GB2361245A - High conductivity indium-tin-oxide films - Google Patents
High conductivity indium-tin-oxide films Download PDFInfo
- Publication number
- GB2361245A GB2361245A GB0009393A GB0009393A GB2361245A GB 2361245 A GB2361245 A GB 2361245A GB 0009393 A GB0009393 A GB 0009393A GB 0009393 A GB0009393 A GB 0009393A GB 2361245 A GB2361245 A GB 2361245A
- Authority
- GB
- United Kingdom
- Prior art keywords
- layers
- oxygen
- ito
- fabricating
- electrical conductor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3694—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer having a composition gradient through its thickness
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2453—Coating containing SnO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/211—SnO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
- C03C2217/231—In2O3/SnO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/90—Other aspects of coatings
- C03C2217/91—Coatings containing at least one layer having a composition gradient through its thickness
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/155—Deposition methods from the vapour phase by sputtering by reactive sputtering
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physical Vapour Deposition (AREA)
Abstract
A transparent electrical conductor deposited upon a substrate (9) by RF sputtering and in one embodiment consisting of a plurality of layers (1-7) of Indium-Tin-Oxide in which alternate layers are oxygen enriched layers. Embodiments of the invention can be formed upon a substrate at low temperature (in the range 20 to 100{C) and the resistivity of the complete film has a relaxed dependency upon the oxygen concentration present in the deposition chamber during the formation of the oxygen enriched layers. The formation of these films is relatively simpler than methods requiring the introduction of hydrogen to the deposition chamber or the in situ measurement of the oxygen concentration during film growth. In this embodiment the film typically has a resistivity of 5x10<SP>-4</SP> L cm and a transparency of greater than 90%.
Description
2361245 1 High Conductivity Indium-Tin-Oxide Films This invention relates
to optically transparent and electrically conductive films made of Indium-Tin-Oxide and deposited by the sputtering process.
Thin films of Indium-Tin-Oxide (ITO) can be produced that possess both the properties of optical transparency and electrical conductivity in the same film at the same time. ITO films find application in forming the electrodes to optoelectronic devices such as discrete lightemitting diodes (LEDs), liquid-crystal-di splays (LCDs), organic LED displays and the like.
Prior to this invention it has been noted that for the production of low resistivity ITO films a closely controlled deposition-rate to oxygenpartial-pressure ratio has been required as set forth in Howson RP and Ridge MI, Thin Solid Films, 1981, 77, 119. Furthermore, for the production of low resistivity ITO films a low deposition-rate to oxygen- partial -pressure ratio has been required as set forth in Kawada A, Thin Solid Films, 1990, 191, 297. Consequently in the production of ITO films with reproducible film quality using the prior art control of the oxygen concentration is critical and this has led to the requirement for elaborate and expensive methods of in situ monitoring of the oxygen concentration.
Another deficiency of the prior art is that low sheet resistance and high transparency can only be made to occur together when the film is deposited over a small range of oxygen partial pressures. This deficiency is exacerbated when the film is deposited onto a substrate with the substrate temperature below 100'C. There are many applications for ITO that involve the deposition of ITO onto plastic substrates or onto semiconductor devices which cannot be heated to high temperatures. It has been noted in "Semi conducting Transparent Thin Films", Hartnagel BL et al., IOP Publishing, Bristol and Philadelphia, 1995, that a deposition technique for producing ITO films with low resistivity and high transparency upon substrates at low substrate temperature which resulted in relaxed constraints upon the process parameters would be of considerable interest.
The introduction of hydrogen in the form of hydrogen gas or as water vapour to the gas mixture in the sputtering chamber has been observed to relax the constraints upon the process parameters, particularly when the ITO was deposited at low substrate temperature. Films with resistivities of 6 x 10 -4 Ocm were deposited with the substrate at room temperature as set forth in Ishibashi S et al., J. Vac. Sci. Technol., 1990, A8, 1399.
Objects of the present invention are, amongst others, to provide a technique for the deposition of ITO films with low resistivity, of the order of 5x 10-4 flcm so that thin-films can be created that possess low sheet-resistance of the order of 500/square and hightransparency of greater than 90%. Further objects of the present invention are that the films be deposited at low substrate temperature and that the required control of the oxygen concentration be sufficiently relaxed without introducing hydrogen into the sputtering chamber so that in situ monitoring of the oxygen concentration in the chamber during sputtering is not required.
2 According to the first aspect of the present invention there is provided an optically transparent electrical conductor deposited by RF sputtering with a multi-layer structure of typically, though not limited to, between seven and thirteen layers inclusive of 1TO in which alternate layers are oxygen enriched layers.
The first aspect of the present invention also provides a method of enriching the oxygen enriched layers whereby the oxygen is introduced into the layer during the deposition of the layer by the introduction of oxygen gas into the sputtering chamber.
According to the second aspect of the present invention there is provided a method of preparing ITO films by the technique of RF sputtering whereby the properties of the film are insensitive to the exact concentration of oxygen in the chamber over the range 1% to 5% by mass during the deposition of the oxygen enriched layers.
According to the third aspect of the present invention there is provided a method of preparing ITO films by the technique of RF sputtering whereby the films are prepared with the substrate at low temperature, typically in, though not limited to, the temperature range 20 to 1 OOOC.
Figure 1 is a section through a complete film in accordance with the first embodiment of the present invention.
Figure 2 is a section through a complete film in accordance with the second embodiment of the present invention.
Figure 3 is a section through a complete film in accordance with the third embodiment of the present invention- Figure 4 is a section through a complete film in accordance with the fourth embodiment of the present invention.
