GB2567692A - Composition for use as a toiletry - Google Patents

Composition for use as a toiletry Download PDF

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Publication number
GB2567692A
GB2567692A GB1717381.6A GB201717381A GB2567692A GB 2567692 A GB2567692 A GB 2567692A GB 201717381 A GB201717381 A GB 201717381A GB 2567692 A GB2567692 A GB 2567692A
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GB
United Kingdom
Prior art keywords
composition according
composition
polymer blend
hydrocolloid
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB1717381.6A
Other versions
GB201717381D0 (en
Inventor
Chaparadza Wellington
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB1717381.6A priority Critical patent/GB2567692A/en
Publication of GB201717381D0 publication Critical patent/GB201717381D0/en
Publication of GB2567692A publication Critical patent/GB2567692A/en
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

A composition is provided for use as a toiletry. The composition comprises: a polymer blend; a hydrocolloid; and water. Preferably the polymer blend contains at least two polymers and at least one cationic polymer. More preferably the cationic polymer is an acrylic homopolymer and a cellulose derivative. Preferably the hydrocolloid is natural gum, more preferably a guar derivative. In an embodiment, the polymer blend comprises polyquaternium 37, propylene dicaprylate/dicaprate, hydroxy ethyl cellulose and PPG-1 trideceth 6. In the same embodiment, the hydrocolloid is guar hydroxypropyltrimonium chloride and the composition is used as a conditioner. Surfactants, additional conditioning agents, perfumes, chelating agents, emulsifiers and preservatives may also be included.

