GB347646A - Improvements in or relating to the manufacture of compound glass - Google Patents

Improvements in or relating to the manufacture of compound glass

Info

Publication number
GB347646A
GB347646A GB31984/29A GB3198429A GB347646A GB 347646 A GB347646 A GB 347646A GB 31984/29 A GB31984/29 A GB 31984/29A GB 3198429 A GB3198429 A GB 3198429A GB 347646 A GB347646 A GB 347646A
Authority
GB
United Kingdom
Prior art keywords
parts
resin
acetone
cellulose
ethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31984/29A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB347646A publication Critical patent/GB347646A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09J161/22Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

In making laminated glass, a layer of reinforcing material having a basis of cellulose derivative is secured between sheets of glass by means of an adhesive comprising a synthetic resin. The resin may be formed by the condensation of a phenol or cresol or other aromatic compound containing a hydroxyl group, a ketone or with an aldehyde, such as formaldehyde, paraformaldehyde or acetaldehyde in the presence of phosphoric acid or an acid phosphate. The resin may also be formed by the condensation of diphenylol propane and an aldehyde such as formaldehyde, or by the condensation of diphenylol propane with a ketone such as acetone. Other suitable resins may be obtained by the condensation of an aromatic sulphonamide such as toluene, benzene, or xylene sulphonamide with an aldehyde such as formaldehyde, paraformaldehyde, and acetaldehyde. Alkyl toluene sulphonamides such as methyl paratoluene sulphonamide and ethyl paratoluene sulphonamide with an aldehyde may also be used for producing the resin. The adhesive may be a mixture of these resins and may also contain other resins, natural or synthetic, a derivative of cellulose, preferably of low viscosity, plasticizers, softening agents and dyes or stabilizers. The cellulose derivative used in the adhesive may be either an inorganic derivative such as cellulose nitrate, or an organic derivative such as cellulose esters, including cellulose acetate formate, propionate or butyrate, or cellulose ethers such as ethyl, methyl or benzyl cellulose. The reinforcing layer and the adhesive may contain such plasticizers as camphor, triacetin, diethyl tartrate, dibutyl tartrate, diethyl phthalate &c., and also pigments and/or dyes particularly of violet tint. Stabilizers such as urea may be added to the derivatives of cellulose. The cellulose derivative is preferably purified by filtration, or treated either in solid form or in solution with oxidizing agents such as nitric acid or hydrogen peroxide. The adhesive may be applied to the glass or strengthening layer or to both by flowing, spraying, dipping or brushing. In some cases a number of coats may be employed, the first coat preferably having a larger proportion of synthetic resin and succeeding coats having less resin and more cellulose derivative and/or plasticizer. Alternatively the glass may be coated with an adhesive as described above and the reinforcing layer built up by applying further coats comprising a synthetic resin and cellulose derivative. The adhesive coating may be dried at 50-100 DEG C. for 15-60 minutes. Where synthetic resin is the sole solid constituent, suitable solutions are:- (a) Synthetic resin 10 parts by weight, acetone 20 parts by weight. or (b) Synthetic resin 10 parts by weight, benzene 20 parts by weight. or (c) Phenol-aldehyde resin 10 parts by weight, ethyl alcohol 20 parts by weight. The following examples give proportions by weight of solutions containing a high boiling solvent:- (a) Cellulose acetate 8 parts, phenol-aldehyde resin 12 parts, acetone 50 parts, benzene 25 parts, ethyl lactate 20 parts. (b) Cellulose acetate 8 parts, toluene sulphonamide aldehyde resin 12 parts, acetone 50 parts, ethyl alcohol 25 parts, benzene 25 parts, ethyl lactate 5 parts. For a mixture of cellulose acetate and synthetic resin the solution may consist of cellulose acetate 10 parts, synthetic resin 10 parts, acetone 100 parts. The following examples give solutions containing one or more plasticizers:- (a) Synthetic resin 10 parts, monomethylxylene sulphonamide 4 parts, acetone 30 parts. or (b) Ethyl toluene sulphonamide resin 10 parts, ethyl toluene sulphonamide 5 parts, acetone 20 parts. or (c) Lactic acid resin 10 parts, diethyl phthalate 4 parts, acetone 30 parts. or (d) Lactic acid resin 10 parts, triacetin 4 parts, acetone 20 parts. or (e) Phenol-aldehyde resin 15 parts, cellulose acetate 6 parts, triacetin 8 parts, acetone 50 parts, ethyl alcohol 25 parts, benzene 25 parts, benzyl alcohol 5 parts. or (f) Lactic acid resin 6 parts, cellulose acetate 15 parts, triacetin 3 parts, acetone 50 parts, ethyl alcohol 25 parts, benzene 25 parts, diacetone alcohol 10 parts. or (g) Phenol aldehyde resin 20 parts, cellulose acetate 5 parts, diethyl phthalate 5 parts, triacetin 3 parts, acetone 100 parts. The following examples contain more than one synthetic resin. (a) Toluene sulphonamide formaldehyde resin 10 parts, ethyl toluene sulphonamide-formaldehyde resin 10 parts, acetone 20 parts. (b) Ethyl toluene sulphonamide formaldehyde resin 8 parts, toluene sulphonamide formaldehyde resin 12 parts, acetone 50 parts, ethyl alcohol 25 parts, benzene 25 parts, ethyl lactate. The resins in the last example may be replaced by lactic acid resin 8 parts, diphenylol propane formaldehyde resin 10 parts. In the following example cellulose nitrate is included. Synthetic resin 15 parts, cellulose nitrate 11 parts, camphor 4 parts, benzene 40 parts, ethyl alcohol 20 parts, butyl alcohol 40 parts, butyl acetate 40 parts, ethyl acetate 60 parts.
GB31984/29A 1928-10-20 1929-10-21 Improvements in or relating to the manufacture of compound glass Expired GB347646A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US347646XA 1928-10-20 1928-10-20

Publications (1)

Publication Number Publication Date
GB347646A true GB347646A (en) 1931-04-29

Family

ID=21878446

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31984/29A Expired GB347646A (en) 1928-10-20 1929-10-21 Improvements in or relating to the manufacture of compound glass

Country Status (1)

Country Link
GB (1) GB347646A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109195792A (en) * 2016-03-11 2019-01-11 首诺公司 Cellulose esters multilayer sandwich

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109195792A (en) * 2016-03-11 2019-01-11 首诺公司 Cellulose esters multilayer sandwich
CN109195792B (en) * 2016-03-11 2021-08-20 首诺公司 Cellulose ester multilayer interlayers

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