GB2431929A - Amino functional siloxane-comprising surface enhancement formulation - Google Patents
Amino functional siloxane-comprising surface enhancement formulation Download PDFInfo
- Publication number
- GB2431929A GB2431929A GB0522354A GB0522354A GB2431929A GB 2431929 A GB2431929 A GB 2431929A GB 0522354 A GB0522354 A GB 0522354A GB 0522354 A GB0522354 A GB 0522354A GB 2431929 A GB2431929 A GB 2431929A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formulation
- weight
- water
- amino functional
- functional polysiloxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 238000009472 formulation Methods 0.000 title claims abstract description 43
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 title claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- -1 polysiloxane Polymers 0.000 claims abstract description 25
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 24
- 238000001035 drying Methods 0.000 claims abstract description 19
- 239000003340 retarding agent Substances 0.000 claims abstract description 19
- 239000012141 concentrate Substances 0.000 claims abstract description 18
- 239000003021 water soluble solvent Substances 0.000 claims abstract description 7
- 238000001704 evaporation Methods 0.000 claims abstract description 6
- 230000008020 evaporation Effects 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 5
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 4
- 238000010790 dilution Methods 0.000 claims abstract description 3
- 239000012895 dilution Substances 0.000 claims abstract description 3
- 239000007764 o/w emulsion Substances 0.000 claims abstract description 3
- 239000002904 solvent Substances 0.000 claims abstract 2
- 239000012071 phase Substances 0.000 claims description 16
- 239000008346 aqueous phase Substances 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- 239000012074 organic phase Substances 0.000 claims description 4
- 238000007865 diluting Methods 0.000 claims description 3
- 239000013020 final formulation Substances 0.000 claims description 3
- 239000000693 micelle Substances 0.000 claims description 2
- 241001508691 Martes zibellina Species 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002334 glycols Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910020175 SiOH Inorganic materials 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002535 acidifier Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003658 microfiber Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229960004592 isopropanol Drugs 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000007524 organic acids Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/14—Other polishing compositions based on non-waxy substances
- C09G1/16—Other polishing compositions based on non-waxy substances on natural or synthetic resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
A surface enhancement formulation which is an oil-in-water emulsion comprising at least 95% by weight water and an emulsified phase comprising 0.1-2% by weight of an amino functional polysiloxane, which is polymerisable in air on evaporation of the water. The composition further comprisies 0.05-1% by weight water soluble drying retarding agent and 0.5-3% by weight of a water soluble solvent (in which both the amino-functional polysiloxane and the drying retarding agent are soluble). Preferred drying retarding agents include glycols such as butyldiglycol, propylene glycol, ethylene glycol and butyl glycol. A preferred solvent is isopropanol. Concentrates for dilution to produce the formulation and a method for the production of the formulation are also outlined. The formulation is particularly useful for application to painted metal or painted plastics surfaces, e.g. car bodywork. When applied the formulation provides good gloss characteristics and pronounced beading of water applied to the surface.
Description
<p>SURFACE ENHANCEMENT FORMULATION</p>
<p>The present invention relates to formulations intended for use in treating a surface to enhance the properties thereof. Such formulations are referred to herein as "surface enhancement formulations". The invention relates particularly, hut by no means exclusively, to such formulations that are intended for use in treating a painted metal or painted plastics surface, e.g. on the exterior of a car or other motor vehicle. Specific examples of such surfaces are the painted metal bodywork of a vehicle or painted plastics bumpers or mirror casings (so-called "mirror backs").</p>
<p>Many motor vehicle owners take a pride in the appearance of the bodywork of their vehicle. To this end, the vehicle will be washed periodically to remove soiling material (e.g. dust or mud) deposited from the environment in which the vehicle is driven. Additionally the bodywork is generally also polished to enhance the appearance.</p>
<p>Polishing also has the effect that water deposited on the bodywork (e.g. as a result ofrain or condensation) tends to become "beaded" on the bodywork surface. This is contrast to unpolished vehicle bodywork for which such water tends to form a film and give a rather "flat" appearance to the bodywork. The beaded appearance is regarded by many vehicle owners as having some aesthetic value.</p>