Description

Examples of the disclosure relate to a composition for use as a toiletry.
BACKGROUND
Compositions for use as toiletries, such as shampoos, conditioners, and cleansers are known. There are growing concerns regarding ingredients used in compositions used as toiletries, particularly as such compositions are used directly on the hair and/or skin. In some instances, known compositions, and particularly compositions which do not comprise sulphates, include thickeners such as cocamide diethanolamine, which is an irritant and carcinogen.
Accordingly, there is a requirement to provide compositions for use as toiletries which are free from chemicals which may have negative health consequences, but which also retain properties expected by a user, for instance, in terms of cleaning and conditioning the skin and/or hair.
All proportions referred to in this specification are indicated as weight % of the total composition.
BRIEF SUMMARY
According to various, but not necessarily all, examples of the disclosure there is provided a composition for use as a toiletry, the composition comprising:
(a) a polymer blend;
(b) a hydrocolloid; and (c) water.
The polymer blend may comprise a cationic polymer. The polymer blend may comprise a mixture of at least two different polymers. The polymer blend may comprise a cationic acrylic homopolymer and a cellulose derivative dispersed in a carrier oil. The polymer blend may comprise a mixture of polyquaternium 37, propylene glycol dicaprylate/dicaprate, hydroxyl ethyl cellulose, and PPG-1 trideceth
6. The polymer blend may comprise 30 to 50 weight % polyquaternium 37, 30 to 50 weight % propylene glycol dicaprylate/dicaprate, 25 to 40 weight % hydroxyl ethyl cellulose, and 2 to 10 weight % PPG-1 trideceth 6.
The composition may comprise 0.001 to 5 weight % of polymer blend, and may comprise 0.1 to 1 weight % of polymer blend, and may comprise 0.2 to 0.7 weight % of polymer blend.
The hydrocolloid may comprise a natural gum. The natural gum may comprise guar gum, and may comprise quartenized guar gum, which may be guar hydroxpropyltrimonium chloride. The natural gum may comprise guar gum and xantham gum. The ratio of guar gum to xantham gum may be 2:8.
The composition may comprise 0.01 to 2 weight % of hydrocolloid, and may comprise 0.1 to 1.5 weight % of hydrocolloid, and may comprise 0.4 to 1.1 weight % of hydrocolloid.
The ratio of polymer blend to hydrocolloid may be 5:1 to 1:5, and may be 3:1 to 1:3, and may be 2:1 to 1:2, and may be 1:1 to 1:3, and may be 1:1.
The composition may comprise 45 to 98 weight % of water, and may comprise 65 to 98 weight % of water, and may comprise 75 to 96 weight % of water.
The composition may comprise a surfactant system. The surfactant system may comprise a surfactant and a co-surfactant. The surfactant may comprise any of: non-ionic surfactant, cationic surfactant, anionic surfactant or amphoteric surfactant. The surfactant may comprise at least two different surfactants. The surfactant may comprise any of: decyl polyglucoside or sodium olivoyl glutamate.
The co-surfactant may comprise cocamidopropyl betaine.
Alternatively, the composition may comprise an emulsifier. The emulsifier may comprise at least two different emulsifiers. The emulsifier may comprise any of: cetearyl alcohol or cetyl alcohol.
Alternatively, the composition may not comprise a surfactant system or an emulsifier.
The composition may comprise 5 to 40 weight % of surfactant, and may comprise 8 to 30 weight % of surfactant, and may comprise 10 to 25 weight % of surfactant. The composition may comprise 0.5 to 15 weight % of co-surfactant, and may comprise 1 to 10 weight % of co-surfactant, and may comprise 1.5 to 7 weight % of co-surfactant.
The composition may comprise 0.3 to 7 weight % of emulsifier, and may comprise 1 to 5 weight % of emulsifier, and may comprise 2 to 4 weight % of emulsifier.
The composition may comprise a conditioning agent. The conditioning agent may comprise a plurality of different conditioning agents. The composition may comprise 0.1 to 10 weight % of conditioning agent, and may comprise 0.3 to 8 weight % of conditioning agent, and may comprise 0.4 to 5 weight % of conditioning agent. In some examples, the composition may comprise 0.1 to 2 weight % of conditioning agent, and may comprise 0.3 to 1.0 weight % of conditioning agent, and may comprise 0.4 to 0.7 weight % of conditioning agent. In other examples, the composition may comprise 1 to 10 weight % of conditioning agent, and may comprise 2 to 8 weight % of conditioning agent, and may comprise 3 to 5 weight % of conditioning agent.
