GB292615A - - Google Patents
Info
- Publication number
- GB292615A GB292615A GB18191/28A GB1819128A GB292615A GB 292615 A GB292615 A GB 292615A GB 18191/28 A GB18191/28 A GB 18191/28A GB 1819128 A GB1819128 A GB 1819128A GB 292615 A GB292615 A GB 292615A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alpha
- product
- gamma
- chloride
- amino group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
292,615. I. G. Farbenindustrie Akt.- Ges. June 23, 1927, [Convention date]. Void [Published under Sect. 91 of the Acts]. Aliphatic diamines, containing one secondary and one primary, secondary or tertiary amino group, are prepared by treating a secondary aromatic amine or nuclear-substitution derivative thereof with an aminoalkyl halide, and splitting off the aryl residue from the product. The amino substituent of .the secondary aromatic amine may be an alkyl, hydroxyalkyl or aminoalkyl group. The aminoalkyl halide may contain a tertiary aliphatic amino group, or a primary or secondary aliphatic amino group substituted by an aryl or arylidene group which is subsequently removed. The splitting off of the aryl residue may be effected by producing a p-nitroso compound or other compound containing a negative substituent, and decomposing the product to liberate the amine by means, for example, of alkali. The products are useful as drugs or as intermediates for the manufacture of drugs and dyestuffs. According to the examples (1) N-methyldiethylaminoethylaniline, obtained from monomethylaniline and diethylaminoethyl chloride, is treated in cold hydrochloric acid solution with sodium nitrite, and to the resulting nitroso compound sodium bisulphite solution is slowly run in; after standing some hours, caustic soda is added and the alpha-diethylamino-#-methylaminoethane distilled in steam; in an analogous manner as-triethylethylenediamine is obtained from N-ethyldiethylaminoethylaniline; (2) monomethylaniline is treated with alpha-dimethylamino-gamma-methylpropyl chloride and from the product, alpha-dimethylaminogamma-methylaminobutane is split off by the process of the preceding example; in the same way alpha-dimethylamino-#-methyl-gamma-methylaminobutane is split off from the product of reaction of monoethylaniline and alpha-dimetbylamino-#gamma-dimethylpropyl chloride, and a-diethylamino-#-diethylaminoethylaminoethane from the product of reaction of N-diethylaminoethylaniline and diethylaminoethyl chloride
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE292615T | 1927-06-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB292615A true GB292615A (en) | 1929-07-18 |
Family
ID=31894027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB18191/28A Expired GB292615A (en) | 1927-06-23 | 1928-06-22 |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB292615A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2762697A (en) * | 1951-06-23 | 1956-09-11 | Monsanto Chemicals | N-(alkylmercaptoalkyl) polyamine herbicides |
DE1128861B (en) * | 1958-07-04 | 1962-05-03 | Davis & Company | Process for the preparation of thioxanthone derivatives |
JP2003514888A (en) * | 1999-11-25 | 2003-04-22 | ビーエーエスエフ アクチェンゲゼルシャフト | Method for producing optically active amine |
-
1928
- 1928-06-22 GB GB18191/28A patent/GB292615A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2762697A (en) * | 1951-06-23 | 1956-09-11 | Monsanto Chemicals | N-(alkylmercaptoalkyl) polyamine herbicides |
DE1128861B (en) * | 1958-07-04 | 1962-05-03 | Davis & Company | Process for the preparation of thioxanthone derivatives |
JP2003514888A (en) * | 1999-11-25 | 2003-04-22 | ビーエーエスエフ アクチェンゲゼルシャフト | Method for producing optically active amine |
JP4776846B2 (en) * | 1999-11-25 | 2011-09-21 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for producing optically active amine |
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