GB2436007A - Method and apparatus for fabricating a colour filter array - Google Patents

Method and apparatus for fabricating a colour filter array Download PDF

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Publication number
GB2436007A
GB2436007A GB0700753A GB0700753A GB2436007A GB 2436007 A GB2436007 A GB 2436007A GB 0700753 A GB0700753 A GB 0700753A GB 0700753 A GB0700753 A GB 0700753A GB 2436007 A GB2436007 A GB 2436007A
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United Kingdom
Prior art keywords
soft mold
color filter
forming
substrate
overcoat layer
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Granted
Application number
GB0700753A
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GB0700753D0 (en
GB2436007B (en
Inventor
Gee Sung Chae
Gyoo Chul Jo
Jin Wuk Kim
Yong Sup Hwang
Chang Hee Lee
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LG Display Co Ltd
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LG Philips LCD Co Ltd
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Publication date
Priority claimed from KR1020040092133A external-priority patent/KR101085133B1/en
Priority claimed from KR1020040092132A external-priority patent/KR101085134B1/en
Application filed by LG Philips LCD Co Ltd filed Critical LG Philips LCD Co Ltd
Priority to GB0700753A priority Critical patent/GB2436007B/en
Priority claimed from GB0513046A external-priority patent/GB2420216B/en
Publication of GB0700753D0 publication Critical patent/GB0700753D0/en
Publication of GB2436007A publication Critical patent/GB2436007A/en
Application granted granted Critical
Publication of GB2436007B publication Critical patent/GB2436007B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/22Absorbing filters
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133516Methods for their manufacture, e.g. printing, electro-deposition or photolithography
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133519Overcoatings
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • G02F1/13394Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars

Abstract

A fabricating method comprises forming a black matrix 102 that defines pixel areas on a substrate 101, forming a colour filter 104 in the pixel areas, coating with a transparent resin (182, Fig.17b), aligning a soft mold 184 having a groove 186a/b to an upper part of the substrate and simultaneously forming an overcoat layer 122 and a rib 134 by molding the transparent resin thereby forming a rib for each pixel area. A soft mould for use in the above method is also claimed. Preferably the soft mould is made from polydimethylsiloxane PDMS, polyurethane or cross-linked novolac resin.

Description

<p>THIN FILM PA1TERNTNG APPARATUS AND METhOD OF FABRICATING</p>
<p>COLOR FILTER ARRAY SUBSTRATE USING THE SAME</p>
<p>[00011 This application claims the benefit of Korean Patent Application Nos. P2004-92132 and P2004-92 133 both filed on November 11,2004, which are hereby incorporated by reference in their entirety.</p>
<p>BACKGROUND OF THE INVENTION</p>
<p>Field of the Invention</p>
<p>(00021 The present invention relates to a liquid crystal display device, and more particularly to a thin film patterning ai,paratus and method of fabricating color filter array substrate using the same. Although the present invention is suitable for a wide scope of applications, it is particularly suitable for a thin film patterning apparatus that can perform a patterning process, without using a photolithography process.</p>
<p>Description of the Related Art</p>
<p>[0003] Generally, a liquid crystal display (LCD) controls the light transmissivity of liquid crystal by use of an electric field, thereby displaying a picture. The liquid crystal display device includes a liquid crystal display panel in which liquid crystal cells are arranged in a matrix form, and a driving circuit for driving the liquid crystal display panel. In the liquid crystal display panel, a reference electrode, such as a common electrode, and pixel electrodes are provided for applying the electric field to each of the liquid crystal cells. Generally, the pixel electrodes are formed on a lower substrate in individual liquid crystal cells, and the common electrode is integral and formed over the entire surface of the upper substrate. The pixel electrodes are connected to thin film transistors TFT, which are used as switching devices. The pixel electrodes along with the common electrode drives the liquid crystal in accordance with a data signal supplied through the TFT.</p>
<p>100041 FIG. 1 is an expanded perspective view of a related art liquid crystal display panel. Referring to FIG. 1, the related art liquid crystal display panel includes a color filtcr array substrate 10 and a thin film transistor array substrate 20, which are bonded together. Liquid crystal molecules 8 are between the color filter array substrate and the thin film transistor array substrate 20. The liquid crystal molecules 8 rotate in response to the data signal applied to it, thereby controlling the amount of light transmitted through the thin film transistor array substrate 20.</p>
<p>10005) The color filter array substrate 10 includes a color filter 4, a black matrix 2 and a common electrode 6, which are formed on the rear surface of the upper substrate 1. The color filter 4 includes red (R), green (G) and blue (B) color filters to enable a full color display. The black matrix 2 is formed between the adjacent color filters 4 to absorb the light from the adjacent cells, thereby preventing deterioration in the contrast.</p>
<p>[0006] The thin film transistor array substrate 20 has a data line 18 and a gate line 12, which are formed to cross each other. A gate insulating film (not shown) is formed over the gate line 12 and over the entire surface of a lower substrate 21. A TFT 16 is formed adjacent to where the data line 18 and the gate line 12 cross. The TFT 16 includes a gate electrode connected to the gate line 12, a source electrode connected to the data line 18, a drain electrode connected to the pixel electrode 14 and an active layer with a channel part. The active layer contacts the source and drain electrodes with ohmic contact layers. The TFT 16 selectively supplies a data signal from the data line 18 to the pixel electrode 14 in response to a gate signal from the gate line 12.</p>
<p>10007] The pixel electrode 14 is located in a cell area that is defined by the data line 18 and the gate line 12, and is formed of a transparent conductive material with high light transmissivity. A potential difference is generated between the pixel electrode 14 and the common electrode 6 by a data signal supplied through the drain electrode. The potential difference causes liquid crystal molecules 8, which are located between the lower substrate 21 and the upper substrate 1, to rotate by dielectric anisotropy. Accordingly, the light supplied to the pixel electrode 14 from a light source is transmitted through the liquid crystal molecule 8 to the upper substrate 1.</p>
<p>[0008] Each pixel of the liquid crystal display panel shown in FIG. 1 includes a sub-pixel for realizing red (R), a sub-pixel for realizing green (G) and a sub-pixel for realizing blue (B). In the case of a pixel composed of R, G, B sub-pixels, only about 27% -33% of the light emitted from a backlight is transmitted through the color filter 4. In order to solve such a problem, a color filter array substrate of the liquid crystal display panel having a different sub-pixel arrangement has been proposed.</p>
<p>[0009] FIG. 2 is a cross-sectional diagram of the related art color filter array substrate having a white color filter. The color filter array substrate of the liquid crystal display panel shown in FIG. 2 has red (R), green (G), blue (B) and white (W) sub-pixels 4R, 4G, 4W and 4B. In a liquid crystal display panel having the W sub-pixel, the amount of light emitted through the color filter 4 is greater than 85% of the light emitted from a backlight. Accordingly, the mean value of the light emitted from each pixel composed of the R, G, B, W sub-pixels is relatively high, thereby improving brightness.</p>
