GB2623635A - Optical limiters - Google Patents
Optical limiters Download PDFInfo
- Publication number
- GB2623635A GB2623635A GB2313257.4A GB202313257A GB2623635A GB 2623635 A GB2623635 A GB 2623635A GB 202313257 A GB202313257 A GB 202313257A GB 2623635 A GB2623635 A GB 2623635A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nanoparticles
- optical
- metal
- silica
- limiting material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000002105 nanoparticle Substances 0.000 claims abstract description 40
- 230000000670 limiting effect Effects 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 22
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010931 gold Substances 0.000 claims abstract description 12
- 229910052737 gold Inorganic materials 0.000 claims abstract description 12
- 239000000725 suspension Substances 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 description 12
- 230000005540 biological transmission Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008033 biological extinction Effects 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NJSVDVPGINTNGX-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethanamine Chemical compound CCC[Si](OC)(OC)OCN NJSVDVPGINTNGX-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 229960000800 cetrimonium bromide Drugs 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/35—Non-linear optics
- G02F1/355—Non-linear optics characterised by the materials used
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/002—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of materials engineered to provide properties not available in nature, e.g. metamaterials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/24—Liquid filters
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/0147—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on thermo-optic effects
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/35—Non-linear optics
- G02F1/3523—Non-linear absorption changing by light, e.g. bleaching
Abstract
An optical limiting material comprises a suspension of nanoparticles. The nanoparticles comprise alternating layers of silica and metal. The layers comprise a core of silica or metal and a further bilayer of silica and metal. The metal may be gold. The nanoparticles may be spherical. The thickness of each layer was be between 1 nm and 50 nm, the core may be 10-200 nm in diameter, and the nanoparticle diameter may be 50 to 500 nm. The material may be part of an optical instrument which may comprise a lens. The material may be used to limit the peak output intensity from a wide range of incident energy.
Description
Optical Limiters The present invention is concerned with optical limiters and optical limiting materials, which are devices/materials that are capable of protecting sensitive optical elements from laser induced damage. These optical limiters can be used to protect users from pulses of intense light.
Laser light is a known hazard for eyes and sensitive optical devices. There is a need to protect the user's eyes and sensitive optical devices from high intensity laser beams.
Simultaneously, it is essential in many cases that a protective filter does not hinder the low intensity signals and that it retains high linear transmission.
A number of solutions for spectral filtering exist, such as absorbing dyes and reflective interference coatings, however these solutions require prior knowledge of the incoming laser wavelength to be attenuated in order for the correct dye or interference structure to be used.
Reflective interference coatings also suffer from strong angular dependence of the transmission properties, including notch filters and narrow-band pass filters, The present invention thus generally aims to provide optical limiters where broad acceptance angles can be achieved and nonlinear responses can be triggered by all wavelengths of visible light in order to provide a novel active, intensity-limiting filter that can be used with lenses and lens arrangements to protect or limit damage to sensitive optical devices or eyes.
Accordingly in a first aspect, the present invention provides an optical limiting material or optical limiter comprising a suspension of nanoparticles wherein the nanoparticles comprise alternating layers of silica and metal, comprising a core of silica or metal and a further bilayer of silica and metal. The nanoparticle may either have a core of metal, upon which there is a layer of silica and a further layer of metal, or alternatively the nanoparticle may have a core of silica upon which there is a layer of metal and a further layer of silica. This new optical limiter is particularly advantageous as it exhibits optical properties that are independent of the angle of incidence, has high linear transmission, and provides strong levels of non-linear attenuation to high-intensity inputs.
A further advantage of the optical limiter of the first aspect is its resilience when stressed to high power laser pulses; the intensity of the laser beam is not only limited by the optical limiter in its entirety, but the nanoparticles undertake a sacrificial function, in that nanoparticles directly illuminated by a laser may be destroyed in the process, allowing other nanoparticles to replace them, as they move in the suspension, for example by means of convection. The high concentration of nanoparticles in suspension means that although some particles may be destroyed (sacrificed) in achieving the optical limiting effect, there would always be sufficient particles in suspension to ensure protection.
Each multishell nanoparticle comprises a minimum of a core of either silica or metal upon which a bilayer of silica and metal is provided, and may further comprise additional bilayers of silica and metal. Such multishell nanoparticles are also plasmonic metamaterials. The core of the optical limiting nanoparticle may be a plasmonic metal such as copper aluminium, silver or gold. Preferably the metal core is gold, as may be the additional metal layers. The metal (gold) core may be surrounded by one, two, three or more bilayers of silica and gold.
There is a noticeable advantage wherein the nanoparticles are most effective as strong nonlinear filters when there is either one or two bilayers per nanoparticle.
