GB2396310A - Rotary device with vanes for dispersing a gas in a molten metal - Google Patents
Rotary device with vanes for dispersing a gas in a molten metal Download PDFInfo
- Publication number
- GB2396310A GB2396310A GB0229871A GB0229871A GB2396310A GB 2396310 A GB2396310 A GB 2396310A GB 0229871 A GB0229871 A GB 0229871A GB 0229871 A GB0229871 A GB 0229871A GB 2396310 A GB2396310 A GB 2396310A
- Authority
- GB
- United Kingdom
- Prior art keywords
- rotor
- gas
- roof
- shaft
- molten metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D27/00—Stirring devices for molten material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/111—Centrifugal stirrers, i.e. stirrers with radial outlets; Stirrers of the turbine type, e.g. with means to guide the flow
- B01F27/1111—Centrifugal stirrers, i.e. stirrers with radial outlets; Stirrers of the turbine type, e.g. with means to guide the flow with a flat disc or with a disc-like element equipped with blades, e.g. Rushton turbine
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
- C22B21/064—Obtaining aluminium refining using inert or reactive gases
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2331—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements
- B01F23/23311—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the introduction of the gas along the axis of the stirrer or along the stirrer elements through a hollow stirrer axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2336—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer
- B01F23/23364—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer the gas being introduced between the stirrer elements
- B01F23/233641—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer the gas being introduced between the stirrer elements at the stirrer axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/07—Stirrers characterised by their mounting on the shaft
- B01F27/072—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis
- B01F27/0725—Stirrers characterised by their mounting on the shaft characterised by the disposition of the stirrers with respect to the rotating axis on the free end of the rotating axis
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
- F27D2003/166—Introducing a fluid jet or current into the charge the fluid being a treatment gas
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Processing Of Solid Wastes (AREA)
- Coating With Molten Metal (AREA)
Abstract
A rotary device for gases such as chlorine, argon, nitrogen or a mixture of these gases in a molten metal such as aluminium has a hollow shaft (20) at one end of which is attached a rotor (22). The rotor (22) has a roof (24) and a base (26) which are spaced apart and connected by a plurality of vanes (32). A compartment (34) is defined between each adjacent pair of vanes (32) and the roof (24) and the base (26), and each compartment (34) has an inlet (36) and at least two outlets (38,40). A flow path is defined through the shaft (20) into the inlets (36) of the compartments (34) and out of the first and second outlets (38,40). Each first outlet (38) is disposed radially outwardly of the respective inlet (36) and arranged to disperse gas laterally of the rotor (22) in use so that the molten metal, is "degassed" or removed of impurities such as hydrogen gas. Each second outlet (40) is disposed in the roof (24) of the rotor (22) and arranged to disperse gas upwardly from the rotor (22) in use.
Description
239631 0
- 1 - ROTARY DEVICE FOR TREATING MOLTEN METAL
The present invention relates to a rotary device for treating a molten metal.
It is well known that the presence of dissolved gas in molten metal can introduce defects in the solidified product. For example, defects are introduced in castings and wrought products manufactured from aluminium or its alloys due to porosity arising from the presence of hydrogen gas. For example, hydrogen gas diffusing to voids and discontinuities (e.g. oxide inclusions) can result in blister formation during the production of aluminium alloy plate, sheet and strip. Other defects such as porosity in castings may also be associated with the presence of hydrogen gas.
It is common practice to treat molten aluminium and its alloys to remove hydrogen and solid impurities by flushing with a gas such as chlorine, argon, nitrogen or a mixture of these gases, the process commonly being referred to as "degassing". One way of performing the degassing is to use a hollow shaft to which a rotor is attached. In use the shaft and rotor are rotated and gas is passed down the shaft and dispersed into the molten metal via the rotor. An example of such an assembly is described in EP 0332292 (the entirety of which disclosure is included herein by reference) and shown in
Figure 1. The rotor 2 comprises a number of compartments C each of which has an inlet 9 and an outlet 10, adjacent compartments being separated by vanes 11. The rotor is characterised by having an open chamber M in its base and by having the outlets larger than the inlets. The rotor is connected to a hollow shaft via a tubular connection piece.
