GB2590184A - Composition for use as a surface and method of use and/or manufacture thereof - Google Patents

Composition for use as a surface and method of use and/or manufacture thereof Download PDF

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Publication number
GB2590184A
GB2590184A GB2017684.8A GB202017684A GB2590184A GB 2590184 A GB2590184 A GB 2590184A GB 202017684 A GB202017684 A GB 202017684A GB 2590184 A GB2590184 A GB 2590184A
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GB
United Kingdom
Prior art keywords
composition
composition according
cork
rubber
rubber particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB2017684.8A
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GB202017684D0 (en
Inventor
Melvin Glenn
Colin Melvin Glenn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB202017684D0 publication Critical patent/GB202017684D0/en
Publication of GB2590184A publication Critical patent/GB2590184A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D121/00—Coating compositions based on unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D197/00—Coating compositions based on lignin-containing materials
    • C09D197/007—Cork
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
    • C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/007—Cork

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)

Abstract

A composition suitable for use as a surface coating comprises cork and/or rubber particles and a solvent-based resin carrier. The carrier may be a styrene-acrylic resin, a styrene-butadiene rubber resin, an acrylated rubber resin, or other solvent-based rubber resin. Typically, the composition is nonaqueous and is liquid and/or pourable. The composition may comprise 10-80 wt.% cork and/or rubber particles, which may have an average diameter of ≤5 mm. The rubber may comprise recycled rubber. The composition may also include one or more colorants, especially titanium dioxide, as well as a further solvent or thinning agent, such as white spirit, petroleum spirit, mineral spirit, mineral turpentine, or a petroleum hydrocarbon. The composition may be a surface coating composition for walls, masonry, construction boards, or panels. Another aspect provides a method of manufacturing the composition. A construction board or panel having the composition on an exterior surface thereof is further claimed.