<p>10010] FIGs. 3A to 3L are cross-sectional views representing a fabricating method of the related art color filter array substrate of the liquid crystal display panel shown in FIG. 2. First, an opaque layer 54, as shown in FIG. 3A, is formed on the upper substrate I by one of sputtering, spin coating and spinless coating. The opaque layer 54 is an opaque resin or an opaque metal, such as chrome (Cr). Subsequently, a photo resist pattern 52 is formed on the opaque layer 54 by a photolithography process using a first mask 50 that defines an exposure area SI and a shielding area S2. The opaque layer 54 is patterned by an etching process using the photo resist pattern 52, thereby forming a black matrix 2 on the upper substrate 1, as shown in FIG. 3B.</p>
<p>[0011] A red resin 58, as shown in FIG. 3C, is spread over the whole surface of the upper substrate 1 on which the black matrix 2 is formed. Subsequently, the red resin 58 is patterned by a photolithography process using a second mask 56 that defines the exposure area Si and the shielding area S2, thereby forming a red color filter 4R, as shown in FIG. 3D.</p>
<p>[00121 A green resin 60, as shown in FIG. 3E, is spread over the entire surface of the upper substrate 1 on which the red color filter 4R is formed. Subsequently, the green resin 60 is patterned by a photolithography process using a third mask 62 that defines the exposure area Si and the shielding area S2, thereby forming a green color filter 4G, as shown in FIG. 3F.</p>
<p>100131 A blue resin 64, as shown in FIG. 3G, is spread on the entire surface of the upper substrate 1 on which the green color filter 40 is formed. Subsequently, the blue resin 64 is patterned by a photolithography process using a fourth mask 66 that defines the exposure area Si and the shielding area S2, thereby forming a blue color filter 4B, as shown in FIG. 311.</p>
<p>[00141 A white resin 68, as shown in FIG. 31, is spread over the entire surface of the upper substrate 1 on which the blue color filter 4B is formed. The white resin 68 is an organic insulating material including an acrylic resin. Subsequently, the white resin 68 is patterned by a photolithography process using a fifth mask 70 that defines the exposure area Si and the shielding area S2, thereby forming a white color filter 4W, as shown in FIG. 3J.</p>
<p>[00151 An organic insulating material is spread over the upper substrate I on which the white color filter 4W is formed, thereby forming an overcoat layer 22, as shown in FIG. 3K. Then, an organic material 76 is spread over the entire surface of the overcoat layer 22 on the upper substrate 1. Subsequently, the photo resist pattern 74 is formed by a photolithography using a sixth mask 72 that defines the exposure area SI and the shielding area S2. The organic material 76 is patterned by the photo resist pattern 74, thereby forming a spacer 24, as shown in FIG. 3L.</p>
<p>[00161 A six mask process is required for forming the color filter array substrate shown in FIG. 2. In this case, costs are high because the fabrication process is complicated. Thus, there is a need for reducing manufacturing costs by simplifying the fabricating process.</p>
<p>10017] FIG. 4 is an expanded perspective view representing a related art vertical alignment type liquid crystal display panel. The liquid crystal display device shown in FIG. 4 can realize a multi-domain by making the liquid crystal have several arrangement directions by using a rib 34. That is, in the vertical alignment type liquid crystal display panel shown in FIG. 4, the electric field applied to the liquid crystal is distorted by the rib 34, so that the liquid crystal is arranged in symmetric directions centered on the rib 34, thus the viewing angle is broadened.</p>
<p>[00181 FIGs. 5A to 5E are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 4. Referring to FIG. 5A, the black matrix 2 is formed on the upper substrate 1. After the opaque resin or the opaque metal is spread over the upper substrate 1, the black matrix 2 is formed by patterning the opaque resin or the opaque metal by a photolithography process using a mask and etching process.</p>
<p>The opaque resin can be, for example, carbon black, and the opaque metal can be, for example, chrome (Cr) or chrome oxide (CrOx/Cr/CrOx, CrOx/Cr/CrSix).</p>
<p>[00191 Referring to FIG. 5B, the color filter 4 is formed on the upper substrate I on which the black matrix 2 is formed. After each of red, greed and blue color resins is spread on the entire surface of the upper substrate I on which the black matrix 2 is formed, the color filter is formed by having each of the red, greed and blue color resins patterned by a photolithography process using a mask.</p>
<p>[00201 Referring to FIG. 5C, an overcoat layer 22 is formed over the upper substrate I on which the color filter 4 is formed. The overcoat layer 22 is formed by having a transparent insulating layer, such as acrylic resin or epoxy resin, spread over the entire surface of the upper substrate 1 on which the color filter 4 is formed.</p>
<p>[00211 Referring to FIG. 5D, a common electrode 6 is formed over the upper substrate 1 on which the overcoat layer 22 is formed. The common electrode 6 is formed by depositing a transparent conductive film, such as ITO or IZO, over the entire surface of the upper substrate 1 on which the overcoat layer is formed.</p>
<p>100221 Referring to FIG. 5E, a rib 34 is formed over the upper substrate I on which the common electrode 6 is formed. After a polymer resin, such as acrylic resin or epoxy resin, is spread on the entire surface of the upper substrate 1 on which the common electrode 1 is formed, the rib 34 of polymer resin is formed by patterning through a photolithography process.</p>
<p>[0023] In the fabricating method of the related art vertical alignment type liquid crystal display panel, a plurality of patterns are formed by photolithography processes.</p>
<p>The photolithography process is a series of photo processes including the steps of spreading photo resist, aligning masks, exposing and developing. The photolithography process has problems in that it requires a long time, a developing solution for developing the photo resist and too much photo resist pattern is wasted, and expensive exposure equipment is required. Further, the process of forming the rib 34 and the process of forming the overcoat layer 22 are separately performed, thus there is a problem in that the fabricating process time and the cost increases.</p>
<p>SUMMARY OF THE INVENTION</p>
<p>[0024] Accordingly, the present invention is directed to a fabricating method of a color filter array substrate that substantially obviates one or more of the problems due to limitations and disadvantages of the related art.</p>
<p>100251 An object of the present invention to provide to a fabricating method of a color filter array substrate that simplifies the fabrication process.</p>
<p>[00261 Another object of the present invention to provide a fabricating method of a color filter array substrate having an overcoat layer with a smooth surface.</p>
<p>[0027] Another object of the present invention to provide a thin film patterning apparatus that can perform a patterning process without using a photolithography process and a fabricating method of a color filter array substrate using the same.</p>
<p>[0028] Additional features and advantages of the invention will be set forth in the description which follows, and in part will be apparent from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention will be realized and attained by the structure particularly pointed out in the written de'rintinn ind clim' hereAf well the inneneil drgwincy [00291 To achieve these and other advantages and in accordance with the purpose of the present invention, as embodied and broadly described, a fabricating method of a color filter array substrate includes the steps of forming a black matrix on a substrate, forming red, green, blue color filters on the substrate on which the black matrix is formed, forming an overcoat layer including a white color filter on the substrate on which the red, green, and blue color filters are formed, aligning a flat panel soft mold to the overcoat layer, and smoothing the overcoat layer using the flat panel soft mold.</p>
<p>[00301 In another aspect, a fabricating method of a color filter array substrate includes the steps of forming a black matrix on a substrate, forming red, green, blue color filters on the substrate on which the black matrix is formed, coating a transparent resin over the substrate on which the red, green, blue color filters are formed, aligning a soft mold having a groove and a projection to an upper part of the substrate on which the transparent resin is formed, and simultaneously forming at least two of a white color filter, an overcoat layer and a spacer using the soft mold.</p>
