GB2445955A - Floating ball barrier in a liquid and gas container - Google Patents

Floating ball barrier in a liquid and gas container Download PDF

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Publication number
GB2445955A
GB2445955A GB0701528A GB0701528A GB2445955A GB 2445955 A GB2445955 A GB 2445955A GB 0701528 A GB0701528 A GB 0701528A GB 0701528 A GB0701528 A GB 0701528A GB 2445955 A GB2445955 A GB 2445955A
Authority
GB
United Kingdom
Prior art keywords
liquid
gas
particles
droplets
balls
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB0701528A
Other versions
GB0701528D0 (en
Inventor
James Anthony Smee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB0701528A priority Critical patent/GB2445955A/en
Publication of GB0701528D0 publication Critical patent/GB0701528D0/en
Publication of GB2445955A publication Critical patent/GB2445955A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/16Preventing evaporation or oxidation of non-metallic liquids by applying a floating layer, e.g. of microballoons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/30Accessories for evaporators ; Constructional details thereof
    • B01D1/305Demister (vapour-liquid separation)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00Large containers
    • B65D88/34Large containers having floating covers, e.g. floating roofs or blankets
    • B65D88/36Large containers having floating covers, e.g. floating roofs or blankets with relatively movable sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/22Safety features
    • B65D90/38Means for reducing the vapour space or for reducing the formation of vapour within containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00Component parts, details or accessories for large containers
    • B65D90/22Safety features
    • B65D90/38Means for reducing the vapour space or for reducing the formation of vapour within containers
    • B65D90/42Means for reducing the vapour space or for reducing the formation of vapour within containers by use of particular materials for covering surface of liquids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • F17C13/004Details of vessels or of the filling or discharging of vessels for large storage vessels not under pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/02Vessels not under pressure with provision for thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/02Vessels not under pressure with provision for thermal insulation
    • F17C3/022Land-based bulk storage containers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00Effects achieved by gas storage or gas handling
    • F17C2265/01Purifying the fluid
    • F17C2265/015Purifying the fluid by separating

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Cleaning In General (AREA)
  • Separation Of Particles Using Liquids (AREA)

Abstract

A container holds a mix of liquid and gaseous crude oil. A barrier layer of balls, beads or similar, floats on the liquid surface, physically trapping and returning any vapour formed by gas bubbling, back to the liquid portion, thus providing a gas portion substantially free of vapour.

Description

Liquid Carryover Control System
Description
Introduction.
Crude oil, as it comes from the well, is a mixture of oil, water, gas and solids in varying proportions. These are separated by many different processes in order for oil companies to sell the various products such as butane and propane gas, petrol, diesel and lubricating oil, and bitumen and heavy asphalt products.
When the pressure in the well is relieved, the gas bubbles out of the iiqud ice a tizzy drink and is piped away separately. In successive separation stages the pressure is dropped to near atmospheric where the product is stored in the large crude oil storage tanks. Gas continues to be liberated perhaps like aiiat fizzy drink, but the* quantity is large due to the huge volume of liquid crude oil. This low pressure gas is piped from the top of the tanjs and cpmpressed and liquefied in a process referred to as condensate recovery. Refer to Figs I & 2 of drawings.
The gas contains droplets or mist of crude 0 whi can be harmlul to the downstream processes, polluting process equipment, compressors and other plant with oil, asphalt and other contaminants.
iiters aid "knock ou vessels are used to get dd of these products and leave pure gas but their success is limited. This patent proposes a solution to control droplets leaving the liquid surface.
Patent Principle This patent document describes a system to stop or limit the formation of droplets at the surface of the liquid crude.
The basic principle is described below.
In many industries wheç hot or vçltile iquis are used for cleaning or other applications, a layer of floating balls is placed on the surface of the liquid both to control splashing and aporation and to conserve heat. In some processes air or gas is bubbled through liquids such as cleaning solvents to agitate the liquid and wash any articles which are immersed. This allows baskets of components or individual items to be lowered through the layers of balls and into the bubbling liquid.
The balls imrndiately seal the surface after this is done, and again when the items are removed. Specialist companies manufacture balls of all sizes in a whole range of materials with resistance to various solvents, oils and other liquids, polypropylene being one of the commonest and cheapest.
g 3 shows how a bubbte can throw qd droplets into the space above the surface and fig 4 shows how a floating layer of particles can dampen this action.
ihs App Hcaion This patent s or the appiicaton oa oang layer o?b1is or pathcies on the surface of the crude oil which has the effect of rçducing or stoppin.g the droplets of oil which are carried over with the gas as mist to the next process. The particles are optimised in size and shape asjs the ttliclsness of the layer in order to absorb the energy of the bursting bubbles so that no liquid droplets are thrown into the space above the liquid.
Trials, show that tiny particles of plastic in the shape of beads or toroids are very effective but this patent is to cover all shapes and sizes of floating particles of any material, used to control the liqui rryove into the gas stream. These may be as small as sand or larger than tennis bafls, with layers of any thickness. Layers of floating particles about 10 ceitimetres.thick hve been found yery effective with toroidal shaped plastic particles about 2 mm diameter, removing around 95% of the droplets present without this layer on the urface.
This patent covers also various methods for applying and removing the particles, as well as methods of preparing materials and particles suitable for this application.
This patent covers all applications of liquid carryover due to bubbling gas liberating droplets into a stream of gas.
ig I and ig 2 show how the system s arranged hen appiled to crude di tanks, and fig 3 and fig 4 show how gas energy is absorbed by a layer of particles floating on the liquid surface.
Newness and novelty Liquid carryover has been a proIem in the dl industry or a long time and many solutions have failed. The normai. approach.is to remove the droplets fr* the gas stream after liberation from a surface, but this method prevents the liquid droplets from forming at the source, the liquid surface. At low pressure it is not possible to use dense filters or cyclones because of the pressure drop. This method of controlling carryover has been provenfor.smatl simulations, working very successfully. No similar method is available within the major oil companies at the present time.