Description

Composition for use as a surface coating and method of use and/or manufacture thereof The present invention relates to a composition for use as a surface coating and to a method of use and/or manufacture thereof Although the following description refers almost exclusively to a surface coating composition in the form of an exterior wall coating composition, it will be appreciated by persons skilled in the art that the composition of the present invention can be used for any purpose and/or applied as a surface coating to any suitable surface, such as to a surface of a construction board or panel, plasterboard, masonry, brick, stone and/or the like, to an interior and/or to an exterior surface, or to any structure, such as a building surface, floor surface and/or the like where a coating is required.
It is known to apply a wall coating in the form of render to an exterior surface of masonry to provide weatherproofing of the masonry and/or to provide a desired aesthetic effect. The render or stucco is typically a construction material made up of aggregate, a binder and water. It is genendly applied to the wall surface as a wet composition using a trowel, which then hardens to a dense solid finish on the masonry.
There are many different types of wall coatings and renders available Most of these wall coatings are water based and therefore suffer from the problem that they cannot be easily applied in cold weather or over the winter months. For example, many water-based coatings cannot be applied when the surface temperature of the exterior air temperature drops below five degrees Celsius. This is the case with water-based cork aggregate contahthig surface coatings. A further problem associated with some wall coatings is that they cannot be easily applied to a wall surface due to their viscosity (Jr stickiness. For example, in order to provide a. traditional render or stucco finish, the surface coating typically has to be sufficiently fluid to allow smooth application onto a wall surface 115ing a. trowel.
It is therefore an a.im of the present invention to provide a surface coating composition which overcomes the abovementioned problems.
It is an aim of the present invention to provide a composition suitable for use as a surface coating with overcomes the abovementioned problems.
It is a further aim of the present invention to provide a method of using a composition suitable for use as a surface coating and/or a surface coating composition which overcomes the abovementioned problems.
It is a yet further aim of the present invention to provide a method of manufacturing a composition suitable for use as a surface coating and/or a surface coating composition winch overcomes the abovementioned problems.
It is a yet further aim of the present invention to provide a construction panel or board which includes a. surface coating composition thereon, and a. method of use thereof.
According to a first aspect of the present invention there is provided a composition for use as a surface coating, said composition including cork and/or rubber particles and a carrier agent, and wherein the carrier agent is a solvent based resin The inclusion of the solvent based resin in the cork and/or rubber containing composition of the present invention allows the composition to be used as a surface coating or surface finish which can be applied to a surface in use, wherein the surface temperature and/or the ambient air temperature is below 5 degrees Celsius, preferably below zero degrees Celsius, and further preferably below minus 5 degrees Celsius, thereby allowing the composition to be used outside in the Winter months or in very cold conditions. Although solvent based wall coatings are known, the combination of a solvent based resin carrier agent with cork and/or rubber particles has not been used before to the best of the Applicant's knowledge.
The use of a solvent based resin in the composition has the advantage over conventional water-based resins in that the particle sizes are much smaller in solvent based resins than in water-based resins. 't his provides solvent based resins with improved adhesion, waterproofing and durability over conventional water-based resins. The cork and/or rubber particles add flexibility, spread-ability and/or trowel-ability to the composition to allow the composition to be applied more easily a.s surface coating in use.
Preferably the carrier agent and the rubber and/or cork particles are mixed together in the composition.
Preferably the mixture of the composition is a homogenous or substantially homogenous mixture.
Preferably the cork and/or rubber particles are suspended in the solvent based resin in the composition.
Preferably die composition can be applied to a surface to provide a waterproof or water-resistant coating to the surface in use.
Preferably the composition is provided in a. liquid and/or pourable form. 't his allows the composition to be fluid or relatively fluid and therefore ca.n be easily applied to a surface by a conventional tool, such as a trowel, brush, roller and/or the like.
Preferably the solvent based resin is or includes a styrene acrylic resin, a styrene butadine rubber resin, an acrylated rubber resin, a solvent based rubber resin, a solvent based synthetic rubber resin and/or the like.
Preferably use of the solvent based resin creates a microporous film on the surface being coating in use. The film has a plurality of relatively small pores which arc smaller than the pores of the surface, such as for example a wall or masonry surface, on which the resin is to be applied in use. 'these pores allow water vapour to pass out through the coated surface and through the film but prevent water from passing in the opposite direction through the surface from the exterior of the film.
Preferably the solvent based resin is a Pliolite0 solvent based resin.
Preferably the solvent based resin is Sandtex Pliolite 365®. however a Pliolite solvent based resin provided by Wethertex0, johnstones0, Dulux0, Leyland® and/or the like could be used.
Preferably the solvent based resin is non-aqueous.
Preferably the composition can be used in surface and/or an: temperatures as low as minus 20 degrees Celsius.
Preferably the composition can be used in surface and/or air temperatures below five degrees Celsius, preferably below zero degrees Celsius, and further preferably below minus 5 degrees Celsius.
Preferably the composition contains a minimum of, an amount equal to, or at least 10% cork and/or rubber particles.