<p>[0031] In another aspect, a fabricating method of a color filter array substrate includes the steps of forming a black matrix that defines pixel areas on a substrate, forming a color filter in the pixel areas, coating a transparent resin over the substrate where the color filter is formed, aligning a soft mold having a groove and a projection to an upper part of the substrate where the transparent resin is formed, and forming an overcoat layer by molding the transparent resin with the soft mold, and simultaneously forming a rib for each pixel area so that an arrangement direction of a liquid crystal is adjusted to be in a plurality of directions.</p>
<p>[00321 In another aspect, a thin film patterning apparatus for fabricating a color filter array substrate which has a black matrix for preventing light leakage, a color filter for realizing color, an overcoat layer for compensating a stepped difference by the color filter, and a rib simultaneously formed of the same material as the overcoat layer for adjusting an arrangement direction of a liquid crystal includes a soft mold which has a projected part formed at an area corresponding to the overcoat layer, and a groove formed at an area corresponding to the rib that projects from the overcoat layer.</p>
<p>[00331 It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.</p>
<p>BRIEF DESCRIPTION OF THE DRAWINGS</p>
<p>[00341 These and other objects of the invention will be apparent from the following detailed description of the embodiments of the present invention with reference to the accompanying drawings.</p>
<p>[0035] FIG. 1 is an expanded perspective view of a related art liquid crystal display panel.</p>
<p>[0036J FIG. 2 is a cross-sectional view of a related art color filter array substrate having a white color filter.</p>
<p>[00371 FIG. 3A to 3L are cross-sectional views representing a fabricating method of the related art color filter array substrate shown in FIG. 2.</p>
<p>[00381 FIG. 4 is an expanded perspective view representing a related art vertical alignment type liquid crystal display panel.</p>
<p>[0039] FIGs. 5A to 5E are cross-sectional views for a fabricating method of the vertical alignment type liquid crystal display panel shown in FIG. 1.</p>
<p>[0040] FIG. 6 is a plan view of a color filter array substrate of a liquid crystal display panel according to a first embodiment of the present invention.</p>
<p>[00411 FIG. 7 is a cross-sectional view of the color filter array substrate shown in FIG. 6.</p>
<p>100421 FIGs. 8A and 8M are cross-sectional views representing a fabricating method of the color filter array substrate shown in FIG. 7.</p>
<p>[00431 FIG. 9 is a cross-sectional view for a color filter array substrate according to a second embodiment of the present invention.</p>
<p>[00441 FIGs. 1OA to 1OD are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 9.</p>
<p>100451 FIG. 11 is a cross-sectional view of a color filter array substrate according to a third embodiment of the present invention.</p>
<p>[0046] FIGs. 12A to l2D are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 11.</p>
<p>[0047J FIG. 13 is a cross-sectional view for a color filter array substrate according to a fourth embodiment of the present invention; 10048] FIGs. 14A to 14F are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 13; [0049] FIG. 15 is a plan view for a vertical alignment type liquid crystal display panel according to a fifth embodiment of the present invention; 10050] FIG. 16 is a cross-sectional view for the vertical alignment type liquid crystal display panel, taken along line "I-I" in FIG. 15; and [0051] FIGs. 17A to 17E are cross-sectional views for a fabricating method of the vertical alignment type liquid crystal display panel shown in FIG. 16.</p>
<p>DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS</p>
<p>[00521 Reference will now be made in detail to the preferred embodiments of the present invention, examples of which are illustrated in the accompanying drawings.</p>
<p>Hereinafter, the preferred embodiments of the present invention will be described in detail with reference to FIGs. 6 to 1 7E.</p>
<p>[00531 FIGs. 6 and 7 are respectively a plan view and a cross-sectional view representing a color filter array substrate according to a first embodiment of the present invention. Referring to FIGs. 6 and 7, a color filter array substrate according to the first embodiment of the present invention includes a black matrix 102 formed on an upper substrate 101; red, green and blue color filters I 04R, I 04G and I 04B; an overcoat layer 122 having a white color filter 104W; and a spacer 124 formed on the overcoat layer I)l I..</p>
<p>[00541 The black matrix 102 is formed on the upper substrate 101 in a matrix form to defme a plurality of cell areas where the color filters 104 are formed, and to prevent light interference between adjacent cells. The black matrix 102 is formed to overlap areas of a thin film transistor array substrate except for a pixel electrode. For example, the black matrix 102 overlaps the gate lines, the data lines and the thin film transistors of the thin film transistor array substrate.</p>
<p>10055] The color filter 104 is formed in cell areas defined by the black matrix 102. The color filter 104 includes a red color filter 104R, a green color filter 104G, a blue color filter 104B and a white color filter 104W to realize R, 0, B and W colors.</p>
<p>[00561 The overcoat layer 122 is formed to include the white color filter 104W.</p>
<p>In other words, the overcoat layer 122 is formed of the same material and with the same height as the white color filter 104W. A spacer 124 is formed on the black matrix 102 to maintain a cell gap between the color filter array substrate and the thin film transistor array substrate.</p>
<p>100571 FIGs. 8A to 8M are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 7. First, an opaque resin or an opaque metal, such as chrome (Cr), is spread over the entire surface of the upper substrate, thereby forming an opaque layer 154, as shown in FIG. 8A. A first etch resist solution 156 is formed on the opaque layer 154 by a spreading process, such as nozzle spray, spinless coating or spin coating. Herein, the etch resist solution 156 is a material that has heat resistance and chemical resistance, such as a novolac resin of about 5-30wt% added to an ethanol solution.</p>
<p>[0058] Subsequently, a first soft mold 150 having a groove 1 52a and a projected part I 52b is aligned to an upper part of the etch resist solution 156. The groove 1 52a of the first soft mode corresponds to an area where the black matrix is to be formed. The first soft mold 150 is formed of a rubber material with high elasticity, such as polydimethylsiloxane (PDMS), polyurethane or cross-linked novolac resin.</p>
<p>[00591 The first soft mold 150 is pressed into the etch resist solution 156 at about its own weight for a designated period, such as about 10 minutes to 2 hours, to make the surface of the projected part 1 52b of the soft mold 150 come into contact with the opaque layer 154. At this moment, the substrate 101 can be baked at a temperature of about 130 C, or an ultraviolet ray can be irradiated onto the etch resist solution 156 so as to soft-cure the etch resist solution 156. Thee etch resist solution 156 moves into the groove 152a of the first soft mold by a capillary effect, which is generated by a pressure between the first soft mold 150 and the substrate 101, and a repulsive force between the first soft mold and the etch resist solution 156. As a result, as shown in FIG. 8B, a first etch resist pattern 148 is formed that has a pattern shape reversely transferred from the groove I 52a of the first soft mold.</p>
<p>100601 After the first soft mold 150 is separated from the substrate 101, the opaque layer 154 is patterned by an etching process using the first etch resist pattern as a mask, thereby forming the black matrix 102, as shown in FIG. 8C. Subsequently, any remaining etch resist pattern 148 on the black matrix 102 is removed by a stripping process using an eco-friendly alcoholic system, for example.</p>
