GB2496309A - Marbled glass and a method of making marbled glass - Google Patents

Marbled glass and a method of making marbled glass Download PDF

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Publication number
GB2496309A
GB2496309A GB1219630.9A GB201219630A GB2496309A GB 2496309 A GB2496309 A GB 2496309A GB 201219630 A GB201219630 A GB 201219630A GB 2496309 A GB2496309 A GB 2496309A
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GB
United Kingdom
Prior art keywords
paint
text
glass
liquid
marbled
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Withdrawn
Application number
GB1219630.9A
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GB201219630D0 (en
Inventor
Sarah Holliday
Michael Phipps
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Individual
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Individual
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Publication of GB201219630D0 publication Critical patent/GB201219630D0/en
Publication of GB2496309A publication Critical patent/GB2496309A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/065Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects having colour interferences or colour shifts or opalescent looking, flip-flop, two tones
    • B05D5/066Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects having colour interferences or colour shifts or opalescent looking, flip-flop, two tones achieved by multilayers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3405Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • B05D1/20Processes for applying liquids or other fluent materials performed by dipping substances to be applied floating on a fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10247Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • B44F9/04Designs imitating natural patterns of stone surfaces, e.g. marble
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00Other substrates
    • B05D2203/30Other inorganic substrates, e.g. ceramics, silicon
    • B05D2203/35Glass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/061Special surface effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/57Three layers or more the last layer being a clear coat
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/72Decorative coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

Marbled glass comprising a glass substrate, the substrate having on at least one of its surfaces a veined pattern of a first paint in one or more colours. Also disclosed is a method of making marbled glass, comprising (a) depositing a first paint of one or more colours onto the surface of a liquid filled container to form a pattern, (b) placing at least one of the surfaces of a glass substrate onto the surface of the said liquid so that it picks up the first paint, and (c) removing the glass from the said liquid.

