production of acetaldehyde by the vapour phase oxidation of ethyl alcohol, all or part of the oxygen and/or the alcohol is introduced into the reaction zone at a number of points spaced along the reaction zone in or parallel to the line of flow of the gases through the zone. For this purpose perforated members or pipes may be arranged in or around a bed of catalyst, or the catalyst bed may be surrounded by a perforated shell. Preferably the oxygen or air is added through the perforated members, the alcohol, which may contain some oxygen (e.g. 10-20 per cent) being passed through the catalyst bed. The total quantity of oxygen used may be the theoretical quantity or more or less, and diluents such as nitrogen, carbon dioxide or steam may be present with either of the reactants. The catalyst may be silver, copper, or silver or copper oxide at 250-500 DEG C. The temperature of the catalyst may be controlled by means of hollow heat-exchanging elements within the reaction zone and supplied with water or other cooling fluid, and such cooling fluid may be caused to move as a travelling film as described in Specification 390,186. If desired the reactant introduced at various points may be at lower temperature than the reaction stream. In the apparatus shown, a catalyst bed 2 is arranged in a reaction vessel 1 having cooling members 3 formed of concentric tubes, the outer tubes being closed at the top and connected at the bottom to a water-box 6, while the inner tubes are open at the top and connected with a steam-box 8, water being admitted at 7 and steam escaping at 9. Reactants are supplied at 13 through a chamber 12 and perforated pipes 10, and at 15 through a perforated plate 19 direct to the catalyst bed, the reaction products being withdrawn at 17. There may be several inlets 15 disposed around the vessel 1. In a modification Fig. 2, the reactants are supplied together through the inlet 13, part of the mixture passing direct through the catalyst bed by way of the perforated plate 19, and part through the perforated pipes 10. Specification 390,504 is referred to.ALSO:<PICT:0391444/III/1> <PICT:0391444/III/2> In the production of acetaldehyde by the vapour phase oxidation of ethyl alcohol, all or part of the oxygen and/or the alcohol is introduced into the reaction zone at a number of points spaced along the reaction zone in or parallel to the line of flow of the gases through the zone. For this purpose perforated members or pipes may be arranged in or around a bed of catalyst, or the catalyst bed may be surrounded by a perforated shell. Preferably the oxygen or air is added through the perforated members, the alcohol which may contain some oxygen (e.g. 10-20 per cent) being passed through the catalyst bed. The total quantity of oxygen used may be the theoretical quantity or more or less, and diluents such as nitrogen, carbon dioxide or steam may be present with either of the reactants. The catalyst may be silver, copper or silver or copper oxide at 250-500 DEG C. The temperature of the catalyst may be controlled by means of hollow heat-exchanging elements within the reaction zone and supplied with water or other cooling fluid, and such cooling fluid may be caused to move as a travelling film as described in Specification 390,186. If desired the reactant introduced at various points may be at lower temperature than the reaction stream. In the apparatus shown, a catalyst bed 2 is arranged in a reaction vessel 1 having cooling members 3 formed of concentric tubes, the outer tubes being closed at the top and connected at the bottom to a water-box 6, while the inner tubes are open at the top and connected with a steam-box 8, water being admitted at 7 and steam escaping at 9. Reactants are supplied at 13 through a chamber 12 and perforated pipes 10, and at 15 through a perforated plate 19 direct to the catalyst bed, the reaction products being withdrawn at 17. There may be several inlets 15 disposed around the vessel 1. In a modification, Fig. 2, the reactants are supplied together through the inlet 13, part of the mixture passing direct through the catalyst bed by way of the perforated plate 19, and part through the perforated pipes 10. Specification 390,504 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2968931A GB391444A (en) | 1931-10-26 | 1931-10-26 | Improvements in or relating to the manufacture of acetaldehyde |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2968931A GB391444A (en) | 1931-10-26 | 1931-10-26 | Improvements in or relating to the manufacture of acetaldehyde |
Publications (1)
Publication Number | Publication Date |
---|---|
GB391444A true GB391444A (en) | 1933-04-26 |
Family
ID=10295523
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2968931A Expired GB391444A (en) | 1931-10-26 | 1931-10-26 | Improvements in or relating to the manufacture of acetaldehyde |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB391444A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1060788A1 (en) * | 1999-06-15 | 2000-12-20 | Methanol Casale S.A. | Isothermal catalytic reactor for exothermic or endothermic heterogeneous reactions |
US6939520B2 (en) * | 2000-12-14 | 2005-09-06 | Methanol Casale S.A. | Reactor for exothermic or endothermic heterogeneous reactions |
US8529861B2 (en) * | 2002-10-17 | 2013-09-10 | Ammonia Casale S.A. | Method to carry out strongly exothermic oxidizing reactions in pseudo-isothermal conditions |
-
1931
- 1931-10-26 GB GB2968931A patent/GB391444A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1060788A1 (en) * | 1999-06-15 | 2000-12-20 | Methanol Casale S.A. | Isothermal catalytic reactor for exothermic or endothermic heterogeneous reactions |
WO2000076652A1 (en) * | 1999-06-15 | 2000-12-21 | Methanol Casale S.A. | Isothermal reactor for exothermic or endothermic heterogeneous reactions |
US6926873B1 (en) | 1999-06-15 | 2005-08-09 | Methanol Casale S.A. | Reactor in particular for exothermic reactions |
US6958135B1 (en) | 1999-06-15 | 2005-10-25 | Methanol Casale S.A. | Isothermal reactor for exothermic or endothermic heterogeneous reactions |
US6939520B2 (en) * | 2000-12-14 | 2005-09-06 | Methanol Casale S.A. | Reactor for exothermic or endothermic heterogeneous reactions |
US8529861B2 (en) * | 2002-10-17 | 2013-09-10 | Ammonia Casale S.A. | Method to carry out strongly exothermic oxidizing reactions in pseudo-isothermal conditions |
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