<p>10061] A red resin 158 is spread over the entire surface of the upper substrate 101 on which the black matrix 102 is formed, as shown in FIG. 8D. The red resin 158 includes a highly hydrophilic polymer. The highly hydrophilic polymer is a liquid pre-polymer, a liquefied polymer, or a material in which a hydrophilic radical is substituted within an acrylic system or epoxy system polymer chain that has high transmittance.</p>
<p>(0062] Subsequently, a second soft mold 160 with a groove 162a and a projected part 162b is aligned to the upper part of the red resin 158. The groove 162a of the second soft mold corresponds to an area where the red color filter is to be formed.</p>
<p>The second soft mold 160 is formed of a hydrophobic rubber material with high elasticity to prevent contamination with the red resin 158. The second soft mold 160 is formed of polydimethylsiloxane (PDMS), polyurethane or cross-linked novolac resin.</p>
<p>100631 The second soft mold 160 is pressed into the red resin 158 at about its own weight for a designated period, such as about 10 minutes to 2 hours, to make the surface of the projected part 162b of the second soft mold 160 come into contact with the substrate 101 and/or the black matrix 102. At this moment, the substrate 101 can be baked at a temperature of about 130 C, or an ultraviolet UV ray can be irradiated onto the red resin 158 to soft-cure the red resin 158. The TJV intensity is in accordance with at least one of a photo initiator and a base material that are included in the red resin 158.</p>
<p>For instance, the UV intensity is about 2000-2500m J/cm2 if a base material included in the red resin 158 is epoxy, and the UV intensity is about 500-1 000mJ/cm2 if a base material is acrylic. lie red resin 158 moves into the groove 1 62a of the second soft mold by a capillary force, which is generated by a pressure between the second soft mold 160 and the substrate 101, and a repulsive force between the second soft mold 160 and the red resin 158. As a result, as shown in FIG. 8E, the red color filter 104R that has a pattern shape reversely transferred from the groove 162a of the second soft mold is formed.</p>
<p>100641 A green resin 164 is spread over the entire surface of the upper substrate 101 on which the red color filter 104 is formed, as shown in FIG. 8F. The green resin 164 includes the foregoing hydrophilic polymer. Subsequently, a third soft mold 166 with the groove 1 68a and the projected part I 68b is aligned to the upper part of the green resin 164. The groove 168a of the third soft mold corresponds to an area where the green color filter is to be formed. The third soft mold 166 is formed of a hydrophobic rubber material with high elasticity as mentioned above. The third soft mold 166 is pressed into the green resin 164 at about its own weight for a designated period, such as about 10 minutes to 2 hours, to make the surface of the projected part l68b of the third soft mold 166 come into contact with at least one of the substrate 101, the red color filter 104R and the black matrix 102. Then, the substrate 101 can be baked at a temperature of about 130 C or an ultraviolet UV ray can be irradiated onto the green resin 164 to soft-cure the green resin 164. The UV intensity is in accordance with at least one of a photo initiator and a base material that are included in the green resin 164. For instance, the UV intensity is about 2000-2500m J/cm2 if a base material included in the green resin 164 is epoxy, and the UV intensity is about 500-J000mJ/cm2 if a base material is acrylic. The green resin 164 moves into the groove 168a of the third soft mold. As a result, as shown in FIG. 8G, the green color filter I 04G that has a pattern shape reversely transferred from the groove 1 68a of the third soft mold is formed.</p>
<p>100651 A blue resin 146 is spread over the entire surface of the upper substrate 101 on which the green color filter lO4G is formed, as shown in FIG. 8H. The blue resin 146 includes the foregoing hydrophilic polymer. Subsequently, a fourth soft mold with the groove I 72a and the projected part I 72b is aligned to the upper part of the blue resin 146. The groove I 72a of the fourth soft mold corresponds to an area where the green color filter is to be formed. The fourth soft mold 170 is formed of a hydrophobic rubber material with high elasticity as mentioned above. The fourth soft mold 170 is pressed into the blue resin 146 at about its own weight for a designated period, such as about 10 minutes to 2 hours, to make the surface of the projected part 172B of the fourth soft mold 170 come into contact with at least one of the substrate 101, the red color filter 104R and the black matrix 102. The substrate 101 can be baked at a temperature of about below 130 C or an ultraviolet UV ray can be irradiated onto the blue resin 146 to soft-cure the blue resin 146. The UV intensity is in accordance with at least one of a photo initiator and a base material that are included in the blue resin 146. For instance, the UV intensity is about 2000-2500m J/cm2 if a base material included in theblue resin 146 is epoxy, and the UV intensity is about 500-i000mJ/cm2 if a base material is acrylic. The blue resin 146 moves into the groove 172a of the fourth soft mold. As a result, as shown in FIG. 81, the blue color filter I 04B which has a pattern shape reversely transferred from the groove 1 72a of the fourth soft mold 170 is fonned.</p>
<p>[00661 An organic insulating material is printed over the entire surface of the substrate on which the blue color filter 104B is formed, thereby forming both a white color filter 104W and an overcoat layer 122, as shown in FIG. 8J. An organic insulating material 174 is spread over the entire surface of the upper substrate 101 on which the white color filter 104 W and the overcoat layer 122 are formed, as shown in FIG. 8K. A second etch resist solution 142 is formed on the organic insulating material 174 by a deposition method, such as nozzle spray, spinless coating or spin coating.</p>
<p>[00671 Subsequently, a fifth soft mold 176 with the groove 1 78a and the projected part 178b is aligned to the upper part of the second etch resist solution 142.</p>
<p>The groove 1 78a of the fifth soft mold corresponds to an area where a spacer is to be formed. The fifth soft mold 176 is pressed into the second etch resist 142 at about its own weight to make the surface of the projected part 178b of the fifth soft mold 176 in contact with the overcoat layer 122. The substrate 101 can be baked at a temperature of about 130 C or an ultraviolet UV ray can be irradiated onto the second etch resist solution 142 to soft-cure the second etch resist solution 142. The second etch resist solution 142 moves into the groove 178a of the fifth soft mold. As a result, as shown in FIG. 8L, the second etch resist pattern 144 that has a pattern shape reversely transferred from the groove I 78a of the fifth soft mold 176 is formed.</p>
<p>[0068] After the fifth soft mold 176 is separated from the substrate 101, the organic insulating material 174 is patterned by an etching process using the second etch resist pattern 144 as a mask, thereby forming the spacer 124, as shown in FIG. 8M.</p>
<p>Subsequently, any remaining second etch resist pattern 144 on the spacer 124 is removed by a stripping process using an eco-friendly alcoholic system, for example.</p>
<p>[0069] In this way, the fabricating method of the color filter array substrate according to the first embodiment of the present invention can pattern the thin films of the color filter array substrate using the soft mold and the etch resist without using any photolithography process. Accordingly, no expensive exposure equipment is required and the process is simplified. The precision is high and process time is short, thereby improving the manufacturing yield.</p>
<p>10070] In the color filter array substrate according to the first embodiment of the present invention, as shown in FIG. 7, a stepped difference (d) with a designated width is formed between the white color filter 104W and the overcoat layer 122. This stepped difference makes the cell gap of an area corresponding to the white color filter 104 different from a cell gap of an area corresponding to the overcoat layer 122.</p>
<p>Accordingly, the electric field between the pixel electrode and the common electrode applied to the liquid crystal can be different, so as to make the rotation angle of the liquid crystal different at different locations, which generates a picture quality deterioration, such as a stain.</p>
