GB2602402B - Method for producing hydrogen by iodine-selenium thermochemical cycle phosphorus reduction - Google Patents

Method for producing hydrogen by iodine-selenium thermochemical cycle phosphorus reduction Download PDF

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Publication number
GB2602402B
GB2602402B GB2203207.2A GB202203207A GB2602402B GB 2602402 B GB2602402 B GB 2602402B GB 202203207 A GB202203207 A GB 202203207A GB 2602402 B GB2602402 B GB 2602402B
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GB
United Kingdom
Prior art keywords
iodine
producing hydrogen
thermochemical cycle
phosphorus reduction
selenium thermochemical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
GB2203207.2A
Other versions
GB202203207D0 (en
GB2602402A (en
Inventor
Meng Dongwang
Qi Naiye
Wang Chunming
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CHINERGY CO Ltd
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CHINERGY CO Ltd
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Publication of GB202203207D0 publication Critical patent/GB202203207D0/en
Publication of GB2602402A publication Critical patent/GB2602402A/en
Application granted granted Critical
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/068Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents the hydrogen being generated from the water as a result of a cyclus of reactions, not covered by groups C01B3/063 or C01B3/105
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/16Oxyacids of phosphorus; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/066Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water with phosphorus
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00Halogens; Halogen acids
    • C01B7/13Iodine; Hydrogen iodide
    • C01B7/14Iodine
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0266Processes for making hydrogen or synthesis gas containing a decomposition step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Removal Of Specific Substances (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
GB2203207.2A 2019-08-20 2020-08-13 Method for producing hydrogen by iodine-selenium thermochemical cycle phosphorus reduction Active GB2602402B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201910768263.XA CN110407167B (en) 2019-08-20 2019-08-20 Method for preparing hydrogen by high-temperature gas cooled reactor coupled iodine selenium thermochemical cycle phosphorus reduction
PCT/CN2020/108766 WO2021031963A1 (en) 2019-08-20 2020-08-13 Method for producing hydrogen by iodine-selenium thermochemical cycle phosphorus reduction

Publications (3)

Publication Number Publication Date
GB202203207D0 GB202203207D0 (en) 2022-04-20
GB2602402A GB2602402A (en) 2022-06-29
GB2602402B true GB2602402B (en) 2023-12-13

Family

ID=68368138

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2203207.2A Active GB2602402B (en) 2019-08-20 2020-08-13 Method for producing hydrogen by iodine-selenium thermochemical cycle phosphorus reduction

Country Status (3)

Country Link
CN (1) CN110407167B (en)
GB (1) GB2602402B (en)
WO (1) WO2021031963A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110407167B (en) * 2019-08-20 2021-04-09 中核能源科技有限公司 Method for preparing hydrogen by high-temperature gas cooled reactor coupled iodine selenium thermochemical cycle phosphorus reduction
CN113526461A (en) * 2020-04-17 2021-10-22 孟想 Single selenium thermochemical cycle hydrogen production method
CN113086945A (en) * 2021-04-14 2021-07-09 中核能源科技有限公司 High-temperature gas cooled reactor hydrogen-electricity-water heat cogeneration system
CN116812865B (en) * 2023-08-29 2023-12-05 浙江百能科技有限公司 System and process for thermochemical selenium-iodine cyclic hydrogen production and simultaneous removal of CO in flue gas

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4127644A (en) * 1977-04-29 1978-11-28 General Atomic Company Process for hydrogen production from water
CN1785796A (en) * 2005-10-14 2006-06-14 浙江大学 Technical method of sulfur iodine open circuit circulation hydrogen manufacture and its equipment
CN103213945A (en) * 2013-04-21 2013-07-24 浙江大学 Method for promoting Bunsen reaction in thermochemical iodine-sulfur cycle for hydrogen manufacturing
CN110407167A (en) * 2019-08-20 2019-11-05 中核能源科技有限公司 A kind of high temperature gas cooled reactor coupling iodine selenium thermochemical cycles phosphorus reduction hydrogen production process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3369868A (en) * 1965-06-25 1968-02-20 Gen Electric Method for hydrogen generation from white phosphorus
GB1519397A (en) * 1976-04-01 1978-07-26 Euratom Process for the production of hydrogen
CN101830443B (en) * 2010-04-14 2011-06-15 清华大学 Process for purifying sulfuric acid phase and hydriodic acid phase in iodine-sulfur cycle
CN102583239B (en) * 2012-01-15 2013-10-30 浙江大学 Method and device for preparing CO and H2 by thermochemical cycle decomposition of CO2 and H2O
GB201416062D0 (en) * 2014-09-11 2014-10-29 Univ The Glasgow Hydrogen generation
CN104817057A (en) * 2015-03-10 2015-08-05 深圳市智慧低碳技术有限公司 Pre-mixing device for sulfur-iodine cycle hydrogen production system and sulfur-iodine cycle hydrogen production system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4127644A (en) * 1977-04-29 1978-11-28 General Atomic Company Process for hydrogen production from water
CN1785796A (en) * 2005-10-14 2006-06-14 浙江大学 Technical method of sulfur iodine open circuit circulation hydrogen manufacture and its equipment
CN103213945A (en) * 2013-04-21 2013-07-24 浙江大学 Method for promoting Bunsen reaction in thermochemical iodine-sulfur cycle for hydrogen manufacturing
CN110407167A (en) * 2019-08-20 2019-11-05 中核能源科技有限公司 A kind of high temperature gas cooled reactor coupling iodine selenium thermochemical cycles phosphorus reduction hydrogen production process

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
SHI, Zhicheng. (Non-official translation: Animal Toxicology), 30 June 2001 (2001-06-30), pages 849-850, section 3, selenium *
ZHU, Hongfa et al.(Non-official translation: Handbook of Inorganic Chemical Products), 31 December 2008 (2008-12-31), page 27, section 30, selenous acid *

Also Published As

Publication number Publication date
GB202203207D0 (en) 2022-04-20
CN110407167B (en) 2021-04-09
WO2021031963A1 (en) 2021-02-25
GB2602402A (en) 2022-06-29
CN110407167A (en) 2019-11-05

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