The composition may comprise a perfume. The composition may comprise 0.005 to 0.5 weight % of perfume, and may comprise 0.01 to 0.1 weight % of perfume, and may comprise 0.02 to 0.05 weight % of perfume.
The composition may comprise a preservative. The composition may comprise 0.005 to 1.0 weight % of preservative, and may comprise 0.01 to 0.1 weight % of preservative, and may comprise 0.02 to 0.08 weight % of preservative.
The composition may comprise a chelating agent. The composition may comprise 0.005 to 0.5 weight % of chelating agent, and may comprise 0.01 to 0.1 weight % of chelating agent, and may comprise 0.02 to 0.05 weight % of chelating agent. The chelating agent may be EDTA.
The composition may consist of just the components specified in any of the above paragraphs.
According to various, but not necessarily all, examples of the disclosure there is provided a method of providing a composition for use as a toiletry, the method comprising mixing:
(a) a polymer blend;
(b) a hydrocolloid; and (c) water.
According to various, but not necessarily all, examples of the disclosure there is provided a shampoo, the shampoo comprising the composition of any of the above paragraphs.
The shampoo may consist of the composition of any of the above paragraphs.
According to various, but not necessarily all, examples of the disclosure there is provided a conditioner, the conditioner comprising the composition of any of the above paragraphs.
The conditioner may consist of the composition of any of the above paragraphs.
According to various, but not necessarily all, examples of the disclosure there may be provided examples as claimed in the appended claims.
BRIEF DESCRIPTION
For a better understanding of various examples that are useful for understanding the detailed description, reference will now be made by way of example only.
DETAILED DESCRIPTION
Examples of compositions according to the disclosure are provided in the tables below. Table 2 provides more detail regarding the specific components listed in broader terms in table 1.
Table 1
Component Example 1 (wt%) Example 2 (wt%) Example 3 (wt%) Example 4 (wt%) Example 5 (wt%)
Polymer blend 0.5 0.5 0.25 0.3 0.4
Hydrocolloid 0.5 1.0 0.75 0.6 0.8
Surfactant 12 20 20 0 0
Co-surfactant 5 2 2 0 0
Emulsifier 0 0 0 3 0
Preservative 0.05 0.05 0.05 0.05 0.05
Conditioning agent 0.5 0.5 0.5 4 3.05
Chelating agent 0 0 0 0.03 0
Perfume 0 0 0 0.03 0
Water 81.45 75.95 76.45 91.99 95.50
Table 2
Component Specific component Example 1 (wt%) Example 2 (wt%) Example 3 (wt%) Example 4 (wt%) Example 5 (wt%)
Polymer blend Polymer blend* 0.5 0.5 0.25 0.3 0.4
Hydrocolloid Guar hydroxpropyltrimonium chloride 0.5 1.0 0.75 0.6 0.8
Surfactant Decyl polyglucoside 12 0 20 0 0
Sodium olivoyl glutamate 0 20 0 0 0
Co- Cocamidopropyl betaine 5 2 2 0 0
surfactant
Emulsifier Cetearyl alcohol 0 0 0 2.4 0
Cetyl alcohol 0 0 0 0.6 0
Preservative Kathon CG 0.05 0.05 0.05 0 0
Methylchloroisothiazolinone 0 0 0 0.05 0.05
Conditioning agent Argan oil 0.1 0 0.1 0 0.05
Shea butter 0.1 0 0 0 0
Aloe vera 0.2 0.2 0.2 0 0
Glycerin 0.1 0.1 0.1 0 0
Meadowfoam oil 0 0.1 0 0 0
Olive oil 0 0.1 0.1 0 0
Cetrimonium chloride 0 0 0 2.0 0
Stearalkonium chloride 0 0 0 2.0 0
Behentrimonium chloride 0 0 0 0 1
Coconut oil 0 0 0 0 2
Chelating agent EDTA 0 0 0 0.03 0
Perfume Perfume 0 0 0 0.03 0
Water Water 81.45 75.95 76.45 91.99 95.50
*The Polymer blend in the above examples is a mixture of 30 to 50 weight % polyquaternium 37, 30 to 50 weight % propylene glycol dicaprylate/dicaprate, 25 to 40 weight % hydroxyl ethyl cellulose, and 2 to 10 weight % PPG-1 trideceth 6. PPG5 1 trideceth 6 is polyoxypropylen(l) polyoxyethylen(l) tridecylether.
In examples of the present disclosure, the polymer composition acts as a viscosifier and an emulsion stabiliser.
The ratio of polymer blend to hydrocolloid in example 1 is 1:1. The ratio of polymer blend to hydrocolloid in example 2 is 1:2. The ratio of polymer blend to hydrocolloid in example 3 is 1:3. The ratio of polymer blend to hydrocolloid in example 4 is 1:2. The ratio of polymer blend to hydrocolloid in example 5 is 1:2.
The above ratios of polymer blend to hydrocolloid have been found to effectively thicken the composition whilst providing excellent conditioning of the hair and skin, and particularly when in a ratio of 1:1. Accordingly, the use of potentially harmful thickeners, such as cocamide diethanolamine, or other thickeners such as sodium chloride, is avoided. The use of sulphates is also avoided, such that the compositions according to the disclosure are free of sulphates.