<p>[00711 FIG. 9 is a cross-sectional view of a color filter array substrate according to a second embodiment of the present invention. Referring to FIG. 9, the color filter array substrate according to the second embodiment of the present invention includes similar components as the color filter array substrate shown in FIG. 7 except that the overcoat layer is formed on the entire surface of the upper substrate to smooth out the surface. Accordingly, a detailed description of the similar components will be omitted.</p>
<p>100721 The overcoat layer 122 is formed to smooth out the substrate where the red, green and blue color filters 104R, 104G and 104B are formed. The overcoat 122 is formed to include the white color filter 104W. The overcoat layer 122 including the white color filter 104W can be a highly hydrophilic polymer. The highly hydrophilic polymer is a liquid pre-polymer, a liquefied polymer, or a material in which a hydrophilic radical is substituted by an acrylic system or epoxy system polymer chain that has high transmittance. Herein, the liquid pie-polymer includes an organic material, a binder and a photo initiator. The organic material is a material that has a repulsive force when in contact with the soft mold, a coloring degree that is not greater than 20 and good transparency, such as poly ethylene glycol (PEG). The binder can be a styrene acrylic monomer in which styrene co-monomer with high adherence is added to the acrylic monomer.</p>
<p>[0073) The color filter array substrate according to the second embodiment of the present invention has both a white color filter 104W and an overcoat layer 122 with a smooth surface. The cell gap is the same over the entire liquid crystal display panel.</p>
<p>Thus, picture quality deterioration due to an uneven overcoat layer can be prevented.</p>
<p>[00741 FIGs. 1 OA to 1 OD are cross-sectional views for a fabricating method of the overcoat layer including the white color filter shown in FIG. 9. As shown in FIG. 1 OA, the black matrix 102, the red, green, blue color filters I 04R, 1 04G and 1 04B are sequentially formed on the upper substrate 101. The highly hydrophilic polymer 182 is printed over the entire surface of the upper substrate 101, as shown in FIG. lOB. A flat panel soft mold 180 is aligned to the upper substrate 101 where the highly hydrophilic polymer 182 is formed, as shown in FIG. 1OC. The flat panel soft mold 180 is pressed into the highly hydrophilic polymer 182 at about its own weight. The substrate 101 can be baked at a temperature of about 130 C or an ultraviolet UV ray can be irradiated onto the highly hydrophilic polymer 182 to soft-cure the highly hydrophilic polymer 182. The UV intensity is in accordance with at least one of a photo initiator and a base material that are included in the highly hydrophilic polymer 182. For instance, the UV intensity is about 2000-2500m J/cm2 if a base material included in the highly hydrophilic polymer 182 is epoxy, and the UV intensity is about 500---l000mJ/cm2 if a base material is acrylic. Then, as shown in FIG. 1 OD, the stepped difference part of the highly hydrophilic polymer 182 becomes flat to form the overcoat layer 122 having a flat upper surface. And then, after the flat panel soft mold 180 is separated from the substrate 101, the substrate 101 is cured at about 200 C.</p>
<p>[00751 The fabricating method of the color filter array substrate according to the second embodiment of the present invention patterns the thin film of the color filter array substrate by use of the soft mold and the etch resist without using any photolithography process, and forms the overcoat layer and the white color filter at the same time. Accordingly, no expensive exposure equipment is required, and the process is simplified. The precision is high and the process time is short, thereby improving the manufacturing yield. Further, the fabricating method of the color filter array substrate according to the second embodiment of the present invention forms the overcoat layer to be flat by use of the flat panel soft mold, thereby preventing picture quality deterioration, such as stain.</p>
<p>10076] FIG. 11 is a cross-sectional view representing a color filter array substrate according to a third embodiment of the present invention. Referring to FIG. 11, the color filter array substrate according to the third embodiment of the present invention includes similar components as the color filter array substrate shown in FIG. 9 except that the overcoat layer and the spacer are integral and fonned together.</p>
<p>Accordingly, a detailed description of similar components will be omitted.</p>
<p>[0077] The overcoat layer 122 is formed to smooth the substrate where the red, green and blue color filters I 04R, I 04G, and I 04B are formed. The overcoat 122 is formed to include the white color filter 104W and the spacer 124. The overcoat layer 122 including the white color filter 104W can be a hydrophilic polymer to prevent contamination from being generated when in contact with a highly hydrophobic soft mold. The highly hydrophilic polymer is a liquid pre-polymer, a liquefied polymer, or a material in which a hydrophilic radical is substituted by an acrylic system or epoxy system polymer chain that has high transmittance. The liquid pre-polymer includes an organic material, a binder and a photo initiator. The organic material is a material that has a repulsive force when in contact with the soft mold, a coloring degree not greater than 20 and a good transparency, such as poiy ethylene glycol PEG and so on. The binder is a styrene acrylic monomer having a styrene co-monomer with high adherence added to a acrylic monomer.</p>
<p>[0078] The spacer 124 acts to maintain the cell gap between the color filter array substrate and the thin film transistor array substrate. The spacer 124 is formed of the same material as the overcoat layer 122 on the black matrix 102. The color filter array substrate according to the third embodiment of the present invention includes the white color filter 104W and the overcoat layer 122 with a smooth surface. The cell gap is the same over the entire liquid crystal display panel. Thus, picture quality deterioration due to an uneven overcoat layer can be prevented.</p>
<p>[0079) FIGs. 12A to 12D are cross-sectional views for a fabricating method of the overcoat layer including the white color filter and spacer shown in FIG. 11. As shown in FIG. 12A, the black matrix 102, the red, green, blue color filters 104R, 104G and 104B are sequentially formed on the upper substrate 101. The highly hydrophilic polymer 182 is printed over the entire surface of the upper substrate 101, as shown in FIG. 12B. A soft mold 184 having a groove 186a and a projected part 186b is aligned to the upper substrate 101 on which the highly hydrophilic polymer 182 is formed, as shown in FIG. 12C. The groove 186a of the soft mold corresponds to an area where a spacer is to be formed. The soft mold 184 is pressed into the highly hydrophilic polymer 182 at about its own weight. The substrate 101 can be baked at a temperature of about 130 C or ultraviolet UV ray is irradiated onto the highly hydrophilic polymer 182 to soft-cure the highly hydrophilic polymer 182. The UV intensity is in accordance with at least one of a photo initiator and a base material that are included in the highly hydrophilic polymer 182. For instance, the UV intensity is about 2000-2500m J/cm2 if a base material included in the highly hydrophilic polymer 182 is epoxy, and the UV intensity is about 500-1000mJ/cm2 if a base material is acrylic. Then, the highly hydrophilic polymer 182 moves into the groove 1 86a of the soft mold. As a result, as shown in FIG. 12D, the spacers 124 with a pattern shape reversely transferred from the groove 186a of the soft mold and the overcoat layer 122 including the white color filter 104W are formed. After the soft mold 184 is separated from the substrate 101, the substrate 101 is cured at about 200 C.</p>