Description

I
MARBLED GLASS AND A METHOD OF MAKING MARBLED GLASS
The invention relates to marbled glass and a method of making marbled glass.
Marbled paper has been known for a number of centuries, and has been widely used, especially in book binding. Marbled paper is produced by floating inks on the surface of a liquid such as water, and distributing the inks so that they form patterns on the liquid. The inks are then transferred onto the paper by laying a sheet of paper onto the surface of the liquid so that the paper absorbs the inks. The paper is left in the liquid until the inks have transferred through to the outermost surface of the paper. The paper Is then removed from the liquid and allowed to dry.
The resulting paper is decorated on both sides with veined patterns so that the paper resembles marble.
The known method of marbling paper relies on the fact that paper will absorb ink. It will not work with a non-absorbent substrate such as glass.
Decorative glass is used in interior design. It Is an object of the invention to provide a new form of decorative glass.
Accordingly, in a first aspect, the invention provides marbled glass comprising a glass substrate, the substrate having on at least one of its surfaces a veined pattern of a first paint in one or more colours.
As the pattern is veined, the glass resembles marble, hence the name "marbled glass". Marbled glass differs from marbled paper in that paint is used to form the veined pattern rather than ink, and the substrate Is non-absorbent glass rather than absorbent paper. Thus, with marbled glass, the paint Is not transferred through to the other side of the glass substrate so that the veined pattern is formed on both sides of the glass.
Instead, the veined pattern is formed on one surface of the glass substrate, but is viewed from the opposite surface of the glass substrate to that on which the veined pattern has been formed. Thus, marbled glass is a form of back-painted glass, that Is, glass which has been painted on its reverse surface, but which is viewed from its front surface.
The marbled glass may comprise at least one coating of a second paint applied over the veined pattern of the first paint. The second paint may be a different colour than any of the colours of the first paint so that it contrasts with the first paint, and provides a background to the veined pattern of the first paint.
The marbled glass may comprise an outer protective coating applied over the veined pattern of the first paint and, where present, the coating(s) of the second paint.
The outer protective coating may comprise a coating of varnish or a film of plastic material.
The marbled glass may comprise an undercoat beneath the veined pattern of the first paint. The undercoat may comprise a layer of varnish.
The undercoat creates a stronger bond between the glass and the first and, where present, second paint(s).
According to a second aspect, the invention provides a method of making marbled glass, the method comprising the steps of: a) depositing a first paint in one or more colours onto the surface of a liquid-Pilled container to form a pattern; b) placing at least one of the surfaces of a glass substrate onto the surface of the liquid so that it picks up the first paint, and c) removing the glass substrate from the liquid.
The pattern which has been formed by depositing the first paint onto the surface of the liquid may not be the desired veined pattern.
Accordingly, once the first paint has been deposited on the surface of the liquid-filled container, it may be distributed about the surface of the liquid so that It forms the desired veined pattern.
The first paint should be such that it will remain on or near the surface of the liquid. Preferably, the first paint floats on the liquid.
Oil-based paints may float on water if they contain the right organic solvents In a sufficient quantity. Accordingly, the first paint may be an oil-based paint.
The term "oil" as used herein means any oil or other organic solvent, and the term "oil-based paint" means any paint where an oil or other organIc solvent is used as part of the binder and/or solvent for the paint.
Following the 2010 Volatile Organic Compounds (VOC) legislation, the amount of organic solvent present in paints has been reduced In order to meet the requirements of this legislation which aims to limit the use of VOCs. However, in many Instances this means that the paints no longer float, as the solids content has increased, and the surface tension qualities have changed. Accordingly, the first paint preferably does not meet the requirements of the 2010 Volatile Organic Compounds (VOC) legislation.
The first paint may comprise more than 25% of VOCs, preferably more than 30% of VOCs, most preferably more than 35% of VOCs.
The first paint may comprise more than 300g/l of VOCs, preferably 350g/l or more of VOCs, more preferably 375g/l or more of VOCs, most preferably 400g/l or more of VOCs.
Although it is preferable that the first paint should be oil-based, it is also preferable that the first paint should not contain so much oil that it takes a very long time to dry. The first paint may be such it dries within 48 hours once applied to the glass substrate, preferably 12 hours, more preferably 2 hours.
Preferably, the viscosity and surface tension of the first paint are such that it will form veined patterns on the surface of the liquid.
Preferably, the veined pattern of the first paint on the glass substrate is dried once the substrate has been removed from the liquid-filled container. This may be done by accelerated means, for example, heat, or by allowing the paint to dry at room temperature.
At least one coating of a second paint may be applied over the veined pattern of the first paint. The second paint may be a different colour than any of the colours of the first paint so that it contrasts with the first paint, and provides a background to the veined pattern of the first paint.
Preferably, the second paint is compatible with the first paint.
If the first paint is an oil-based paint, the second paint is more likely to be compatible with the first paint if it too Is an oil-based paint.
Accordingly, the second paint may be an oil-based paint, for example, an enamel.