- 2- It is an object of the present invention to provide an improved rotary device which preferably offers one or more of the following advantages over the known devices:-
(i) higher durability and therefore longer life, (ii) more rapid degassing, and (ii) more efficient removal of solid impurities such as oxide inclusions.
According to the present invention there is provided a rotary device for dispersing a gas in a molten metal, said device comprising a hollow shaft at one end of which is a rotor, said rotor having a roof and a base, said roof and base being spaced apart and connected by a plurality of vanes, a compartment being defined between each adjacent pair of vanes and the roof and the base, each compartment having an inlet and first and second outlets, a flow path being defined through the shaft into the inlets of the compartments and out of the first and second outlets, wherein each first outlet is disposed radially outwardly of the respective inlet and arranged to disperse gas laterally of the rotor in use, and wherein each second outlet is disposed in the roof of the rotor and arranged to disperse gas upwardly from the rotor in use.
Surprisingly, the inventors have found that the combination of laterally directed and upwardly directed outlets allows smaller and more numerous bubbles of gas to be created which results in significantly more efficient degassing and cleaning compared to the device of EP 0332292 such that the rotation speed can be reduced while maintaining the same efficiency of degassing/cleaning, thereby extending the life of the shaft and rotor, or degassing/cleaning can be achieved more efficiently at the same rotor speed, providing the opportunity to reduce treatment time.
Preferably, each second outlet is a cut-out extending inwardly from the outer periphery of the roof. Conveniently, the cut-outs are part-circular or semi-
circular and are preferably arranged symmetrically around the rotor. It will of course be appreciated that the cut-outs can be of any shape and that one or more of the second outlets could alternatively be constituted by a bore (of any shape) through the roof into one of the compartments.
In a preferred embodiment, the rotor has four compartments (defined by four vanes) with eight second outlets in the form of semi-circular cutouts arranged symmetrically around the rotor (i.e. two per compartment).
However, the number of outlets may be increased (e.g. to 12 or 16) for larger rotors and reduced for smaller rotors.
Preferably, the rotor is provided with a chamber in which mixing of molten metal and gas can take place. Preferably, the chamber is located radially inwardly of the inlets, preferably has an opening,in the base of the rotor and is in the flowpath between the shaft and the inlets, such that in use when the device rotates, molten metal is drawn into the chamber through the base of the rotor where it is mixed with gas passing into the chamber from the shaft, the metal/gas dispersion then being pumped into the compartments through the inlets before being discharged from the rotor through the first and second outlets. Preferably, the first outlets have a greater cross-sectional area than the inlets.
- 4 - Preferably the rotor is circular in transverse cross section and is most preferably attached to the shaft at its centre, so as to reduce drag during rotation. Preferably, the shaft and rotor are formed separately, the two being attached together by releasable fixing means. The shaft may be connected directly to the rotor (e.g. by providing mating screw threads on each of the shaft and rotor), or indirectly, e.g. via a threaded tubular connection piece.
The rotor is conveniently formed from a solid block of material (preferably graphite), the compartments being conveniently formed by a milling operation. For the avoidance of doubt, it should be made clear that the invention resides also in the rotor per se.
The present invention further resides in a method of treating molten metal comprising the steps of: (i) immersing the rotor and part of the shaft of the device of the present invention in the molten metal to be treated, (ii) rotating the shaft, and (iii) passing gas and optionally one or more treatment substances down the shaft and into the molten metal via the rotor, whereby to degas the metal.
The nature of the molten metal is not restricted. However, preferred metals for the treatment include aluminium and all its alloys (including low silicon alloys (4-6% Si) e.g. BS alloy LM4 (Al-Si5Cu3); medium silicon alloys (7.5
- 5 - 9.5% Si) e.g. BS alloy LM25 (Al-Si7Mg); eutectic alloys (10-13% Si) e.g. BS alloy LM6 (Al-Sil2); hypereutectic alloys (> 16% Si) e.g. BS alloy LM30 (Al-Sil7Cu4Mg); aluminium magnesium alloys e.g. BS alloy LM5 (Al-MgSSil; Al-Mg6)), magnesium and its alloys (e.g. BS alloy AZ91 (8.0-
9.5% Al) and BS alloy AZ81 (7.5-9.0% Al)) and copper and its alloys (including high conductivity coppers, brasses, tin bronzes, phosphor bronzes, lead bronzes, gunmetals, aluminium bronzes and copper-nickels).