<p>[00801 The fabricating method of the color filter array substrate according to the third embodiment of the present invention patterns the thin film of the color filter array substrate by use of the soft mold and the etch resist without using any photolithography process, and forms the overcoat layer, the white color filter and the spacer at the same time. Accordingly, no expensive exposure equipment is required and the process can be simplified. The precision is high and the process time is short, thereby improving the manufacturing yield.</p>
<p>[00811 FIG. 13 is a cross-sectional view for a color filter array substrate according to a fourth embodiment of the present invention. Referring to FIG. 13, the color filter array substrate according to the fourth embodiment of the present invention includes similar components as the color filter array substrate shown in FIG. 11 except for the overcoat layer having an opening to expose a white pixel area, and the spacer formed of the same material as the overcoat layer. The overcoat layer 122 is formed over the color filter except for an area where the white color comes through from the backlight. The overcoat layer 122 acts to compensate for the stepped difference between the red, greed and blue color filters.</p>
<p>L00821 The spacer 124 acts to maintain the cell gap between the color filter array substrate and the thin film transistor array substrate. The spacer 124 is simultaneously formed of the same material as the overcoat layer 122. At least one of the overcoat 122 and the spacer 124 is formed of highly hydrophilic polymer to prevent contamination from being generated when in contact with a highly hydrophobic soft mold. The highly hydrophilic polymer is a liquid pre-polymer, a liquefied polymer, or a material in which a hydrnnhilic radical is substituted by an acrylic system or epoxy system polymer chain that has high transmittance. Herein, the liquid pre-polymer includes an organic material, a binder and a photo initiator. The organic material is a material that has a repulsive force when in contact with the soft mold, a coloring degree not greater than 20 and good transparency, such as poly ethylene glycol (PEG). The binder is a styrene acrylic monomer in which a styrene co-monomer with high adherence is added to an acrylic monomer.</p>
<p>[0083J FIGs. 14A to 14F are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 13. As shown in FIG. 14A, the black matrix 102, the red, green, blue color filters 104R, 104G and 104B are sequentially formed on the upper substrate 101. A highly hydrophilic first polymer 198 is printed over the whole surface of the upper substrate 101, as shown in FIG. 14B. A soft mold 188 having a groove 1 90a and a projected part I 90b is aligned to the upper substrate 101 where the highly hydrophilic first polymer 198 is formed, as shown in FIG. 14C.</p>
<p>The projected part 190b of the soft mold 188 corresponds to an area where an opening in the overcoat layer is to be formed. The soft mold 188 is pressed into the highly hydrophilic first polymer 198 at about its own weight. The substrate 101 is baked at a temperature of about 130 C or an ultraviolet UV ray is irradiated onto the highly hydrophilic first polymer 198 to soft-cure the highly hydrophilic first polymer 198. The ISV intensity is in accordance with at least one of a photo initiator and a base material that are mcluded in the highly hydrophilic first polymer 198. For instance, the UV intensity is about 2000--2500m J/cm2 if a base material included in the highly hydrophilic first polymer 198 is epoxy, and the UV intensity is about 50O--100OmJ/cm2 if a base material is acrylic. Then, the highly hydrophilic first polymer 198 is separated from the projected part 190b of the soft mold. As a result, as shown in FIG. 14D, the overcoat layer 122 with an opening reversely transferred from the a projected part 1 90b of the soft mold is formed. And then, after the soft mold 188 is separated from the substrate 101, the substrate 101 is cured at about 200 C.</p>
<p>10084] A highly hydrophilic second polymer 192, as shown in FIG. 14E, is printed over the entire surface of the upper substrate 101 on which the overcoat layer 122 is formed. A soft mold 194 having a groove 1 96a and a projected part 1 96b is aligned to the upper substrate 101 on which the highly hydrophilic second polymer 192 is formed. The groove 196a of the soft mold 194 corresponds to an area wheLe a spacer is to be formed. The soft mold 194 is pressed into the highly hydrophilic second polymer 192 at about its own weight. The substrate 101 is baked at a temperature of about 130 C or an ultraviolet UV ray is irradiated onto the highly hydrophilic second polymer 192 to soft-cure the highly hydrophilic second polymer 192. The UV intensity is in accordance with at least one of a photo initiator and a base material that are included in the highly hydrophilic second polymer 192. For instance, the UV intensity is about 2000-'2500m J/cm2 if a base material included in the highly hydrophilic first polymer 198 is epoxy, and the UV intensity is about 500-l000mJ/cm2 if a base material is acrylic. The highly hydrophilic second polymer 192 moves into the groove 1 96a of the soft mold. As a result, as shown in FIG. 14F, the spacer 124 is formed with a pattern shape reversely transferred from the groove 1 96a of the soft mold. After the soft mold 194 is separated from the substrate 101, the substrate 101 is cured at about 200 C.</p>
<p>[00851 In this way, the fabricating method of the color filter array substrate according to the fourth embodiment of the present invention patterns the thin film of the color filter array substrate by use of the soft mold and the etch resist without using the photolithography process to form the white color filter and the spacer at the same time.</p>
<p>Accordingly, no expensive exposure equipment is required and the process can be simplified. The precision is high and the process time is short, thereby improving the manufacturing yield.</p>
<p>100861 Further, the liquid crystal display panel according to the present invention can be applicable to a TN mode in which a vertical electric field is formed by a common electrode formed on the upper substrate and a pixel electrode formed on the lower substrate, as well as to any IPS mode in which a horizontal electric field is formed by a common electrode and a pixel electrode formed on the lower substrate. The fabricating method of the color filter array substrate according to the present invention can form the white color filter, the spacer and the overcoat layer by using the soft mold in a vacuum stage. In this case, bubbles can be prevented from being generated when the soft mold is in contact with the highly hydrophilic polymer, which is the material of the white color filter, the spacer and the overcoat layer. Hereinafter, the color filter array substrate of the vertical alignment type liquid crystal display panel and the fabricating method thereof, and the thin film patterning apparatus according to a fifth embodiment of the present invention will be explained in detail in conjunction with FIGs. 15 to 17E.</p>
<p>[0087] FIG. 15 is a plan view of a color filter array substrate of a vertical alignment type liquid crystal display panel according to a fifth embodiment of the present invention, and FIG. 16 is a cross-sectional view representing the color filter array substrate of the vertical alignment type liquid crystal display panel, taken along line "I-I" of FIG. 15. Referring to FIGs. 15 and 16, the color filter array substrate according to the fifth embodiment of present invention includes a black matrix 102; red R, green G, blue B color filters 104; an overcoat layer 122 and a rib 134 formed on and integrated with the color filter 104; and a common electrode 106 formed to cover the rib 134, which are formed on an upper substrate 101. The black matrix 102 is formed on the upper substrate 101 in a matrix shape to define a plurality of cell areas where the color filters 104 are to be formed, and prevents light interference between adjacent cells.</p>
<p>The black matrix 102 is formed to overlap an area of the thin film transistor array substrate except for a pixel electrode. For example, the pixel electrode overlaps the gate lines, the data lines and the thin film transistors of the thin film transistor array substrate. The black matrix 102 can be an opaque resin, such as carbon black, or an opaque metal, such as chrome (Cr) or chrome oxide (CrOxICr/CrOx, CrOxJCr/CrSix).</p>