The suspension may comprise of one nanoparticle type where each particle has the same design parameters, or it could comprise of several nanoparticle types where each type has a different design parameter, for example each layer may have a different parameter or the suspension may have a heterogeneous mix of different nanoparticles. This could be advantageous where one type of nanoparticle may perform better at one wavelength compared to another. Improved protection may be created by mixing at least two particle types together.
Preferably, the nanoparticles are suspended in a liquid having low thermal conductivity and high volatility. Such liquids include Cetrimonium Bromide (CTAB) and APTMS (3-aminopropyl-trimethoxysilane). Alternatively the liquid may be water or deionised water.
The multishell nanoparticles may take various geometrical forms, such as the geometry of a sphere, or the geometry of a cylinder, but preferably the multishell nanoparticles are spherical. The main advantage to having spherical nanoparticles is that the spherical geometry removes the dependence of the intensity limiting on the incident light's direction and polarisation.
Suitable dimensions for the particles, particle core, and subsequent layers will be understood by the person skilled in the art, however the radius of the core may be between 5 and 100 nm, and may for example be 10, 20, 30, 40 or 50 nm. Subsequent layers of metal and silica may range between 5 and 50 nm, such as 10, 20, 30, 40 or 50 nm. The total diameter of the nanoparticles may be between 50 and 500 nm, though this may be dependent on the number of layers and bilayers. A one-bilayer particle (core plus bilayer) may have a diameter of 120 nm, a two-bilayer particle (core plus two bilayers) a diameter of 180 nm, and three bilayer particle (core plus three bilayers) 240 nm. Preferably the thickness of each respective layer has a range of between 1-50 nm, preferably aiming for the total diameter of the nanoparticles to be smaller than the operational wavelength of the laser, where the wavelength of the laser is known, which can be advantageous because the smaller-than-wavelength size means that diffraction effects are minimised. This is required so that the laser interacts with the average effect of the particles, otherwise there are diffraction effects; if the particle size is comparable with the wavelength you will get diffraction.
In a further aspect of the invention, the present invention provides an optical instrument comprising the optical limiter/optical limiting material of the first aspect. Use of the optical limiting material in optical instruments has the advantage of providing the optical instrument, or user of the optical instrument, with enhanced protection from intense pulses of light.
Preferably the optical instrument has a lens arrangement wherein there is provided a focal plane within the optical instrument. The optical limiting material is preferably situated at or near to the focal plane in order to provide protection from intense pulses of light.
In a further embodiment of the invention, the optical limiting material is used for the purpose of limiting the peak output intensity from a wide range of incident energies. The use of the optical limiting material is capable of providing protection from beams of intense light across the visible spectrum and provides the advantage that it does not matter what colour of intense light is shone through, the optical limiting material provides protection against this.
Examples
The present invention shall now be discussed with reference to the following non-limiting figures, table and examples, wherein Figure 1 shows experimental extinction spectra of the one, two and three bilayers nnoparticles as described in Table 1.
Figure 2 (a) and (b) shows Nonlinear behaviour of multishells in solutions under illumination at 532 nm: (a) peak fluence transmitted by the sample in function of incident fluence; (b) transmitted energy in function of incident energy, used as a control to understand the nature of the limiting effect shown in (a). The one bilayer and two bilayer systems display very strong intensity limiting due to nonlinear absorption. Several types of mulfishell nanoparticles have been considered and tested. The core of all nanoparticles generated was a spherical gold nanoparficle which is surrounded by one, two or three bilayers of silica and gold, suspended in deionised (Dl) water. The structures have the dimensions shown in Table 1.
Table 1: Dimensions of the nanoparticles used as limiters in suspension. Reported are also the total diameters of the various configurations.
Parameter Value (nm) Gold core radius 30 Silica shells thickness 10 Gold shells thickness 20 Total diameter -one bilayer 120 Total diameter -two bilayers 180 Total diameter -three bilayers 240 The fabrication of such nanoparticles involves the following procedure: seeds of silica are deposited around a gold core, and eventually coalesce into a layer; this step is then repeated for the gold layer that surrounds the silica layer and so on for the other layers, the structures will be identified by the number of silica-gold bilayers, i.e. 1-bilayer means a spherical gold nanoparticle with a silica shell and an outer gold shell; a 2-bilayers multishell is made of gold-silica-gold-silica-gold from the centre outwards, and so on.
Having regard to Figure 1, the linear extinction spectra of all multi-layered structures studied is shown. The one bilayer system has two absorption peaks, centred respectively at 575 nm and 790 nm; they display an extinction of 0.8 at 532 nm and 0.3 at 1064 nm. By increasing the number of layers two effects can be seen: a red shift of the absorption resonances and a more complicated spectrum, sign of the stronger contribution of the higher order moments.
Three investigations have been carried out: the first one involved illumination of the suspensions with a 532 nm laser; in the second one the nanoparticles were illuminated by a 1064 nm laser; finally in the third one it was studied how the cuvette's path length affects the nonlinear transmission.