Preferably, the gas is an inert gas (such as argon or nitrogen) and is more preferably dry. Gases not traditionally regarded as being inert but having no deleterious effect on the metal may also be used such as chlorine, or a chlorinated hydrocarbon. The gas may be a mixture of two or more of the foregoing gases. From a balance between cost and inertness of the gas, dry nitrogen is preferred. The method is particularly useful for the removal of hydrogen gas from molten aluminium.
It will be understood that for any given rotor, efficiency of degassing will be determined by the speed of rotation, the gas flow rate and treatment time.
As well as degassing, the treatment may also be combined with the injection of fluxes into the melt along with the inert purge gas. The treatment is then a combined degassing/grain refinement and/or modification and/or cleaning/crossing treatment, in which case the optional treatment substance may be granulated cleaning/crossing, grain refining, modification species or a combination of these (usually referred to as "flux" or "fluxes"). Such fluxes may be titanium and/or boron salts (e.g. AlTiB alloy) for grain refining, and sodium salts or strontium (usually as 5-10% master alloy) for
- 6 - modification of aluminium-silicon alloys. Such processes are per se well known to the skilled foundryman.
The required size of the rotor, speed of rotation, gas flow rate and (optional) flux quantity will all be determined by the particular treatment being undertaken, taking into account the mass of metal being treated, the optimum treatment time and whether the process is a continuous or a batch process.
An embodiment of the invention will now be described by way of example only, with reference to the accompanying drawings in which: Figure 1 is a vertical section through a prior art rotor described in
EP0332292,
Figures 2a and 2b are respectively a perspective and a side view of a rotary device in accordance with the present invention, Figure 3 is a top plan view of the rotor of Figures 2a and 2b, and Figures 4 to 6 are graphs illustrating reduction in gas content of AlSilOMg before and after degassing with nitrogen using a rotor according to the present invention and a comparative rotor.
Referring to Figures 2 and 3, a rotary device for dispersing gas and/or other treatment substances in molten metal is shown. The device comprises a shaft 20 having a bore 20a therethrough, a rotor 22 and a tubular connection piece 23. The rotor 22 is made from graphite and is of unitary construction. The rotor 22 is generally disc-shaped and comprises an annular upper part (roof 24) and spaced therefrom an annular lower part (base 26). A threaded throughbore
- 7 - 28 is provided centrally in the roof 24 of the rotor 22 and serves in use as an attachment point for the tubular connection piece 23 which is correspondingly externally screw-threaded. An open chamber 30 is provided centrally in the base 26 of the rotor 22. The chamber 30 extends upwardly to the roof 24 of the rotor 22 and is continuous with the throughbore 28 in the roof 24, the throughbore 28 and chamber 30 thereby defining a continuous passage vertically through the rotor 22. The chamber 30 extends radially outwardly further than the throughbore 28. The roof 24 and base 26 are connected by four vanes 32 which are disposed between the roof 24 and the base 26 and which extend outwardly from the periphery of the chamber 30 to the periphery 22a of the rotor 22. A compartment 34 is defined between each pair of adjacent vanes 32, the chamber 30 and the roof 24 and the base 26.
Each compartment 34 has an inlet aperture 36 from the chamber 30 and a first outlet on the periphery 22a of the rotor 22 in the form of an elongated slot 38. The outlet slot 38 has a greater cross-sectional area than the inlet aperture 36.
As can be seen more readily in Figure 3, the peripheral edge 22a of the roof 24 of the rotor 22 is provided with a plurality (eight in this embodiment) of part-circular cut-outs 40. Each cut-out 40 serves as a second outlet for its respective compartment 34 (in this case two cutouts 40 are provided per compartment 34).