<p>100881 The color filter 104 is formed in a cell area defined by the black matrix 102. The color filter 104 realizes red R, green U and blue B. The overcoat layer 122 is formed on the color filter 104 to compensate for the stepped difference between the color filter and the black matrix 102. The overcoat layer 122 can be a highly hydrophilic polymer. The highly hydrophilic polymer is a liquid pre-polymer, a liquefied polymer, or a high molecule with a structure where a material having hydrophilic radical is substituted by an acrylic system or epoxy system polymer chain which has high transmittance. Herein, the liquid pre-polymer includes an organic material, a binder and a photo initiator. The organic material is a material that has a repulsive force when in contact with the soft mold, a coloring degree not greater than 20 and a good transparency, such as poly ethylene glycol (PEG). The binder is of styrene acrylic monomer that styrene co-monomer with high adherence is added to the acrylic monomer.</p>
<p>[0689j A rib 134 is formed of thc same material as the overcoat layer 122. The rib 134 makes the electric field, which is applied to the liquid crystal, distort so that the liquid crystal is arranged in symmetric directions centering on the rib 134. The common electrode 106 is formed on the whole surface of the upper substrate on which the overcoat layer 122 and the rib 134 are formed. A reference voltage for driving liquid crystal is applied to the common electrode 106. The color filter array substrate of the vertical alignment type liquid crystal display panel according to the fifth embodiment of the present invention is simultaneously formed of the same material as the overcoat layer 122 and the rib 134. Accordingly, the fabricating process is simplified and the manufacturing cost can be reduced.</p>
<p>E00901 FIGs. 1 7A to I 7E are cross-sectional views for a fabricating method of the color filter array substrate shown in FIG. 16. First, after an opaque resin or an opaque metal is spread over the upper substrate 101, the opaque resin or the opaque metal is patterned, thereby forming the black matrix 102 as shown in FIG. l7A. After red, green and blue resins are each spread over the upper substrate 101 where the black matrix 102 is formed, the red, green and blue resins are patterned, thereby forming the color filter.</p>
<p>100911 The highly hydrophilic polymer 182, as shown in FIG. 17B, is printed over the entire surface of the upper substrate 101 where the color filter 104 is formed, by a spin coating or slit coating method. The soft mold 184 with the groove 1 86a and the projected part 186b, as shown in FIG. 17C, is aligned to the upper substrate 101 where the highly hydrophilic polymer 182 is formed. The groove 186a of the soft mold corresponds to an area where the rib is to be formed. The soft mold 184 is formed of polydimethylsiloxane PDMS, polyurethane, cross-linked novolac resin and so on. The soft mold 184 is pressed into the highly hydrophilic polymer 182 at about its own weight. At this moment, the substrate 101 is baked at a temperature of about 130 C or an ultraviolet UV ray is irradiated onto the highly hydrophilic polymer 182, thereby soft-curing the highly hydrophilic polymer 182. The UV intensity is in accordance with at least one of a photo initiator and a base material that are included in the highly hydrophilic polymer 182. For instance, the UV intensity is about 2O00--2500m J/cm2 if a base material included in the highly hydrophilic polymer 182 is epoxy, and the UV intensity is about 500-l000mJ/cm2 if a base material is acrylic. The highly hydrophilic polymer i 82 moves inio the groove i 86a of the soil inoiu by a capillary force, whieh is generated by a pressure between the soft mold 184 and the substrate 101, and a repulsive force between the soft mold 184 and the highly hydrophilic polymer 182. As a result, as shown in FIG. 17D, the rib 134, which has a pattern shape reversely transferred from the groove I 86A of the soft mold, and the overcoat layer 122 which is in contact with the projected part 1 86b of the soft mold are fonned. And then, after the soft mold 184 is separated from the substrate 101, the substrate 101 is cured at a temperature of about 150 C.</p>
<p>[0092] A transparent conductive film, such as ITO and IZO and so on, is deposited on the entire surface of the substrate 101 on which the rib 134 and the overcoat layer 122 are simultaneously formed, thereby forming the common electrode 106, as shown in FIG. 17E.</p>
<p>[0093] The fabricating method of the color filter array substrate according to the present invention simultaneously forms the overcoat layer 122 and the rib 134 using the soft mold without using a photolithography process. Accordingly, no expensive exposure equipment is required and the process is simple. The precision is high to enable the process time, thereby improving the manufacturing yield. On the other hand, the rib 134 and the overcoat layer 122 can be formed in a vacuum state by use of the soft mold 184. In this case, bubbles can be prevented from being generated when the soft mold 184 is in contact with the highly hydrophilic polymer which is the material of the rib 134 and the overcoat layer 122.</p>
<p>10094J As described above, the fabricating method of the color filter array substrate according to the present invention forms the white color filter by use of the soft mold and the etch resist at the same time as at least any one of the spacer and the overcoat layer. Accordingly, no expensive exposure equipment is required, and the process can be simplified and the precision is high to enable the process time, thereby improving the manufacturing yield. Further, the color filter array substrate and the fabricating method thereof according to the present invention has the stepped difference between the white pixel area and the other pixel area to enable to prevent the picture quality deterioration such as stain. Further, the thin film patterning apparatus and the fabricating method of the color filter array substrate using the same according to the present invention simultaneously forms the overcoat layer and the rib, which adjusts the arrangement direction of the liquid crystal, by using the soft mold, but not Usifl ihe photo process. Accordingly, the fabricating process is simplified to improve the manufacturing yield.</p>
<p>[00951 It will be apparent to those skilled in the art that various modifications and variations can be made in a thin film patterning apparatus and method of fabricating color filter array substrate using the same of the present invention without departing from the spirit or scope of the invention. Thus, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.</p>

Claims (1)

  1. <p>CLAIMS: 1. A fabricating method of a color filter array substrate,
    comprising the steps of: forming a black matrix that defines pixel areas on a substrate; forming a color filter in the pixel areas; coating a transparent resin over the substrate where the color filter is formed; aligning a soft mold having a groove and a projection to an upper part of the substrate where the transparent resin is formed; and forming an overcoat layer by molding the transparent resin with the soft mold, and simultaneously forming a rib for each pixel area so that an arrangement direction of a liquid crystal is adjusted to be in a plurality of directions.</p>
    <p>2. The fabricating method according to claim 1, wherein the step of simultaneously forming the rib and the overcoat layer includes the steps of: pressing the soft mold, which has the groove corresponding to the rib, into the transparent resin; and forming the rib by having the transparent resin move into the groove, and forming the overcoat layer which is flat by having the surface of the soft mold in contact with the transparent resin.</p>
    <p>3. The fabricating method according to claim 2, wherein the step of pressing the soft mold, which has the groove corresponding to the rib, to the transparent resin includes the step of: pressing the soft mold into the transparent resin at about its own weight; and soft-curing the transparent resin by baking at a temperature of about 130 C for about 10 minutes to 2 hours or by irradiating an ultraviolet ray onto the transparent resin.</p>
    <p>4. The fabricating method according to claim 1, 2 or 3, wherein the transparent resin is formed of any one of a liquid pre-polymer and a liquefied polymer.</p>