An outer protective coating may be applied over the veined pattern or the first paint and, where present, the coating(s) of the second paint.
The outer protective coating may comprise a coating of varnish or a film of plastics material.
Preferably, the glass substrate Is de-greased before being laid onto the surface of the liquid.
An undercoat may be applied to the glass substrate before the glass substrate is laid onto the surface of the liquid.
The liquid may be any suitable liquid. Preferably, the liquid is water.
The glass substrate may take any form, for example, sheet glass.
The invention will now be illustrated, by way of example only, with reference to the following drawings of whIch: Figure 1 shows a plan view of marbled glass produced according L4 the method of the Invention, and Figure 2 shows an exploded side view of the marbled glass of Figure 1.
The marbled glass shown in Figures 1 and 2 comprises a sheet of glass 1 havIng a front surface 2 and a reverse surface 3. The sheet of glass 1 may be of any thickness. In the described embodiment, it is 6mm thick.
Any type of glass may be used. In the described embodiment, toughened low-iron glass has been used. Toughened glass has been used because it is stronger and less liable to break than normal glass. Low-iron glass has been used because it is completely colourless, and does not have the blue-green tint of normal glass, thereby allowing the true colour of the paints used for the marbling to be seen.
A veined pattern 4 of a first paint in one or more colours has been applied to the reverse surface 3 of the glass sheet 1. Two coatings 5a, 5b of a second paint have been applied over the veined paint pattern 4. The second paint is a different colour than any of the colours of the first paint so that it contrasts with the first paint, and provides a background to the veined pattern 4 of the first paint. An outer protective coating 6 comprising a film of plastics material has been applied over the outermost coating 5b of the second paint.
The marbled glass shown in Figures 1 and 2 Is viewed from its front surface 2. As it is in sheet form, it is partlculariy suitable for use as a cladding material to be applied to walls, furniture or any other flat surface.
For example, it may be used as a splash-back for a sink.
In order to make the marbled glass shown in Figures 1 and 2, small amounts of the first paint in one or more colours are flicked and dribbled onto the surface of a large bath of water.
The first paint Is such that it floats on water. Oil-based paints may float on water if they contain a sufficient amount of the rIght organic solvents. However the oil content must not be too high, otherwise the paint will take a long time to dry. Furthermore, the viscosity and surface tension of the paint should be such that the paint readily forms veined patterns on the surface of the water, and does not clump together. An example of a suitable paint is the Satinwood paint made by Duiux to the pre-2010 specification. After 2010, the specification of this paint was aitered so that it meets the new Volatile Organic Compounds (VOC) legislation. Under this legislation, the maximum amount of VOCs which can be contained in paint has been reduced by 25%. Satinwood paint made by Dulux to the post-2010 specification is not suitable for use in marbling glass as It does not float on water. Another example of a suitable paint is the enamei paint made by HMG Paints Ltd. Once the first paint has been deposited onto the surface of the water, the paint is moved about on the surface with a plastic stick to get the desired veined pattern and degree of spread.
A very thin layer of clear varnish is applied to a sheet 1 of 6mm thick toughened low-Iron glass and allowed to dry. The sheet of glass 1 is then thoroughly cleaned and de-greased before being gently laid onto the surface of the water with its reverse surface 3 facIng the surface of the water, and lowered beneath the surface of the water. It is then pulled back out of the water, flipped over and laid on its back to dry.
Once the first paint has dried completely, the pattern on the glass can be manipulated to some degree in that some of the paint can be lifted off by gently rubbing it with a damp cloth and abrasive cleaner. This allows the density of marbling on the glass to be controlled.
A second paint is then applied over the veined pattern of first paint to form a solid coating Sa over the marbling. In general, the second paint Is applied with a roller or a paint brush. However, if the second paint is in the form of a suspension as is the case with metallic suspension paint, then the paint may be applied with scrunched up tissue paper so as to avoid visible roller/brush marks.
The second paint should be compatible with the first paint as well as being tough and durable. The second paint is a different colour than any of the colours of the first paint so that it contrasts with the first paint, and provides a background to the veined pattern of the first paint. The second paint may be opaque or semi-transparent. Known paints for back-painting glass such as Spraycoat' made by Creative Resins are not suitable because these paints are extremely aggressive, and so are not usually compatible with the first paint. An example of a suitable paint is Coach Enamel made by HMG Paints.
Once the coating 5a of the second paint has dried, another layer of the second paint Is applied on top of the first layer to form a second coating 5b.
Once two coatings Sa, 5b of the second paint have been applied and are dry, a film of plastics material Is applied over the dried paint In order to form an outer protective coating 6. Alternatively, if the outer protective coating is likely to be seen, a polyurethane varnish may be used. Such a varnish wili give extra damp protection.
Because of the way in which the marbled glass is made, each sheet of marbled glass is different from any other sheet of marbled glass. As such, it Is a bespoke product.
The above embodiment has been described to illustrate the invention, and is not intended to be limiting. The skilled person wlil be readily able to devise alternative embodiments without departing from the scope of the claims. a