An appropriately internally screw-threaded region 20b is provided at one end of the shaft 20 for securely mounting the shaft 20 onto the connection piece 23. The opposite end of the shaft 20 is connected to the lower end of a hollow drive shaft (not shown) whose upper end is connected to drive means
- 8 - (in this case an electric motor, not shown) and the bore 20a of the shaft 20 is connected through the hollow drive shaft to a source of gas (not shown).
From the description above, it will be clear that a continuous flow path exists
from the source of gas, through the bore 20a of the shaft 20 and the connection piece 23, through the roof 24 of the rotor 22 into the chamber 30, through the inlet apertures 36 into the compartments 34 and out of the rotor 22 through the first and second outlets 38,40.
In use, the rotor and shaft assembly is immersed in the molten metal to be degassed (in for example a refractory lined ladle or other vessel) and rotated at the desired speed by activation of the electric motor. The source of gas is opened and adjusted to the desired flow rate and degassing carried out for a predetermined duration.
During degassing, gas passes down the shaft 20 into the rotor chamber 30, where it is mixed with molten metal which is drawn upwardly into the chamber 30. The gas/metal dispersion flows into the compartments 34 via the inlets 36 and exits the rotor 22 laterally through the first outlets 38 and upwardly through the second outlets 40.
Examples 1 to 3 A rotor as described above having a diameter of 190 mm was used to-degas 200 Kg of AlSilOMg alloy held at 720 C. The gas used was dry nitrogen at a flow rate of 15 L/min. The speed of rotation was 450 rpm and degassing was carried out over 5 minutes (Example 1). The effectiveness of the rotor
- 9 - was assessed by determination of the Density Index (DI) of the metal before and after treatment. DI is calculated using the formula DI Datm-D8ombar 100 Datm where Datm is the density of a sample of metal which has been allowed to solidify under atmospheric pressure and D80mbar is the density of a sample which has been allowed to solidify under a vacuum of 80mbar. The higher the DI of a sample, the greater the hydrogen gas content of the metal.
Examples 2 and 3 were performed as for Example 1, except that the rotation speed used was 350 rpm (Example 2; treatment time 5 minutes, 2 runs, Example 3; treatment time 3 minutes, 2 runs).
Comparative Examples 1 to 3 For comparison, degassing was carried out under identical conditions to the corresponding Example using a rotor identical to that of Example 1, except that the roof of the rotor was not provided with any cut-outs.
RESULTS
The results in terms of density index (DI) reduction are tabulated below and represented graphically in Figures 3 to 5 (Examples/Comparative Examples 1 to 3). Although it will be appreciated that no two batches of melt will have exactly the same starting DI, it is readily apparent that the rotor of the present invention offers a significant improvement over a comparable rotor having the cut-outs omitted. For example, from Table 2 and Figure 3, it can be seen that the DI of Example 2 (both runs) is half that of comparative example 2 after treatment, even when the starting DI is higher (run 2).
- 10- Table 1: DI (%) (degassing at 450 rpm, 15 L/min for 5 mins) Example 1 Comparative example 1 Before 8.43 10.15 After 0.38 0.76 Table 2: DI (%) (degassing at 350 rpm, 15 L/min for 5 mins) Example 2
run 1 run 2 comparative example 2 Before 4.58 6.92 5.34 After 0.38 0.38 0. 76 Table 3: DI (%) (degassing at 350 rpm, 15 L/min for 3 mins) Example 3 comparative example 3 run 1 run 2 run 1 run 2 Before 6.08 2.66 4.98 7.66 After 0 0.38 1.15 1.89 When thedegassing time is reduced the efficiency of the comparative rotor deteriorates (comparative example 3), whereas the rotor of the present invention maintains the high reduction in DI (Example 3).
