GB341899A - Manufacture of artificial threads and other products from cellulose compounds - Google Patents

Manufacture of artificial threads and other products from cellulose compounds

Info

Publication number
GB341899A
GB341899A GB2225929A GB2225929A GB341899A GB 341899 A GB341899 A GB 341899A GB 2225929 A GB2225929 A GB 2225929A GB 2225929 A GB2225929 A GB 2225929A GB 341899 A GB341899 A GB 341899A
Authority
GB
United Kingdom
Prior art keywords
alkali
treatment
sulphide
alkali sulphide
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2225929A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB2225929A priority Critical patent/GB341899A/en
Publication of GB341899A publication Critical patent/GB341899A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/53Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Coatings and other materials produced by the processes of the parent Specification, and Specifications 335,993, [Class 95, Paints &c.], and 341,930 are desulphurized by treating with warm or hot alkali sulphide solution containing at least 5 per cent of alkali sulphide calculated as Na2S; 9 H2O, or with an equivalent strength of alkali hydrosulphide. The treatment removes any yellow colouration or opalescence in the materials as first prepared. It may be carried out on the freshly prepared material or after finishing and drying in the ordinary way. The material may be treated in stretched or non-stretched condition. The treatment may precede or follow a bleaching process, but the latter may be dispensed with if the alkali sulphide is sufficiently strong. The tenacity is said to be increased in many cases, and the treatment may be applied to material which at the time of formation or after treatment with ordinary weak sulphide solutions and bleaching, is not yellow or opalescent. The strength of the alkali sulphide may be varied considerably, for example from 5 to 58 per cent. Specification 274,521, [Class 2 (ii), Cellulose &c.], also is referred to.ALSO:Artificial silk, films, bands, plates, dressings, coatings and the like produced by the processes of the parent Specification, and Specifications 335,993, [Class 2 (ii), Cellulose &c.], and 341,930, are desulphurized by treating with warm or hot alkali sulphide solution containing at least 5 per cent of alkali sulphide, calculated as Na2S; 9H2O, or with alkali hydrosulphide of equivalent strength. The treatment removes any yellow colouration or opalescence in the material as first prepared. It may be carried out on the freshly formed material or after finishing and drying in the normal way. The treatment may take place before or after a bleaching process but the latter may be dispensed with if the alkali sulphide solution is sufficiently strong. The material may be treated in stretched or non-stretched condition. The treatment is stated to increase the tenacity of the material in many cases. In the examples, artificial silk, made according to certain of the examples of the parent Specification, which resists the action of ordinary weak desulphurizing baths, is introduced in unbleached undesulphurized condition into 30 per cent sodium sulphide solution at 100 DEG C. and after 2 minutes is rinsed with hot and cold water and dried. The treated silk is rendered pure white with increased lustre. The strength of the alkali sulphide may be varied from 5 to 58 per cent and the time of treatment may be increased when using the lower concentrations of alkali sulphide. After washing out the alkali sulphide, the silk may be treated with dilute sulphuric acid before the final washing. The process may be applied to products which are white at the time of formation or after desulphurizing and bleaching in the ordinary way, in order to impart to them a softer feel. Specification 274,521, [Class 2 (ii), Cellulose &c.], also is referred to.ALSO:Containing cellulose xanthates and ethers.-Plates, bands, dressings, coatings and the like produced by the processes of the parent Specification, and Specifications 335,993, [Class 70, Indiarubber &c.], and 341,930, are desulphurized by treating with warm or hot alkali sulphide solution containing at least 5 per cent of alkali sulphide, calculated as Na2S; 9H2O, or with alkali hydrosulphide of equivalent strength. The treatment removes any yellow colouration or opalescence in the material as first produced. It may be carried out on the freshly formed material or after finishing and drying in the ordinary way. The treatment may take place before, during or after a bleaching process but the latter may be dispensed with if the alkali sulphide is sufficiently strong. The material may be treated in stretched or non-stretched condition. The treatment is stated to increase the tenacity of the material in many cases, and it may be applied to products, which are not yellow or opalescent at the time of formation or after treating with the ordinary weak sulphide solutions and bleaching. The strength of the alkali sulphide may be varied considerably, for example, from 5 to 58 per cent. Specification 274,521, [Class 2 (ii), Cellulose &c.], also is referred to.
GB2225929A 1929-07-19 1929-07-19 Manufacture of artificial threads and other products from cellulose compounds Expired GB341899A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2225929A GB341899A (en) 1929-07-19 1929-07-19 Manufacture of artificial threads and other products from cellulose compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2225929A GB341899A (en) 1929-07-19 1929-07-19 Manufacture of artificial threads and other products from cellulose compounds

Publications (1)

Publication Number Publication Date
GB341899A true GB341899A (en) 1931-01-19

Family

ID=10176462

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2225929A Expired GB341899A (en) 1929-07-19 1929-07-19 Manufacture of artificial threads and other products from cellulose compounds

Country Status (1)

Country Link
GB (1) GB341899A (en)

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