Preferably reference to cork and/or rubber particles can include cork and/or rubber granules, bits, aggregates and/or the like thereof Further preferably the composition contains between approximately 10%-80% cork and/or rubber particles by weight or volume of the composition. The amount of cork and/or rubber particles can be adjusted to achieve a desired composition and/or surface texture in use, to have desired performance characteristics, such as viscosity, breathability, waterproofing, and/or the like.
Preferably the cork particles consists only of cork.
Preferably the rubber particles consist of or iclude recycled rubber, such as for example recycled car tyres and/or the like.
Preferably the cork and/or rubber particles have an average diameter of 0-5mm, or less than or equal to 5rum, further preferably 0-4mm, or less than or equal to Preferably the granule size or average diameter of the cork and/or rubber particles can be adjusted in different compositions to provide compositions with different textured finishes when applied to a surface in use.
Preferably the cork and/or rubber particles have an average diameter equal to or less than 5 fines, and further preferably equal to or less than 4 fines.
Preferably the provision of the cork and/or rubber particles reduces the viscosity or stickiness of the composition, thereby allowing the composition to be more easily applied to a surface in use, such as for example to a masonry surface.
In one embodiment the composition is provided as a wall, masonry, construction board or panel and/or surface coating composition.
In one embodiment a. construction panel or board is provided with at least one layer of the composition provided on at least one exterior surface of the construction panel (Jr board. The construction panel or board can include any single layer, multi-layered or laminate panel or board, such a.s for example, including plasterboard, fire-retardant board material, sound proof board material, insulation board material and/or the like.
In one embodiment the composition includes one or more colourants. The colourants typically provide the composition with a desired or user selected colour.
Preferably the one (Jr more colourants include (Jr consist of a titanium dioxide colourant.
In one embodiment a further solvent or thinning agent is included in the composition. For example, the further solvent or thinning agent can be used to reduce the viscosity of the composition.
In one embodiment between 0-10% by volume or weight of the total composition of the further solvent or thinning agent can be added to the composition.
In one example the further solvent or thinning agent could include or consist of any or any combination of White Spirit, mineral spirit, mineral turpentine or petroleum hydro carbon (s) Preferably the one or more colourants and/or further solvent or thinning agent are mixed into the composition to form a homogenous or substantially homogenous mixture.
Preferably the cork and/or rubber particles, the carrier agent, and optionally the one or more colourants and/or further solvent or tluimthg agent are mixed together at room temperature (i.e. 20-22 degrees centigrade) and pressure (i.e. 1bar or 100KIPa).
in one example, the composition is pressurised prior to application onto a surface to provide the surface coating. For example, in a spray application, the composition could be pressurised to 136 bar or 2000psi.
in one embodiment the surface coating composition is applied at a thickness of approximately 4mm, but this will typically depend on the size of the rubber and/or cork particles used in the composition Preferably the cork particles is or includes natural cork.
Preferably the components of the composition can be mixed using any conventional mixing device, such as a paddle-based mixer and/or the In one embodiment, the composition consists of cork and/or rubber particles, a solvent based resin and optionally one or more colourants and/or thinning agent.
Preferably die composition is applied to a surface, masonry surface, construction panel or board surface, brick surface, construction block surface, stone surface and/or the like in use.
In one embodiment the composition can be used as an anti-carbonation coating, such as for example to protect concrete structures against carbon dioxide damage.
According to one aspect of the present invention there is provided a wall coating composition and/or method of use thereof.
According to one aspect of the present invention there is provided a construction panel including a wall coating composition and/or a method of use thereof According to one aspect of the present invention there is provided a method of manufacturing a composition suitable for a surface coating, said method including mixing cork and/or rubber particles with a carrier agent, wherein the carrier agent is a solvent based resin.
According to one aspect of the present invention there is provided a method of using a composition, said composition including cork and/or rubber particles and a carrier agent, and wherein the carrier agent is a solvent based resin, said method includes the step of applying the composition to a surface, masonry surface, construction panel or board surface, brick surface, construction block surface, stone surface and/or the like.
The advantages of the composition of the present invention are that it can be applied to a surface, such as masonry, brick, construction block or stone surface using any conventional tools, such as a trowel. A trowel can also be used to provide a traditional render or stucco finish to the masonry, brick, construction block or stone. The composition is touch dry in less than 30 minutes after it has been applied to a surface and is waterproof within 20 minutes. It can be used and applied at low temperatures, such as below zero degrees Celsius. It provides a relatively flexible and crack resistant finish.
A detailed example of a composition according to an embodiment of the present invention is provided in I)xample 1 below: Example 1 Composition Cork and/or rubber granules -60% by weight of total composition Pre-pigmented Pliolite° carrier agent-40% by weight of total composition Method of Manufacture of Example 1 Composition I. Firstly, the solvent based resin, which in this example is a pre-pigmented Pliolite0 agent, is measured out in a mixing receptacle, such as for example a drum paint mixer 7. The cork and/or rubber granules are then measured out and mixed into the mixing receptacle with the solvent based resin. This takes place at room temperature (for example, 20-22 degrees Celsius) and pressure (for example, 1 bar or 100K Pa).
3. The mixture is stirred continuously until a homogenous or substantially homogenous mixture is formed.
4. 't he mixture can then optionally be dispensed into smaller containers for transport, storage and/or application onto a suitable surface.

