GB293453A - Improvements in or relating to resinous compositions and varnishes made therefrom - Google Patents
Improvements in or relating to resinous compositions and varnishes made therefromInfo
- Publication number
- GB293453A GB293453A GB18184/28A GB1818428A GB293453A GB 293453 A GB293453 A GB 293453A GB 18184/28 A GB18184/28 A GB 18184/28A GB 1818428 A GB1818428 A GB 1818428A GB 293453 A GB293453 A GB 293453A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- oil
- resins
- rosin
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000002966 varnish Substances 0.000 title abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 8
- 239000003921 oil Substances 0.000 abstract 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229920001568 phenolic resin Polymers 0.000 abstract 3
- 239000005011 phenolic resin Substances 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 3
- 239000002383 tung oil Substances 0.000 abstract 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000010685 fatty oil Substances 0.000 abstract 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 abstract 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 abstract 2
- 235000011007 phosphoric acid Nutrition 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- MLKXDPUZXIRXEP-UHFFFAOYSA-N 2-[6-fluoro-2-methyl-3-[(4-methylsulfinylphenyl)methylidene]-1-indenyl]acetic acid Chemical class CC1=C(CC(O)=O)C2=CC(F)=CC=C2C1=CC1=CC=C(S(C)=O)C=C1 MLKXDPUZXIRXEP-UHFFFAOYSA-N 0.000 abstract 1
- 240000000972 Agathis dammara Species 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 229920001342 Bakelite® Polymers 0.000 abstract 1
- 240000005209 Canarium indicum Species 0.000 abstract 1
- 241000016649 Copaifera officinalis Species 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 abstract 1
- 240000002834 Paulownia tomentosa Species 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 239000004637 bakelite Substances 0.000 abstract 1
- 235000010338 boric acid Nutrition 0.000 abstract 1
- 125000005619 boric acid group Chemical class 0.000 abstract 1
- 150000001907 coumarones Chemical class 0.000 abstract 1
- 239000004862 elemi Substances 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 235000004426 flaxseed Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 abstract 1
- 239000004312 hexamethylene tetramine Substances 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000025 natural resin Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 239000010499 rapseed oil Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/32—Chemically modified polycondensates by organic acids or derivatives thereof, e.g. fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F5/00—Obtaining drying-oils
- C09F5/08—Obtaining drying-oils by esterification of fatty acids
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
293,453. Bakelite Corporation, (Assignees of Turkington, V. H.). July 7, 1927, [Convention date]. Synthetic resins. - Resinous compositions are made by reacting a phenol with a fatty oil, and combining the product with a methylene-containing hardening agent, a sufficient proportion of non-phenolic resin being present to act as a blending agent. Suitable fatty oils comprise tung, linseed or rape oils or mixtures thereof, tung oil being preferred. Suitable non-phenolic resins comprise most natural resins including rosin, rosin-glycerine ester, copals and elemi, and also coumarones, phthalic-anhydride-glycerine resins, furfural and acetone resins. The proportions of a phenol and oil are such that all or nearly all the phenol combines with the oil. The amount of methylene-containing body, such as formaldehyde, paraformaldehyde, hexamethylenetetramine, should be the equivalent of 6 mols of formaldehyde to 6 mols of phenol used. The amount of non-phenolic resin should be not less than 20 parts by weight to 100 parts of phenol used, but may be increased up to 1500 parts. In an example, phenol, tung oil and a little phosphoric acid are heated, and formaldehyde, rosin and a little aqueous ammonia added. After evaporation of water heating is continued to give a product which is a clear non-tacky solid at room temperature. Phosphoric or boric acids may be used as catalysts for the phenol and oil reaction. The second reaction may be produced with or without acid, neutral or alkaline catalysts. The products may be liquid when hot and non-tacky solids when cold and may be used liquid or dissolved in solvents such as turpentine, toluene, xylene, &c. as varnishes, with or without metallic driers &c. Specification 267,736 is referred to. The Specification as open to inspection under Sect. 91 (3) (a) describes the presence of acid resins, such as rosin or manila copal, during the reaction between the phenol and oil. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US293453XA | 1927-07-07 | 1927-07-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB293453A true GB293453A (en) | 1929-12-23 |
Family
ID=21848576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB18184/28A Expired GB293453A (en) | 1927-07-07 | 1928-06-22 | Improvements in or relating to resinous compositions and varnishes made therefrom |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB293453A (en) |
-
1928
- 1928-06-22 GB GB18184/28A patent/GB293453A/en not_active Expired
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