Having regard to Figure 2 (a) and (b) the results for the 532 nm illumination are shown, compared with the transmission of simple deionised water as a reference. Peak transmitted fluence in function of incident fluence and transmitted energy in function of incident energy is shown. When dealing with camera damage thresholds, peak fluence, i.e. the highest value of fluence measured across the detecting camera, is the relevant quantity at play. As is clear from Figure 2, the one and two bilayers system act as strong nonlinear filters, limiting the output peak fluence across approximately two orders of magnitude change in input energy, showing the filters perform non-linearly over a wide range of input energies; the energy control plot suggests that they act as absorbers as less energy arrives to the detector. The three bilayers particles are less effective as expected from their linear spectra.
Claims (10)
- Claims 1. An optical limiting material comprising a suspension of nanoparticles, wherein the nanoparticles comprise alternating layers of silica and metal, comprising a core of silica or metal and a further bilayer of silica and metal.
- 2. An optical limiting material according to Claim 1 wherein the core of the nanoparticles is metal.
- 3. An optical limiting material according to Claims 1 and 2 wherein the core of the nanoparticles is gold.
- 4. An optical limiting material according to Claims 1-3 wherein the nanoparticles are spherical.
- 5. An optical limiting material according to Claims 1-4 wherein the thickness of each layer within the bilayer are within a range of 1 nm to 50 nm..
- 6. An optical limiting material according to Claims 1-5 wherein the diameter of the core of the nanoparticle is between 10-200 nm.
- 7. An optical limiting material according to Claims 1-6 wherein the total diameter of the nanoparticle is between 50-500 nm.
- 8. An optical instrument comprising an optical limiting material according to claims 1-7
- 9 An optical instrument according to Claim 8, further comprising a lens arrangement to provide a focal plane for light entering the instrument wherein the optical limiting material is situated at or sufficiently near the focal plane.
- 10. Use of an optical limiting material according to claims 1-7, to limit the peak output intensity from a wide range of incident energy.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB2212770.8A GB202212770D0 (en) | 2022-09-02 | 2022-09-02 | Optical limiters |
Publications (2)
Publication Number | Publication Date |
---|---|
GB202313257D0 GB202313257D0 (en) | 2023-10-18 |
GB2623635A true GB2623635A (en) | 2024-04-24 |
Family
ID=83933254
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GBGB2212770.8A Ceased GB202212770D0 (en) | 2022-09-02 | 2022-09-02 | Optical limiters |
GB2313257.4A Pending GB2623635A (en) | 2022-09-02 | 2023-08-31 | Optical limiters |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GBGB2212770.8A Ceased GB202212770D0 (en) | 2022-09-02 | 2022-09-02 | Optical limiters |
Country Status (2)
Country | Link |
---|---|
GB (2) | GB202212770D0 (en) |
WO (1) | WO2024047594A1 (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011146093A2 (en) * | 2009-12-15 | 2011-11-24 | William Marsh Rice University | Electricity generation |
US20120156102A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Waste remediation |
US20120153621A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Cooling systems and hybrid a/c systems using an electromagnetic radiation-absorbing complex |
US20120155841A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Generating a heated fluid using an electromagnetic radiation-absorbing complex |
WO2012082364A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Distilling a chemical mixture using an electromagnetic radiation-absorbing complex for heating |
WO2014127345A2 (en) * | 2013-02-18 | 2014-08-21 | William Marsh Rice University | Solar steam processing of biofuel feedstock and solar distillation of biofuels |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120002312A1 (en) * | 2009-03-13 | 2012-01-05 | Oxazogen, Inc. | Non-focal optical power limiting polymeric materials |
-
2022
- 2022-09-02 GB GBGB2212770.8A patent/GB202212770D0/en not_active Ceased
-
2023
- 2023-08-31 GB GB2313257.4A patent/GB2623635A/en active Pending
- 2023-09-01 WO PCT/IB2023/058653 patent/WO2024047594A1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011146093A2 (en) * | 2009-12-15 | 2011-11-24 | William Marsh Rice University | Electricity generation |
US20120156102A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Waste remediation |
US20120153621A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Cooling systems and hybrid a/c systems using an electromagnetic radiation-absorbing complex |
US20120155841A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Generating a heated fluid using an electromagnetic radiation-absorbing complex |
WO2012082364A1 (en) * | 2010-12-15 | 2012-06-21 | William Marsh Rice University | Distilling a chemical mixture using an electromagnetic radiation-absorbing complex for heating |
WO2014127345A2 (en) * | 2013-02-18 | 2014-08-21 | William Marsh Rice University | Solar steam processing of biofuel feedstock and solar distillation of biofuels |
Also Published As
Publication number | Publication date |
---|---|
WO2024047594A1 (en) | 2024-03-07 |
GB202313257D0 (en) | 2023-10-18 |
GB202212770D0 (en) | 2022-10-19 |
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