Claims (24)

  1. Claims 1. A composition for use as a surface coating, said composition including cork and/or rubber particles and a carrier agent, and wherein the carrier agent is a solvent based resin.
  2. 2. A composition according to claim 1, wherein the cork and/or rubber particles form a homogenous or substantially homogenous mixture with the carrier agent, with the cork and/or rubber particles suspended in the carrier agent.
  3. 3. A composition according to claim 1, wherein the composition is in liquid and/or pourable form prior to use.
  4. 4. A composition according to any preceding claim, wherein the solvent based resin is or includes any or any combination of a styrene acrylic resin, a styrene butadine rubber resin, an acrylated rubber resin, a solvent based rubber resin or a solvent based synthetic rubber resin.
  5. 5. A composition according to any preceding claim, wherein the solvent based resin is a Phobic® solvent based resin.
  6. 6. A composition according to claim 5, wherein the solvent based resin is any or any combination of Sandtex Pliolite 365®, Wethertex Pholite°, Johnstones Pliolite0, Duhtx Phobic° or Leyland Plio
  7. 7. A composition according to any preceding claim, wherein the composition is non-aqueous.
  8. 8. A composition according to any preceding claim, wherein the composition is formed such that on application to a surface is forms a microporous film on the surface.
  9. 9. A composition according to any preceding claim, wherein the composition is formed such that it can be applied to surfaces and/or used in air. temperatures below five degrees Celsius, below zero degrees Celsius and/or below minus five degrees Celsius.
  10. 10.A composition according to any preceding claim, wherein the composition con-fulls a mthnnum of, an amount equal to, or at least 10% cork and/or rubber particles.
  11. 11.A composition according to claim 10, wherein the composition contains between approximately 10-80% by weight or volume of cork and/or rubber particles.
  12. 12.A composition according to any preceding claim, wherein the cork and/or rubber particles includes any or any combination of cork and/or rubber granules, bits or aggregates.
  13. 13. A composition according to any preceding claim;Therein the cork particles consist only of cork.
  14. 14. A composition according to any preceding claim, wherein the rubber particles consist of or include recycled rubber.
  15. 15. A composition according to any preceding claim, wherein the cork and/or rubber particles have an average diameter of 0-5mm, less than or equal to 5nun, 0-4nun, or less than or equal to 4min
  16. 16.A composition according to any of claims 1-14, wherein the cork and/or rubber particles have an average diameter equal to or less than 5 fines, or equal to or less than 4 fines.
  17. 17.A composition according to any preceding claim, wherein the composition is any or any combination of a wall surface coating composition, a masonry surface coating composition, a construction board surface coating composition, a panel surface coating composition.
  18. 18.A composition according to any preceding claim, wherein t le composition includes one or more colourants.
  19. 19.A composition according to claim IS, wherein the one or more colourants include or consist of a titanium dioxide colourant.
  20. 20.A composition according to any preceding claim, wherein the composition includes a further solvent or thinning agent.
  21. 21. A composition according to any preceding claim, wherein the further solvent or thinning agent includes or consists of any or any combination of white spirit, petroleum spirit, mineral spirit, mineral turpentine, or petroleum hydrocarbon (s).
  22. 22. A construction panel or board including at least one layer of the composition according to claim 1 provided on an exterior surface of the construction panel or board.
  23. 23. A method of manufacturing a composition for use a.s a surface coating, said method including the step of mixing cork and/or rubber particles with a carrier agent, and wherein the carrier agent is a solvent based resin.
  24. 24. The method according to claim 23, wherein the cork and/or rubber particles are mixed with the carrier agent at room temperature and/or pressure.25. the method according to claim 23, wherein the method includes the step of mixing one or more colourants and/of further solvent or thinning agent in the composition.
GB2017684.8A 2019-11-20 2020-11-10 Composition for use as a surface and method of use and/or manufacture thereof Withdrawn GB2590184A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB1916876.4A GB201916876D0 (en) 2019-11-20 2019-11-20 Surface coating composition and method of use thereof

Publications (2)

Publication Number Publication Date
GB202017684D0 GB202017684D0 (en) 2020-12-23
GB2590184A true GB2590184A (en) 2021-06-23

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GB2017684.8A Withdrawn GB2590184A (en) 2019-11-20 2020-11-10 Composition for use as a surface and method of use and/or manufacture thereof

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2007684A (en) * 1977-11-14 1979-05-23 Basf Farben & Fasern Coating agent
JP2004202483A (en) * 2002-08-30 2004-07-22 Sk Kaken Co Ltd Method for forming coating film for interior finishing of building
CN104877505A (en) * 2015-06-15 2015-09-02 合肥启华环保科技有限公司 Anti-ultraviolet external wall insulation latex paint and preparation method thereof
CN106047152A (en) * 2016-06-29 2016-10-26 明光市阳光木业有限公司 Thermal-insulation paint for high-density boards
CN108841281A (en) * 2018-06-26 2018-11-20 国网湖南省电力有限公司 The preparation method of rubber industry wastewater powder modified fluoride-containing acrylate polymer coating
CN109504282A (en) * 2018-12-05 2019-03-22 湖南松井新材料股份有限公司 A kind of anti-pollution type hand-feeling coating and its preparation method and application
CN109929419A (en) * 2017-12-18 2019-06-25 南京苏五道信息科技有限公司 A kind of rubber coating factory formula

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2007684A (en) * 1977-11-14 1979-05-23 Basf Farben & Fasern Coating agent
JP2004202483A (en) * 2002-08-30 2004-07-22 Sk Kaken Co Ltd Method for forming coating film for interior finishing of building
CN104877505A (en) * 2015-06-15 2015-09-02 合肥启华环保科技有限公司 Anti-ultraviolet external wall insulation latex paint and preparation method thereof
CN106047152A (en) * 2016-06-29 2016-10-26 明光市阳光木业有限公司 Thermal-insulation paint for high-density boards
CN109929419A (en) * 2017-12-18 2019-06-25 南京苏五道信息科技有限公司 A kind of rubber coating factory formula
CN108841281A (en) * 2018-06-26 2018-11-20 国网湖南省电力有限公司 The preparation method of rubber industry wastewater powder modified fluoride-containing acrylate polymer coating
CN109504282A (en) * 2018-12-05 2019-03-22 湖南松井新材料股份有限公司 A kind of anti-pollution type hand-feeling coating and its preparation method and application

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GB201916876D0 (en) 2020-01-01
GB202017684D0 (en) 2020-12-23

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