In some examples, the conditioning agent may be a fruit and/or vegetable extract.
In some examples of the disclosure, for instance, examples 1 to 3 above, the composition may optimally provide a shampoo.
In other examples of the disclosure, for instance, examples 4 and 5 above, the composition may optimally provide a conditioner. The conditioner may be of the type which is subsequently rinsed off, or left on, or sprayed.
In other examples of the disclosure the composition may optimally provide a shampoo and conditioner.
Examples of the disclosure also provide a method of providing the composition wherein the components, for instance, the components in any of examples 1 to 5 are mixed together to provide a composition according to examples of the disclosure.
There is thus described a composition for use as a toiletry with a number of advantages as described above, and as follows.
In examples where the composition optimally provides a shampoo, the composition cleanses and conditions the hair, softens the hair, soothes the scalp and greatly improves hair manageability and ease of combing. Furthermore, the composition provides a rich and creamy foam, which is a desirable quality.
In examples where the composition optimally provides a conditioner, hair treated with the conditioner is left smooth, shiny, manageable, easily combed and moisturised.
The composition according to examples of the disclosure is suitable for use on the hair and/or skin.
The composition according to examples of the disclosure is stable, and shows no tendency to phase separate over an extended period of time.
The composition according to examples of the disclosure comprises fewer components than known compositions which are used as shampoos and/or conditioners, and is thus less expensive to manufacture. Furthermore, the composition is free of irritants and other chemicals which may damage the hair and/or skin, and is thus suitable for sensitive skin.
The composition according to examples of the disclosure has excellent conditioning properties and is therefore particularly suitable for African-Caribbean hair.
Although embodiments of the present invention have been described in the preceding paragraphs with reference to various examples, it should be appreciated that modifications to the examples given can be made without departing from the scope of the invention as claimed.
Features described in the preceding description may be used in combinations other than the combinations explicitly described.
Although functions have been described with reference to certain features, those functions may be performable by other features whether described or not.
Although features have been described with reference to certain embodiments, those features may also be present in other embodiments whether described or not.
The term “comprise” is used in this document with an inclusive not an exclusive meaning. That is any reference to X comprising Y indicates that X may comprise only one Y or may comprise more than one Y. If it is intended to use “comprise” with an exclusive meaning then it will be made clear in the context by referring to “comprising only one...” or by using “consisting”.
In this brief description, reference has been made to various examples. The description of features or functions in relation to an example indicates that those features or functions are present in that example. The use of the term “example” or “for example” or “may” in the text denotes, whether explicitly stated or not, that such features or functions are present in at least the described example, whether described as an example or not, and that they can be, but are not necessarily, present in some of or all other examples. Thus “example”, “for example” or “may” refers to a particular instance in a class of examples. A property of the instance can be a property of only that instance or a property of the class or a property of a subclass of the class that includes some but not all of the instances in the class. It is therefore implicitly disclosed that a features described with reference to one example but not with reference to another example, can where possible be used in that other example but does not necessarily have to be used in that other example.
Whilst endeavoring in the foregoing specification to draw attention to those features of the invention believed to be of particular importance it should be understood that the Applicant claims protection in respect of any patentable feature or combination of features hereinbefore referred to and/or shown in the drawings whether or not particular emphasis has been placed thereon.