<p>According to the present invention there is provided a surface enhancement formulation which is an oil-in-water emulsion comprising at least 95% by weight water and an emulsified phase containing 0.1 to 2% by weight of an amino functional polysiloxane which is polymerisable in air on evaporation of water, said composition further containing 0.05 to 1% by weight of a water soluble drying retarding agent and 0.5- 3% by weight ofa water soluble solvent ln which the amino functional polysiloxane and drying retarding agent are soluble, all percentages being based on the total weight of the formulation.</p>
<p>The formulation in accordance with the invention may he applied to a painted metal or plastics surface (particularly, hut not exclusively, on the exterior of a motor vehicle) to provide a protective coating on the surface (examples of such surfaces are given above). More particularly, the coating is formed as a result of evaporation of water and polynierisation in air of the amino functional polysiloxane. The formulation maybe applied to the surface by means of a cloth (e.g. a micro-fibre cloth) that is rubbed over the surface to spread the formulation. The presence of the drying retarding agent causes slower evaporation of water (than would otherwise be the case if the agent were not present) allowrng time for the formulation to be "worked" over the surface.</p>
<p>The resulting coating provides a number ofhenefts. Firstly, the coating provides for a greater degree of "beading" of water deposited on the surface (e.g. by rain or condensation) than is the case with many conventional polishes. Therefore the aesthetic appearance ofcar bodywork (which has water deposited thereon) is enhanced. Secondly the applied coating can provide a higher gloss level than many conventional polishes.</p>
<p>Thirdly the coating lasts longer than many conventional polishes. Fourthly there maybe a reduced tendency of soiling material (e.g. dust or mud) to adhere to the painted bodywork thus making cleaning (by washing) easier.</p>
<p>The emulsified phase may be in the form of micelles and/or have an average droplet size of less than 1,000 nrn (nanometres), more preferably less than 500 nm (nanornetres), even more preferably less than 100 nm (nanometres) and still more preferably less than 50 nm, and most preferably less than 20 nm. The average droplet size may for example be about 10 nm.</p>
<p>The amino functional polysiloxane should be one that is film fonning to provide (alter polymerisation) a coating in the form of a lacquer and is preferably present in an niciint ni( _1 / hv x,pi uh ind rnruzt rre1er2h1\I 2hrl11 (1 S_i (I / by weoht o l-,-i ii -. .J.. . ., . . . .J..</p>
<p>0.9% by weight (based on the total weight of the formulation).</p>
<p>The amino functional polysiloxane may be one which undergoes linear polymcrisation in air (as opposed to cross-linking).</p>
<p>The amino functional polysiloxane may, for example, having a molecular weight of 40,000-60,000, more preferably about 45,000-55,000, e.g. about 50,000.</p>
<p>A particularly suitable amino functional polysiloxane is an amino functional polydirnethylsi loxane.</p>
<p>A particularly suitable amino functional poly-dimethylsiloxane is available under the designation BC 93/075 from Basildon Chemical Company Ltd. The product chain extends through reactions of SiOMe -SiOH condensation and SiOH -SiOH condensation.</p>
<p>Preferably the drying retarding agent is present in the formulation in an amount of 0.1 to 0.3% by weight, e.g. about 0.2% by weight.</p>
<p>A particularly suitable drying retarding agent is butyldiglycol. Further examples include monopropylene glycol, monoethylene glycol and butyl glycol.</p>
<p>The amount of water soluble solvent will generally he in the range of 1-2% by weight, e.g. about 1.5%.</p>
<p>A particularly suitable water soluble solvent is iso-propanol. Further examples include ethanol and methanol.</p>
<p>A surface active agent will generally be present to maintain the emulsified phase.</p>
<p>The amount of the surface active agent will generally he in the range of 0.01 to 1% by ud-'inh1t rf th frrtnii1qtinn Thc' ciirfirp rtiv unt be i ncn_rnip QllrIcu'c' 1iuc' agent, e.g. as a available under the designation Berol 048 as available from Akzo Nobel.</p>
<p>Formulations in accordance with the invention may be prepared by the steps of (i) producing an organic phase by dissolving the amino functional polysiloxane and drying retarding agent in the organic solvent; (ii) producing an acidified aqueous phase containing the surface active agent; (iii) homogenising the organic phase with the aqueous phase to produce a concentrate comprising, by total weight of the concentrate, 40-80% by weight of water, 1-20% by weight ofthe amino functional polysiloxane as an emulsified phase, 0.5-10% by weight of the drying retarding agent, and 5-30% by weight of the organic solvent; and (iv) diluting the concentrate with water to produce the final formulation.</p>