Claims (3)

1. A system of floating layer of balls or particles placed on the surface of depressurised crude oil, which is liberating gas, which has the effect of reducing or stopping the droplets of oil which are carried over with the gas as mist to the next process.
2. Various methods for applying and removing the particles, as welt as methods of preparing, testing and optimising materials and particles suitable for this application.
3. All applications of floating balls or particles to reduce or eliminate liquid carryover due to bubbling gas liberating droplets into a stream of gas.
GB0701528A 2007-01-26 2007-01-26 Floating ball barrier in a liquid and gas container Withdrawn GB2445955A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB0701528A GB2445955A (en) 2007-01-26 2007-01-26 Floating ball barrier in a liquid and gas container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB0701528A GB2445955A (en) 2007-01-26 2007-01-26 Floating ball barrier in a liquid and gas container

Publications (2)

Publication Number Publication Date
GB0701528D0 GB0701528D0 (en) 2007-03-07
GB2445955A true GB2445955A (en) 2008-07-30

Family

ID=37872850

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0701528A Withdrawn GB2445955A (en) 2007-01-26 2007-01-26 Floating ball barrier in a liquid and gas container

Country Status (1)

Country Link
GB (1) GB2445955A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130270723A1 (en) * 2010-10-27 2013-10-17 Future Engineering As Device For A Cleaning Unit For Hydraulic Oil And Lubricating Oil

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB752345A (en) * 1954-01-07 1956-07-11 Standard Oil Co A method of inhibiting the evaporation of volatile products
US2797138A (en) * 1953-03-06 1957-06-25 Standard Oil Co Method of inhibiting evaporation of crude oil and floating layer for use therein
JPS502002A (en) * 1973-05-09 1975-01-10
US4035149A (en) * 1975-01-15 1977-07-12 Shell Oil Company Vapor barriers for liquid conservation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2797138A (en) * 1953-03-06 1957-06-25 Standard Oil Co Method of inhibiting evaporation of crude oil and floating layer for use therein
GB752345A (en) * 1954-01-07 1956-07-11 Standard Oil Co A method of inhibiting the evaporation of volatile products
JPS502002A (en) * 1973-05-09 1975-01-10
US4035149A (en) * 1975-01-15 1977-07-12 Shell Oil Company Vapor barriers for liquid conservation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130270723A1 (en) * 2010-10-27 2013-10-17 Future Engineering As Device For A Cleaning Unit For Hydraulic Oil And Lubricating Oil
US9522345B2 (en) * 2010-10-27 2016-12-20 Future Engineering As Device for a cleaning unit for hydraulic oil and lubricating oil

Also Published As

Publication number Publication date
GB0701528D0 (en) 2007-03-07

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)