Claims (26)

1. A composition for use as a toiletry, the composition comprising:
(a) a polymer blend;
(b) a hydrocolloid; and (c) water.
2. A composition according to claim 1, in which the polymer blend comprises a cationic polymer.
3. A composition according to claims 1 or 2, in which the polymer blend comprises a mixture of at least two different polymers.
4. A composition according to any of the preceding claims, in which the polymer blend comprises a cationic acrylic homopolymer and a cellulose derivative dispersed in a carrier oil.
5. A composition according to any of the preceding claims, in which the polymer blend comprises a mixture of polyquaternium 37, propylene glycol dicaprylate/dicaprate, hydroxyl ethyl cellulose, and PPG-1 trideceth 6.
6. A composition according to any of the preceding claims, in which the polymer blend comprised 30 to 50 weight % polyquaternium 37, 30 to 50 weight % propylene glycol dicaprylate/dicaprate, 25 to 40 weight % hydroxyl ethyl cellulose, and 2 to 10 weight % PPG-1 trideceth 6.
7. A composition according to any of the preceding claims, in which the hydrocolloid comprises a natural gum.
8. A composition according to claim 7, in which the natural gum is guar hydroxpropyltrimonium chloride.
9. A composition according to any of the preceding claims, in which the ratio of polymer blend to hydrocolloid is 5:1 to 1:5.
10. A composition according to any of the preceding claims, in which the ratio of polymer blend to hydrocolloid is 3:1 to 1:3.
11. A composition according to any of the preceding claims, in which the ratio of polymer blend to hydrocolloid is 2:1 to 1:2,
12. A composition according to any of the preceding claims, in which the ratio of polymer blend to hydrocolloid is 1:1 to 1:3,
13. A composition according to any of the preceding claims, in which the ratio of polymer blend to hydrocolloid is 1:1.
14. A composition according to any of the preceding claims, in which the composition comprises a surfactant system.
15. A composition according to claim 14, in which the surfactant system comprise a surfactant and a co-surfactant.
16. A composition according to any of claims 1 to 13, in which the composition comprises an emulsifier.
17. A composition according to claim 16, in which the emulsifier comprises at least two different emulsifiers.
18. A composition according to any of claims 1 to 13, in which the composition does not comprise a surfactant system or an emulsifier.
19. A composition according to any of the preceding claims, in which the composition comprises a conditioning agent.
20. A composition according to claim 19, in which the conditioning agent comprises a plurality of different conditioning agents.
21. A composition according to any of the preceding claims, in which the composition comprises a perfume.
22. A composition according to any of the preceding claims, in which the composition comprises a preservative.
23. A composition according to any of the preceding claims, in which the composition comprises a chelating agent.
24. A method of providing a composition for use as a toiletry, the method comprising mixing:
(d) a polymer blend;
(e) a hydrocolloid; and (f) water.
25. A shampoo, the shampoo comprising the composition according to any of the above claims.
26. A conditioner, the conditioner comprising the composition according to any of the above claims.
GB1717381.6A 2017-10-23 2017-10-23 Composition for use as a toiletry Withdrawn GB2567692A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1717381.6A GB2567692A (en) 2017-10-23 2017-10-23 Composition for use as a toiletry

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1717381.6A GB2567692A (en) 2017-10-23 2017-10-23 Composition for use as a toiletry

Publications (2)

Publication Number Publication Date
GB201717381D0 GB201717381D0 (en) 2017-12-06
GB2567692A true GB2567692A (en) 2019-04-24

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001076543A1 (en) * 2000-04-05 2001-10-18 The Procter & Gamble Company Hair conditioning composition comprising a thickening system
WO2009030614A1 (en) * 2007-09-05 2009-03-12 Basf Se Personal care compositions comprising dye-polymer complexes
WO2012025615A2 (en) * 2010-08-27 2012-03-01 Colomer Beauty And Professional Products, S.L. Process and kit for treating hair
DE102011089357A1 (en) * 2011-12-21 2012-08-23 Henkel Ag & Co. Kgaa Hair treatment agent useful for hair care, comprises four different quaternary ammonium compounds comprising e.g. quaternary imidazoline compounds, cationic keratin hydrolyzate, alpha-hydroxy acid, and ethanol or isopropanol
US20170333734A1 (en) * 2014-11-13 2017-11-23 Basf Se Shampoos and conditioners having a conditioning effect

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001076543A1 (en) * 2000-04-05 2001-10-18 The Procter & Gamble Company Hair conditioning composition comprising a thickening system
WO2009030614A1 (en) * 2007-09-05 2009-03-12 Basf Se Personal care compositions comprising dye-polymer complexes
WO2012025615A2 (en) * 2010-08-27 2012-03-01 Colomer Beauty And Professional Products, S.L. Process and kit for treating hair
DE102011089357A1 (en) * 2011-12-21 2012-08-23 Henkel Ag & Co. Kgaa Hair treatment agent useful for hair care, comprises four different quaternary ammonium compounds comprising e.g. quaternary imidazoline compounds, cationic keratin hydrolyzate, alpha-hydroxy acid, and ethanol or isopropanol
US20170333734A1 (en) * 2014-11-13 2017-11-23 Basf Se Shampoos and conditioners having a conditioning effect

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