<p>The aqueous phase (ii) comprises water, a surface active agent (e.g. as described above) and an acidifying agent to give the aqueous phase a preferred pH of 4 to 6 since at a pH of greater than 6 the amino functional polysiloxanc may not form an emulsified phase during subsequent steps of the process (see below). The preferred pH of the aqueous phase is 4 to 5. Most preferably the acidifying agent is an organic acid, particularly acetic acid.</p>
<p>The oil and aqueous phases ((I) and (ii) respectively) may then he homogenised using a high speed homogeniser to produce the concentrate (iii) which may subsequently 1-i;lt-l 17;t1, Mntc'r tim nrnri,icn ti-ic' 1'nni nrn-. ,.intirn (-r\ &/ 4 ii t.4Lj VYILSI WV LtL'.L LV.J.JL SLLd'.d Li I/ LiIiI I JI Ii LLLJULLJLI i V J. The following non-limiting Example illustrates preparation of a formulation in accordance with the invention.</p>
<p>Example</p>
<p>A formulation in accordance with the invention was prepared by the steps of: (a) preparing a concentrate; and (b) diluting the concentrate.</p>
<p>(a) Preparation of Concentrate An oil phase an aqueous phase were produced separately. Each phase had the following composition in which the percentages are based on the total weight of the final concentrate.</p>
<p>OIL PHASE</p>
<p>Component Amount zso-Propanol 15.0 BC 93/075 9.0 butyldiglycol 2.0 Amino functional poly-dimethylsiloxane ex Basildon Chemical Company Ltd.</p>
<p>AQUEOUS PHASE</p>
<p>Component -Amount Water 71.45 acetic acid 0.45 2 Bcrol 048 2.0 acticide BFM 0.10 2 non-ionic surfactant preservative The concentrate was prepared by high speed homogenisation. The resulting product was clear and comprised the BC 93/075 (amino functional poly-dimethylsiloxane) as an emulsified phase, believed to be micellar with an average "particle" size of about 20 nm (nanometres).</p>
<p>(b) Dilution of Concentrate The final formulation was prepared by mixing 10% by weight of the concentrate prepared as described above with 90% by weight of water.</p>
<p>The product was applied using a micro fibre cloth to the painted surface ofa motor vehicle. When dry, the formulation provided very good gloss characteristics and pronounced beading of water applied to the surface.</p>
Claims (1)
- <p>CLAIMS</p><p>1. A surface enhancement lorniulation which is an oil-in-waler emulsion compnsing at least 95% by weight water and an emulsified phase containing 0.1 1o2% by weight ofan amino functional polysiloxane which is polymeri sable in air on evaporation of water, said composition further containing 0.05 to 1% by weight of a water soluble drying retarding agent and 0.5-3% by weight of a waler soluble solvent in which the amino functional polysiloxane and drying retarding agent are soluble, all percentages being based on the total weight of the formulation.</p><p>2. A formulation as claimed in claim I wherein the emulsified phase is in the form of micelles.</p><p>3. A formulation as claimed in claim I or 2 wherein the emulsified phase has a droplet size of less than 50 nm (nanometres).</p><p>4. A formulation as claimed in claim 3 wherein the emulsified phase has a droplet size of less than 20 nm (nanometres).</p><p>5. A formulation as claimed in any one of claims 1 to 4 wherein the amino functional polysiloxane is present in an amount of 0.5-1.5% by weight.</p><p>6. A formulation as claimed in claim 5 wherein the amino functional polysiloxane is present in an amount of 0.8-1.0% by weight.</p><p>7 A G't-r-ivii,ilievii c (i1irnrrl ri%/ e,1r' fIiriic 1 lr ( f1r ryr,- .J IS./t. All .LA%S tlhAlhll.J functional polysiloxane undergoes linear polymerisation.</p><p>8. A formulation as claimed in any one of claims 1 to 7 wherein the amino functional polysiloxane has a molecular weight of 40,000-60,000.</p><p>9. A formulation as claimed in claim 8 wherein the amino functional polysiloxane has a molecular weight of 45,000-55,000.</p><p>10. A formulation as claimed in any one of claims I to 9 wherein the amino functional polysiloxane is an amino functional polydimethylsiloxane.</p><p>11. A formulation as claimed in any one of claims 1 to 9 wherein the drying retarding agent is present in an amount of 0.1 to 0.3% by weight.</p><p>12. A formulation as claimed in any one of claims I to 11 wherein the drying retarding agent is butyl diglycol.</p><p>13. A formulation as claimed in anyone of claims 1 to 12 wherein the water soluble solvent is present in an amount of 1-2% by weight.</p><p>14. A formulation as claimed in any one of claims I to 13 wherein the water soluble solvent is iso-propopanol.</p><p>15. A surface enhancement formulation which is an oil-in-water emulsion comprising at least 96% by weight water and an emulsified phase containing 0.5 to 1.5% by weight of an amino functional polysiloxane which is polymerisablc in air on evaporation of water, said composition further containing 0.1 to 0.3% by weight of a water soluble drying retarding agent and 1-2% by weight of a water soluble solvent in which the amino functional polysiloxane and drying retarding agent are soluble, all nercent;wes heim' based on the total weiht of the formulation. I.