GB2532677A - Lithium-sulfur electric current producing cell - Google Patents

Lithium-sulfur electric current producing cell Download PDF

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Publication number
GB2532677A
GB2532677A GB1603651.9A GB201603651A GB2532677A GB 2532677 A GB2532677 A GB 2532677A GB 201603651 A GB201603651 A GB 201603651A GB 2532677 A GB2532677 A GB 2532677A
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GB
United Kingdom
Prior art keywords
lithium
electric current
producing cell
sulfur
current producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB1603651.9A
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GB201603651D0 (en
Inventor
Musameh Mustafa
Best Adam
Ruether Thomas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commonwealth Scientific and Industrial Research Organization CSIRO
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Commonwealth Scientific and Industrial Research Organization CSIRO
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Filing date
Publication date
Priority claimed from AU2013903291A external-priority patent/AU2013903291A0/en
Application filed by Commonwealth Scientific and Industrial Research Organization CSIRO filed Critical Commonwealth Scientific and Industrial Research Organization CSIRO
Publication of GB201603651D0 publication Critical patent/GB201603651D0/en
Publication of GB2532677A publication Critical patent/GB2532677A/en
Withdrawn legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/604—Polymers containing aliphatic main chain polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0045—Room temperature molten salts comprising at least one organic ion
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

The invention provides a lithium-sulfur electric current producing cell comprising an anode; electrolyte; and cathode, where the cathode comprises a polymer-sulfur composite comprising: 5 to 80 wt% sulfur; 0 to 90 wt% conductive polymer; 0 to 50 wt% of one or more conductive agents, other than the conductive polymer; and 0.5 to 20 wt% a first dopant comprising a negatively charged organic polymer; wherein the conductive polymer is doped with the first dopant.
GB1603651.9A 2013-08-29 2014-08-29 Lithium-sulfur electric current producing cell Withdrawn GB2532677A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AU2013903291A AU2013903291A0 (en) 2013-08-29 Lithium sulphur electric current producing cell
PCT/AU2014/000862 WO2014176644A2 (en) 2013-08-29 2014-08-29 Lithium-sulfur electric current producing cell

Publications (2)

Publication Number Publication Date
GB201603651D0 GB201603651D0 (en) 2016-04-13
GB2532677A true GB2532677A (en) 2016-05-25

Family

ID=51844024

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1603651.9A Withdrawn GB2532677A (en) 2013-08-29 2014-08-29 Lithium-sulfur electric current producing cell

Country Status (6)

Country Link
US (1) US20160218352A1 (en)
KR (1) KR20160078334A (en)
CN (1) CN105745778B (en)
AU (1) AU2014262137B2 (en)
GB (1) GB2532677A (en)
WO (1) WO2014176644A2 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170047581A1 (en) * 2014-02-11 2017-02-16 Batelle Memorial Institute Additives to enhance electrode wetting and performance and methods of making electrodes comprising the same
DE102014221736A1 (en) * 2014-10-24 2016-04-28 Robert Bosch Gmbh Polymer electrolyte for lithium-sulfur cell
US10601031B2 (en) 2014-06-06 2020-03-24 Robert Bosch Gmbh Polymer electrolyte for a lithium sulfur cell
US20160118685A1 (en) * 2014-10-24 2016-04-28 Battelle Memorial Institute Methods and compositions for lithium ion batteries
FR3030122B1 (en) * 2014-12-10 2017-01-13 Blue Solutions ORGANIC LITHIUM BATTERY
WO2017090231A1 (en) * 2015-11-27 2017-06-01 パナソニックＩｐマネジメント株式会社 Electrochemical device and method for manufacturing same
JP6385486B2 (en) * 2016-03-11 2018-09-05 東京電力ホールディングス株式会社 POSITIVE MATERIAL FOR SOLID BATTERY AND METHOD FOR MANUFACTURING THE SAME
US10084182B2 (en) * 2017-02-23 2018-09-25 Nanotek Instruments, Inc. Alkali metal-sulfur secondary battery containing a protected sulfur cathode and manufacturing method
US10411264B2 (en) * 2017-02-27 2019-09-10 Global Graphene Group, Inc. Cathode active material layer for lithium secondary battery and method of manufacturing
US10804567B2 (en) 2017-05-11 2020-10-13 Korea Institute Of Science And Technology Electrolyte system for lithium metal secondary battery and lithium metal secondary battery including the same
KR20180124697A (en) 2017-05-11 2018-11-21 한국과학기술연구원 Electrolyte system and lithium metal battery comprising the same
US11239466B2 (en) * 2018-01-09 2022-02-01 Saudi Arabian Oil Company Nanocomposite cathode materials for use in batteries
US10547059B2 (en) 2018-02-21 2020-01-28 Duracell U.S. Operations, Inc. Sulfate and sulfonate based surfactants for alkaline battery anode
WO2019217616A1 (en) * 2018-05-09 2019-11-14 Sabic Global Technologies B.V. Polyelectrolyte encapsulated sulfur particles and their preparation and use
KR20200142897A (en) * 2019-06-14 2020-12-23 주식회사 엘지화학 Sulfur-carbon composite, positive electrode for lithium secondary battery and lithium secondary battery comprising the same
CN110148748B (en) * 2019-06-19 2022-08-19 哈尔滨理工大学 Preparation method of soybean protein isolate-based high-rate lithium-sulfur battery cathode carbon material
JP2021021025A (en) * 2019-07-29 2021-02-18 国立大学法人東京農工大学 Method for producing conductive porous body and method for producing thermoelectric conversion member
CN111370754A (en) * 2020-03-16 2020-07-03 浙江大学 Preparation method of ultrathin electrolyte film and all-solid-state battery