Claims (17)
1. A rotary device for dispersing a gas in a molten metal, said device comprising a hollow shaft at one end of which is a rotor, said rotor having a roof and a base, said roof and base being spaced apart and connected by a plurality of vanes, a compartment being defined between each adjacent pair of vanes and the roof and the base, each compartment having an inlet and first and second outlets, a flow path being defined through the shaft into the inlets of the compartments and out of the first and second outlets, wherein each first outlet is disposed radially outwardly of the respective inlet and arranged to disperse gas laterally of the rotor in use, and wherein each second outlet is disposed in the roof of the rotor and arranged to disperse gas upwardly from the rotor in use.
2. A device as claimed in claim 1, wherein each second outlet is a cutout extending inwardly from the outer periphery of the roof.
3. A device as claimed in claim 2, wherein the cut-outs are part-circular or semi-circular and are preferably arranged symmetrically around the rotor.
4. A device as claimed in any preceding claim, wherein the rotor has four compartments (defined by four vanes) with eight second outlets in the form of semi-circular cut-outs arranged symmetrically around the rotor.
5. A device as claimed in any preceding claim, wherein the rotor is provided with a chamber in which mixing of molten metal and gas can take place.
- 12-
6. A device as claimed in claim 6, wherein the chamber is located radially inwardly of the inlets and has an opening in the base of the rotor, such that in use when the device rotates, molten metal is drawn into the chamber through the base of the rotor where it is mixed with gas passing into the chamber from the shaft, the metal/gas dispersion then being pumped into the compartments through the inlets before being discharged from the rotor through the first and second outlets.
7. A device as claimed in any preceding claim, wherein the first outlets have a greater cross-sectional area than the inlets.
8. A device as claimed in any preceding claim wherein the rotor is circular in transverse cross section and is most preferably attached to the shaft at its centre.
9. A device as claimed in any preceding claim, wherein the shaft and rotor are formed separately, the two being attached together by releasable fixing means.
10. A device as claimed in any preceding claim wherein the rotor is formed from a solid block of material, preferably graphite.
11. A method of treating molten metal comprising the steps of:-
(i) immersing the rotor and part of the shaft of the device of any one of claims 1 to 10 in the molten metal to be treated, (ii) rotating the shaft, and
- 13- (iii) passing gas and optionally one or more treatment substances down the shaft and into the molten metal via the rotor, whereby to degas the metal.
12. The method as claimed in claim 11, wherein the metal to be treated is selected from aluminium, magnesium, copper and alloys thereof.
13. The method as claimed in claim 11 or 12, wherein the gas used in step (iii) is selected from one or more of chlorine, a chlorinated hydrocarbon, nitrogen and argon.
14. The method as claimed in claim 13, wherein the gas used in step (iii) is dry nitrogen
15. The method as claimed in any one of claims 11 to 14, wherein the treatment comprises a grain refinement and/or modification and/or cleaning treatment and the optional treatment substance of step (iii) is a granulated cleaning/crossing, grain refining and/or modification species.,
16. The method as claimed in claim 15, wherein the optional treatment substance is selected from one or more of titanium salts and/or boron salts, sodium salts and strontium master alloy.
17. A rotor for use in the rotary device of any one of claims 1 to 10, said rotor comprising a roof and a base, said roof and base being spaced apart and connected by a plurality of vanes, a compartment being defined between each adjacent pair of vanes and the roof and the base, each compartment having a gas inlet and first and second gas outlets, wherein each first outlet is disposed
- 14 radially outwardly of the respective inlet and arranged to disperse gas laterally of the rotor in use, and wherein each second outlet is disposed in the roof of the rotor and arranged to disperse gas upwardly from the rotor in use.