</p><p>1 6. A kit of parts comprising a formulation as claimed in any one of claims I to 15 and a cloth for application of the formulation.</p><p>17. A kit as claimed in claim I 6 wherein the cloth is a niicrofihre cloth.</p><p>18. A method of enhancing a painted metal surface comprising applying to said surface a formulation as claimed in any one of claims ito 16.</p><p>19. A method ofpreparing a formulation as claimed in claim I comprising the steps of (i) producing an organic phase by dissolving the ammo functional polysiloxane and drying retarding agent in the organic solvent; (ii) pproducing an acidified aqueous phase containing the surface active agent; (iii) homogenising the organic phase with the aqueous phase to produce a concentrate comprising, by total weight of the concentrate, 40-80% by weight of water, 1 -20% by weight of the amino functional polysiloxane as an emulsified phase, 0.5-10% by weight ofthe drying retarding agent, and 5-30% by weight of the organic solvent; and (iv) diluting the concentrate with water to produce the final formulation.</p><p>20. A concentrate for dilution to a formulation as claimed in claim I, the concentrate comprising by total weight ofthe concentrate, 40-80% by weight ofwater, 1- 20% by weight ofthe amino functional polysiloxane as an emulsified phase, 0.5-10% by weight of the drying retarding agent, and 5-30% by weight of the organic solvent.</p>
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0522354A GB2431929B (en) | 2005-11-02 | 2005-11-02 | Surface enhancement formulation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0522354A GB2431929B (en) | 2005-11-02 | 2005-11-02 | Surface enhancement formulation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB0522354D0 GB0522354D0 (en) | 2005-12-07 |
| GB2431929A true GB2431929A (en) | 2007-05-09 |
| GB2431929B GB2431929B (en) | 2010-09-01 |
Family
ID=35516204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB0522354A Active GB2431929B (en) | 2005-11-02 | 2005-11-02 | Surface enhancement formulation |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2431929B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018048342A1 (en) | 2016-09-06 | 2018-03-15 | Organoclick Ab | Method for making fluorocarbon free emulsions without using traditional surfactants/emulsifiers by emulsifying alkoxysilanes or other non-water soluble hydrophobizing agents using amino functional siloxanes and the uses thereof |
| WO2021216514A1 (en) * | 2020-04-21 | 2021-10-28 | Energizer Auto, Inc. | Rapid hydrophobic surface modification compositions and methods of use thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5716443A (en) * | 1995-12-04 | 1998-02-10 | Taiho Industries, Co., Ltd. | Surface treating agent for coating vehicles |
| DE10107772A1 (en) * | 2001-02-16 | 2002-09-05 | Christ Otto Ag | Vehicle care emulsion allowing good drying and/or hot wax application in car washes contains a cationic surfactant, solvent, silicone wax, emulsifiers, oils and water |
| US20030129420A1 (en) * | 2002-01-10 | 2003-07-10 | Schultz Michael A. | Wax-impregnated towelette |
| JP2004300387A (en) * | 2003-04-01 | 2004-10-28 | San Ai Oil Co Ltd | Gloss and water repellency-imparting composition, method for producing the same and automatic method of application |
| US20060041026A1 (en) * | 2004-08-19 | 2006-02-23 | Wacker-Chemie Gmbh | Oil-in-water emulsions of aminosiloxanes |
-
2005
- 2005-11-02 GB GB0522354A patent/GB2431929B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5716443A (en) * | 1995-12-04 | 1998-02-10 | Taiho Industries, Co., Ltd. | Surface treating agent for coating vehicles |
| DE10107772A1 (en) * | 2001-02-16 | 2002-09-05 | Christ Otto Ag | Vehicle care emulsion allowing good drying and/or hot wax application in car washes contains a cationic surfactant, solvent, silicone wax, emulsifiers, oils and water |
| US20030129420A1 (en) * | 2002-01-10 | 2003-07-10 | Schultz Michael A. | Wax-impregnated towelette |
| JP2004300387A (en) * | 2003-04-01 | 2004-10-28 | San Ai Oil Co Ltd | Gloss and water repellency-imparting composition, method for producing the same and automatic method of application |
| US20060041026A1 (en) * | 2004-08-19 | 2006-02-23 | Wacker-Chemie Gmbh | Oil-in-water emulsions of aminosiloxanes |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018048342A1 (en) | 2016-09-06 | 2018-03-15 | Organoclick Ab | Method for making fluorocarbon free emulsions without using traditional surfactants/emulsifiers by emulsifying alkoxysilanes or other non-water soluble hydrophobizing agents using amino functional siloxanes and the uses thereof |
| WO2021216514A1 (en) * | 2020-04-21 | 2021-10-28 | Energizer Auto, Inc. | Rapid hydrophobic surface modification compositions and methods of use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| GB0522354D0 (en) | 2005-12-07 |
| GB2431929B (en) | 2010-09-01 |
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