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6110619A (en) * 1997-12-19 2000-08-29 Moltech Corporation Electrochemical cells with cationic polymers and electroactive sulfur compounds
US20130040197A1 (en) * 2011-08-08 2013-02-14 Battelle Memorial Institute Polymer-Sulfur Composite Materials for Electrodes in Li-S Energy Storage Devices
US20130164615A1 (en) * 2011-12-22 2013-06-27 Arumugam Manthiram Conductive polymer-coated, shaped sulfur-nanocomposite cathodes for rechargeable lithium-sulfur batteries and methods of making the same

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JPH01132052A (en) * 1987-08-10 1989-05-24 Nitto Denko Corp Conductive organic polymer battery
CN101789519B (en) * 2010-01-25 2014-06-04 北京理工大学 Ionic liquid-based composite electrolyte
CN103000934B (en) * 2011-09-16 2016-03-30 苏州宝时得电动工具有限公司 Lithium-sulfur cell

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6110619A (en) * 1997-12-19 2000-08-29 Moltech Corporation Electrochemical cells with cationic polymers and electroactive sulfur compounds
US20130040197A1 (en) * 2011-08-08 2013-02-14 Battelle Memorial Institute Polymer-Sulfur Composite Materials for Electrodes in Li-S Energy Storage Devices
US20130164615A1 (en) * 2011-12-22 2013-06-27 Arumugam Manthiram Conductive polymer-coated, shaped sulfur-nanocomposite cathodes for rechargeable lithium-sulfur batteries and methods of making the same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Chemistry of Materials, 2012, vol 24, Iss 15, FU, YONGZHU et al, "Enhanced Cyclability of Lithium-Sulfur Batteries by a Polymer Acid-Doped Polypyrrole Mixed Ionic-Electronic Conductor", Pages 3081-3087 *
Journal of Power Sources, 2 August 2013, vol 246, TANG, QIWEI et al, "Nafion coated sulfur-carbon electrode for high performance lithium-sulfur batteries", pages 253-259 *

Also Published As

Publication number Publication date
WO2014176644A3 (en) 2015-01-22
GB201603651D0 (en) 2016-04-13
CN105745778A (en) 2016-07-06
AU2014262137A1 (en) 2016-03-17
CN105745778B (en) 2019-06-28
KR20160078334A (en) 2016-07-04
US20160218352A1 (en) 2016-07-28
WO2014176644A9 (en) 2015-02-19
WO2014176644A2 (en) 2014-11-06
AU2014262137B2 (en) 2018-08-02

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