Claims (1)

  1. <claim-text>CLAIMS1. Marbled glass comprising a glass substrate, the substrate having on at least one of its surfaces a veined pattern of a first paint In one or more colours.</claim-text> <claim-text>2. Marbled glass according to claim 1, the marbled glass comprising at least one coating of a second paint applied over the veined pattern of the first paint.</claim-text> <claim-text>3. Marbled glass according to claim 1 or claim 2, the marbled glass comprising an outer protective coating applied over the veined pattern of the first paint and, where present, the coating(s) of the second paint.</claim-text> <claim-text>4. Marbled glass according to claim 3, whereIn the outer protective coating comprises a coating of varnish or a film of plastics material.</claim-text> <claim-text>5. Marbled glass according to any preceding claim, the marbled glass comprising an undercoat beneath the veined pattern of the first paint.</claim-text> <claim-text>6. A method of making marbled glass, the method comprising the steps of: a) depositing a first paint in one or more colours onto the surface of a liquid-filled container to form a pattern; b) placing at least one of the surfaces of a glass substrate onto the surface of the liquid so that It picks up the iirst paint, and c) removing the glass substrate from the liquid.</claim-text> <claim-text>7. A method according to claim 6, wherein, once the first paint has been deposited on the surface of the liquid-filled container, it Is distributed about the surface of the liquid so that It forms a desired veined pattern.</claim-text> <claim-text>8. A method according to claim 6 or claim 7, wherein the first paint is such that it floats on the liquid.</claim-text> <claim-text>9. A method according to any of claims 6 to 8, wherein the first paint is an oil-based paint.</claim-text> <claim-text>10. A method according to claim 9, wherein the first paint does not meet the requirements of the 2010 Volatile Organic Compounds (VOC) legislation.</claim-text> <claim-text>11. A method according to any preceding claim, wherein the first paint contains more than 25% of VOCs, preferably more than 30% of VOCs, most preferably more than 35% of VOCs.</claim-text> <claim-text>12. A method according to any of claims 1 to 10, wherein the first paint comprises more than 300g/l of VOCs, preferably 350g/l or more of VOCs, more preferably 375g/l or more of VOCs, most preferably 400g/l or more of VOCs.</claim-text> <claim-text>13. A method according to any of claims 6 to 12, wherein the first paint is such that it drIes within 48 hours once applied to the glass substrate, preferably 12 hours, more preferably 2 hours.</claim-text> <claim-text>14. A method according to any of claims 6 to 13, wherein the vIscosity and surface tension properties of the first paint are such that It will form veined patterns on the surface of the liquid.</claim-text> <claim-text>15. A method according to any of claims 6 to 14, wherein the veined pattern of the first paint on the glass substrate is dried once the substrate has been removed from the liquid-filled container, 16. A method according to any of claims 6 to 15, wherein at least one coating of a second paint is applied over the veined pattern of the first paint.17. A method according to claim 16, wherein the second paint is compatible with the first paint.18. A method according to claim 16 or claim 17, wherein the second paint is an oil-based paint.19. A method according to any of claims 6 to 18, wherein an outer protective coating is applied over the veined pattern of the first paint and, where present, the coating(s) of the second paint.20. A method according to claim 19, whereIn the outer protective coating comprises a coating of varnish or a film of plastics material.21. A method according to any of claims 6 to 20, wherein the glass substrate is de-greased before being laid onto the surface of the liquid.22. A method according to any of claims 6 to 21 wherein an undercoat is applied to the glass substrate before the glass substrate is laid onto the surface of the liquid.23. A method according to any of claims 6 to 22, wherein the liquid is water.24. Marbled glass substantially as described herein or as shown in the drawings.25. A method of makhg marbled glass substantafly as described herein.</claim-text>
GB1219630.9A 2011-11-04 2012-11-01 Marbled glass and a method of making marbled glass Withdrawn GB2496309A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB1119027.9A GB201119027D0 (en) 2011-11-04 2011-11-04 Marbled glass and a method of making marbled glass

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GB201219630D0 GB201219630D0 (en) 2012-12-12
GB2496309A true GB2496309A (en) 2013-05-08

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GB1219630.9A Withdrawn GB2496309A (en) 2011-11-04 2012-11-01 Marbled glass and a method of making marbled glass

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020255068A1 (en) * 2019-06-21 2020-12-24 Omni Decor S.R.L. Decorated glass sheet and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2645077A1 (en) * 1989-03-30 1990-10-05 Bouillet Jean Noel Method for decorating a support by means of marbling and resulting support
US5348766A (en) * 1993-01-05 1994-09-20 Elaine Latham Method for marbleizing an object by dipping the object into paint floating on borax-conditioned water
DE4323843A1 (en) * 1993-07-16 1995-01-19 Wild Josef & Co Method of producing patterned coloured coatings
EP0815951A1 (en) * 1996-06-28 1998-01-07 Elaine Latham A method of coating a surface of an object
EP1710214A1 (en) * 2005-03-29 2006-10-11 Inks &Coatings Supplies Ltd. Tennants Applying colour to improvious surfaces

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2645077A1 (en) * 1989-03-30 1990-10-05 Bouillet Jean Noel Method for decorating a support by means of marbling and resulting support
US5348766A (en) * 1993-01-05 1994-09-20 Elaine Latham Method for marbleizing an object by dipping the object into paint floating on borax-conditioned water
DE4323843A1 (en) * 1993-07-16 1995-01-19 Wild Josef & Co Method of producing patterned coloured coatings
EP0815951A1 (en) * 1996-06-28 1998-01-07 Elaine Latham A method of coating a surface of an object
EP1710214A1 (en) * 2005-03-29 2006-10-11 Inks &Coatings Supplies Ltd. Tennants Applying colour to improvious surfaces

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
WPI Abstract Accession No 1990-350658/47 & FR 2645077A1 *
WPI Abstract Accession No 1995-053021/08 & DE 4323843A1 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020255068A1 (en) * 2019-06-21 2020-12-24 Omni Decor S.R.L. Decorated glass sheet and manufacturing method thereof

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GB201219630D0 (en) 2012-12-12
GB201119027D0 (en) 2011-12-14

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