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0229871A GB2396310A (en) | 2002-12-21 | 2002-12-21 | Rotary device with vanes for dispersing a gas in a molten metal |
ES03786125T ES2271678T3 (en) | 2002-12-21 | 2003-12-17 | DEVICE OF ROTATING AGITATION FOR THE TREATMENT OF A FUSED METAL. |
CA2511435A CA2511435C (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
MXPA05006559A MXPA05006559A (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal. |
DE60308064T DE60308064T2 (en) | 2002-12-21 | 2003-12-17 | ROTOR STIRRER FOR TREATING METAL MELTS |
AU2003295124A AU2003295124B2 (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
PT03786125T PT1573077E (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
DK03786125T DK1573077T3 (en) | 2002-12-21 | 2003-12-17 | Rotary tube device for processing molten metal |
PCT/GB2003/005492 WO2004057045A1 (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
AT03786125T ATE338147T1 (en) | 2002-12-21 | 2003-12-17 | ROTOR STIRRING DEVICE FOR TREATING METAL MELTS |
SI200330441T SI1573077T1 (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
US10/540,152 US7669739B2 (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
JP2004561626A JP2006511705A (en) | 2002-12-21 | 2003-12-17 | Rotating stirrer for processing molten metal |
EP03786125A EP1573077B1 (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
CNB2003801098774A CN100342043C (en) | 2002-12-21 | 2003-12-17 | Rotary stirring device for treating molten metal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0229871A GB2396310A (en) | 2002-12-21 | 2002-12-21 | Rotary device with vanes for dispersing a gas in a molten metal |
Publications (2)
Publication Number | Publication Date |
---|---|
GB0229871D0 GB0229871D0 (en) | 2003-01-29 |
GB2396310A true GB2396310A (en) | 2004-06-23 |
Family
ID=9950204
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0229871A Withdrawn GB2396310A (en) | 2002-12-21 | 2002-12-21 | Rotary device with vanes for dispersing a gas in a molten metal |
Country Status (14)
Country | Link |
---|---|
US (1) | US7669739B2 (en) |
EP (1) | EP1573077B1 (en) |
JP (1) | JP2006511705A (en) |
CN (1) | CN100342043C (en) |
AT (1) | ATE338147T1 (en) |
AU (1) | AU2003295124B2 (en) |
CA (1) | CA2511435C (en) |
DE (1) | DE60308064T2 (en) |
DK (1) | DK1573077T3 (en) |
ES (1) | ES2271678T3 (en) |
GB (1) | GB2396310A (en) |
MX (1) | MXPA05006559A (en) |
PT (1) | PT1573077E (en) |
WO (1) | WO2004057045A1 (en) |
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US8030082B2 (en) | 2006-01-13 | 2011-10-04 | Honeywell International Inc. | Liquid-particle analysis of metal materials |
JP5318326B2 (en) * | 2006-02-06 | 2013-10-16 | 株式会社神戸製鋼所 | Gas injection nozzle device and gas injection equipment provided with the same |
RS51225B (en) * | 2007-07-05 | 2010-12-31 | Foseco International Limited | Rotary stirring device for treating molten metal |
US9127332B2 (en) * | 2008-03-11 | 2015-09-08 | Pyrotek, Inc. | Molten aluminum refining and gas dispersion system |
CN101892379B (en) * | 2010-06-18 | 2011-05-11 | 新星化工冶金材料(深圳)有限公司 | Magnesium alloy melt stirring device |
CZ304029B6 (en) | 2012-07-02 | 2013-08-28 | Jap Trading, S. R. O. | Rotary device for refining molten metal |
CN102965497A (en) * | 2012-12-11 | 2013-03-13 | 北京矿冶研究总院 | Feeding and stirring device of hydrometallurgy reactor |
EP2756879B1 (en) * | 2013-01-22 | 2016-06-08 | Kunze, Silvia | Apparatus for introducing gas into a liquid |
US9057376B2 (en) | 2013-06-13 | 2015-06-16 | Bruno H. Thut | Tube pump for transferring molten metal while preventing overflow |