    <p>5. The fabricating method according to any one previous claim, wherein the soft mold includes any one of polydimethylsiloxane PDMS, polyurethane and cross-linked novolac resin.</p>
    <p>6. A thin film patterning apparatus for fabricating a color filter array substrate which has a black matrix for preventing light leakage, a color filter for realizing color, an overcoat layer for compensating a stepped difference by the color filter, and a rib simultaneously formed of the same material as the overcoat layer for adjusting an arrangement direction of a liquid crystal, comprising: a soft mold which has a projected part formed at an area corresponding to the overcoat layer, and a groove formed at an area corresponding to the rib that projects ilutli LiIc UVC1LUdt Idyci. - 7. The thin film patterning apparatus according to claim 6, wherein the overcoat layer and the rib is formed of any one of a liquid pre-polymer and a liquefied polymer.</p>
    <p>8. The thin film patterning apparatus according to claim 7, wherein the one of the liquid pre-polymer and the liquefied polymer moves into the groove by a capillary force when in contact with the soft mold.</p>
    <p>9. The thin film patterning apparatus according to claim 6, 7 or 8, wherein the soft mold includes any one of polydimethylsiloxane PDMS, polyurethane and cross-linked novolac resin.</p>
    <p>10. A fabricating method of a color filter array substrate, comprising the steps of: forming a black matrix on a substrate; forming red, green, blue color filters on the substrate on which the black matrix is formed; forming an overcoat layer including a white color filter on the substrate on which the red, green, and blue color filters are formed; aligning a flat panel soft mold to the overcoat layer; and smoothing the overcoat layer using the flat panel soft mold.</p>
    <p>11....L.... _i_. in - 1 1. 1 ii LU11LLU1 u1L11ou autuuig LU L1dJ1JJ IV, WIICI.C1II LLIC siep ui iunuing the black matrix includes the steps of: forming an opaque layer and an etch resist on the substrate; forming an etch resist pattern by pressing a first soft mold into the etch resist, wherein the first soft mold has a groove which corresponds to the black matrix; and etching the opaque layer using the etch resist pattern as a mask.</p>
    <p>12. The fabricating method according to claim 11, wherein the first soft mold and the second soft mold is formed of a hydrophobic material.</p>
    <p>13. The fabricating method according to claim 11, wherein the step of forming the etch resist pattern includes the step of: pressing the first soft mold into the etch resist at about its own weight; and soft-curing the etch resist.</p>
    <p>14. The fabricating method according to claim 13, wherein the first soft mold and the second soft mold is formed of a hydrophobic material.</p>
    <p>15. The fabricating method according to claim 10, wherein the step of forming the red, green, blue color filters on the substrate on which the black matrix is formed includes the steps of: forming a resin, which corresponds to any one of the red, green, blue color filters, on the substrate; and forming the color filter by pressing a second soft mold into the resin, which corresponds to any one of the red, green, blue color filters, wherein the second soft mold has a groove which corresponds to the color filter.</p>
    <p>16. The fabricating method according to claim 15, wherein the first soft mold and the second soft mold is formed of a hydrophobic material.</p>
    <p>17. The fabricating method according to claim 15, wherein the step of forming the color filter by pressing the second soft mold into the resin includes the step of: nreno the e-nnd r,ft rnr,ld infr, th rpen t hs-iit ciirn 1 O---------.---------.--*----.--soft-curing the resin by baking at a temperature of about 130 C for about 10 minutes to 2 hours or by irradiating an ultraviolet ray onto the resin.</p>
    <p>18. The fabricating method according to any one of claims 10 to 17, wherein the overcoat layer includes the white color filter that is formed of a hydrophilic material.</p>
    <p>19. The fabricating method according to claim 18, wherein the overcoat layer including the white color filter is formed of one of a liquid pre-polymer and a liquefied polymer.</p>
    <p>20. The fabricating method according to claim 17, wherein the first soft mold includes one of polydimethylsiloxane PDMS, polyurethane and cross-linked novolac resin.</p>
    <p>21. A fabricating method of a color filter array substrate, comprising the steps of: forming a black matrix on a substrate; forming red, green, blue color filters on the substrate on which the black matrix is formed; coating a transparent resin over the substrate on which the red, green, blue color filters are formed; aligning a soft mold having a groove and a projection to an upper part of the substrate on which the transparent resin is formed; and simultaneously forming at least two of a white color filter, an overcoat layer and a spacer using the soft mold.</p>
    <p>22. The fabricating method according to claim 21, wherein the step of simultaneously forming the white color filter, the overcoat layer and the spacer using the soft mold includes the steps of: pressing the soft mold, which has a groove corresponding to the spacer, into the transparent resin; and forming the spacer by having the transparent resin move into the groove, and forming the overcoat layer which is flat by having the surface of the soft mold in contact with the transparent resin and includes the white color filter.</p>
    <p>23. The fabricating method according to claim 22, wherein the step of pressing the soft mold, which has a groove corresponding to the spacer, to the transparent resin includes the step of: pressing the soft mold into the transparent resin with about its own weight; soft-curing the transparent resin by baking at a temperature of about 130 C for about 10 minutes to 2 hours or by irradiating an ultraviolet ray onto the transparent resin.</p>
    <p>24. The fabricating method according to claim 21, 22 or 23, wherein the transparent resin is formed of one of a liquid pre-polymer and a liquefied polymer.</p>
    <p>25. The fabricating method according to any one of claims 21 to 24, wherein the soft mold includes one of polydimethylsiloxane PDMS, polyurethane and cross-linked novolac resin.</p>
GB0700753A 2004-11-11 2005-06-27 Thin film patterning apparatus and method of fabricating color filter array substrate using the same Expired - Fee Related GB2436007B (en)

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KR1020040092133A KR101085133B1 (en) 2004-11-11 2004-11-11 Method of Fabricating Color Filter Array Substrate
KR1020040092132A KR101085134B1 (en) 2004-11-11 2004-11-11 Thin Film Patterning Apparatus And Method Of Fabricating Color Filter Array Substrate Using The Same
GB0700753A GB2436007B (en) 2004-11-11 2005-06-27 Thin film patterning apparatus and method of fabricating color filter array substrate using the same
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GB2439639A (en) * 2006-06-29 2008-01-02 Lg Philips Lcd Co Ltd Resist for soft mold and method for fabricating liquid crystal display using the same

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JPH0363628A (en) * 1989-08-02 1991-03-19 Mitsumura Genshiyokuban Insatsujiyo:Kk Spacer and formation thereof
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JPH04324803A (en) * 1991-04-25 1992-11-13 Dainippon Printing Co Ltd Manufacture of color filter
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JPH0363628A (en) * 1989-08-02 1991-03-19 Mitsumura Genshiyokuban Insatsujiyo:Kk Spacer and formation thereof
KR20040059323A (en) * 2002-12-28 2004-07-05 엘지.필립스 엘시디 주식회사 Method and apparatus for fabrication of liquid crystal display module

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Publication number Priority date Publication date Assignee Title
GB2439639A (en) * 2006-06-29 2008-01-02 Lg Philips Lcd Co Ltd Resist for soft mold and method for fabricating liquid crystal display using the same
GB2439639B (en) * 2006-06-29 2009-06-03 Lg Philips Lcd Co Ltd Resist for soft mould and method for fabricating liquid crystal display using same
US7838196B2 (en) 2006-06-29 2010-11-23 Lg. Display Co., Ltd. Resist for soft mold and method for fabricating liquid crystal display using the same

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