US9011117B2 (en) | 2013-06-13 | 2015-04-21 | Bruno H. Thut | Pump for delivering flux to molten metal through a shaft sleeve |
WO2016022530A1 (en) * | 2014-08-04 | 2016-02-11 | Pyrotek, Inc. | Apparatus for refining molten aluminum alloys |
GB2529449B (en) * | 2014-08-20 | 2016-08-03 | Cassinath Zen | A device and method for high shear liquid metal treatment |
GB201504296D0 (en) * | 2015-03-13 | 2015-04-29 | Univ Brunel | Method and device for melt treatment to remove excessive inclusions and impurities and unwanted gases in aluminium alloy melts |
US11066713B2 (en) | 2015-12-09 | 2021-07-20 | Tenova South Africa (Pty) Ltd | Method of operating a top submerged lance furnace |
CN106119563B (en) * | 2016-08-02 | 2018-04-17 | 宁波科达精工科技股份有限公司 | A kind of method of molten aluminum degasification |
CN106907937A (en) * | 2017-03-22 | 2017-06-30 | 珠海肯赛科有色金属有限公司 | A kind of gyratory agitation device for the gas dispersion in fusing metal |
JP6667485B2 (en) * | 2017-10-20 | 2020-03-18 | 株式会社豊田中央研究所 | Recycling method of Al alloy |
CN108057360A (en) * | 2017-12-27 | 2018-05-22 | 杨丽君 | A kind of molten metal alloy melt stirring device of vacuum automation |
JP2019178368A (en) * | 2018-03-30 | 2019-10-17 | アイシン・エィ・ダブリュ株式会社 | Aluminum alloy member and manufacturing method of aluminum alloy member |
KR20240065147A (en) | 2021-09-21 | 2024-05-14 | 포세코 인터내셔널 리미티드 | Rotary devices for molten metal processing |
CN113909451B (en) * | 2021-10-13 | 2023-09-29 | 宁波众创智能科技有限公司 | Continuous on-line degassing quantitative furnace |
WO2024062216A1 (en) * | 2022-09-23 | 2024-03-28 | Foseco International Limited | Rotary device for treating molten metal |
TWI823620B (en) * | 2022-10-14 | 2023-11-21 | 中國鋼鐵股份有限公司 | Stirring device with double rotors |
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- 2002-12-21 GB GB0229871A patent/GB2396310A/en not_active Withdrawn
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2003
- 2003-12-17 ES ES03786125T patent/ES2271678T3/en not_active Expired - Lifetime
- 2003-12-17 AU AU2003295124A patent/AU2003295124B2/en not_active Expired
- 2003-12-17 PT PT03786125T patent/PT1573077E/en unknown
- 2003-12-17 AT AT03786125T patent/ATE338147T1/en active
- 2003-12-17 MX MXPA05006559A patent/MXPA05006559A/en active IP Right Grant
- 2003-12-17 JP JP2004561626A patent/JP2006511705A/en active Pending
- 2003-12-17 CN CNB2003801098774A patent/CN100342043C/en not_active Expired - Lifetime
- 2003-12-17 EP EP03786125A patent/EP1573077B1/en not_active Expired - Lifetime
- 2003-12-17 WO PCT/GB2003/005492 patent/WO2004057045A1/en active IP Right Grant
- 2003-12-17 DK DK03786125T patent/DK1573077T3/en active
- 2003-12-17 US US10/540,152 patent/US7669739B2/en active Active
- 2003-12-17 CA CA2511435A patent/CA2511435C/en not_active Expired - Lifetime
- 2003-12-17 DE DE60308064T patent/DE60308064T2/en not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
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GB0229871D0 (en) | 2003-01-29 |
AU2003295124B2 (en) | 2009-06-11 |
PT1573077E (en) | 2006-11-30 |
JP2006511705A (en) | 2006-04-06 |
CA2511435A1 (en) | 2004-07-08 |
US7669739B2 (en) | 2010-03-02 |
CA2511435C (en) | 2010-09-07 |
MXPA05006559A (en) | 2005-08-16 |
DK1573077T3 (en) | 2007-01-02 |
WO2004057045A1 (en) | 2004-07-08 |
EP1573077A1 (en) | 2005-09-14 |
DE60308064D1 (en) | 2006-10-12 |
ES2271678T3 (en) | 2007-04-16 |
CN1754005A (en) | 2006-03-29 |
EP1573077B1 (en) | 2006-08-30 |
AU2003295124A1 (en) | 2004-07-14 |
DE60308064T2 (en) | 2007-04-12 |
ATE338147T1 (en) | 2006-09-15 |
CN100342043C (en) | 2007-10-10 |
US20090071294A1 (en) | 2009-03-19 |
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