A first embodiment of the invention will now be described by way of example with reference to Figure 1.
Films are deposited by sputtering sequential layers from an ITO target of composition 90% indium oxide (1n203), 10% tin oxide (Sn02) and of purity 99.99%, in an RF excited plasma in argon gas or in an RF excited plasma in a mixture of argon gas and oxygen gas.
Referring to Figure 1 the film is formed upon a suitable substrate 9, for example but not limited to, glass. Prior to starting the deposition process the chamber is evacuated to a pressure of approximately 2x 10-6 torr. Argon gas is then admitted into the chamber to a 10-2 pressure in the range 5x10- '1 1 torr. A plasma is struck in the chamber, excited by an RF source with a power of typically though not lim, ited to 20OV, --,)r a 1 00min diameter ,et. TP- film is deposited in sequential layers io,! breakin- ihe vacuum.
c 3 Layer 1 is deposited by sputtering in the argon plasma. The layer is deposited to a thickness of typically though not limited to 17nin. After layer 1 has been deposited the substrate shutter is positioned to prevent further deposition upon the substrate. Oxygen is then admitted into the chamber to a ratio of oxygen to argon of typically though not limited to the range of L99 to 5:95 by mass. The substrate shutter is then removed to allow the deposition to continue with layer 2. Layer 2 is deposited to a thickness of typically though not limited to 17nin. After layer 2 has been deposited the substrate shutter is positioned to prevent further deposition upon the substrate. The oxygen supply is then cut off and the chamber continually pumped to reduce the concentration of oxygen to below 0. 1 %. The sub strate shutter is then removed to allow the deposition to continue with layer 3. Layer 3 is deposited to a thickness of typically though not limited to 17nin. After layer 3 has been deposited the substrate shutter is then positioned to prevent further deposition upon the substrate. The oxygen supply to the chamber is restored and the oxygen concentration allowed to return to typically though not limited to 1% to 5%. The substrate shutter is then removed to allow the deposition to continue with layer 5, a second layer of oxygen enriched ITO. This sequence of operations resulting in the deposition of alternate oxygen enriched / non-oxygen enriched layers is repeated until the desired number of layers has been deposited. In this first embodiment the desired number of layers is seven and consequently the last layer deposited, layer 7, is deposited with the supply of oxygen to the chamber cut off.
In a second embodiment, referring to Figure 2, the procedure for the formation of the film is identical to the first embodiment except that the first layer deposited, layer 2, is deposited with the oxygen concentration in the sputtering chamber in the range typically 1% to 5%. Subsequent layers deposited alternate between oxygen enriched and non- oxygen enriched until the film is built up. The number of layers in this embodiment is an even number and the last layer is therefore not oxygen enriched.
In a third embodiment, referring to Figure 3, the procedure for the formation of the film is identical to the first embodiment except that the formation of the film is terminated with layer 6; a layer deposited with the oxygen concentration in the sputtering chamber in the range typically 1% to 5%. The number of layers in this embodiment is an even number.
In a forth embodiment, referring to Figure 4, the procedure for the formation of the film is identical to the first embodiment except that the first layer deposited, layer 2, is deposite dwith the oxygen concentration in the sputtering chamber in the range typically 1% to 5%, and thelformation of the film is terminated with layer 8; a layer deposited with the oxygen concentration in the sputtering chamber in the range typically 1% to 5%. The number of layers in this embodiment is an odd number.
Obviously, many modifications and variations of the present invention are possible now that the present invention has been disclosed. Therefore, it is to be understood that within the scope of the appended claims the invention may be practiced otherwise than as specifically described above.
ill.
Claims (14)
1. An optically transparent electrical conductor deposited by RF sputtering with a multilayer structure of typically, though not limited to, between seven and thirteen layers inclusive of Indium-Tin Oxide (ITO) in which alternate layers are oxygen enriched.
The transparent electrical conductor according to Claim 1 wherein said conductor comprises of an electrically conductive material formed on a substrate.
The transparent electrical conductor according to Claim 1 wherein said conductor comprises of a plurality of ITO layers with alternate layers enriched with oxygen.
4. The transparent electrical conductor according to Claim 3 wherein each of the layers is approximately 17nin thick.
The transparent electrical conductor according to Claim 3 wherein the total number of layers is between seven and thirteen inclusive.
The transparent electrical conductor according to Claim 3 where the sheet resistance of the film is below 50n per square and the transmittance of the film is greater than 90% over the visible and near infra red range.
T A method of fabricating ITO films by deposition upon a substrate.
8. A method of fabricating ITO films according to Claim 7 where the deposit consists of a Z:1 plurality of layers deposited without breaking the vacuum.
A method of fabricating ITO films according to Claim 7 whereby the method of deposition is RF sputtering.
10. A method of fabricating ITO films according to Claim 9 whereby the sputtering is via an RF excited plasma in argon gas or whereby the sputtering is via an RF excited plasma in a mixture of argon gas and oxygen gas.
11. A method of fabricating ITO films according to Claim 10 wherein the oxygen enrichment is introduced into the oxygen enriched layers ftom oxygen in the plasma during the deposition of the layer.
12. A method of fabricating ITO films according to Claim 7 whereby the ITO is sputtered from an ITO target of composition 90% indium oxide (1n203), 10% tin oxide (Sn02) and of purity 99.99%.
13. A i-nethod films according to Claim 10 in which the oxygen gas as a S --n2C 1, to /o mass.
14. A method of fabricating ITO films according to Claim 7 whereby the substrate temperature during deposition is in the approximate range 20 to 100T.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0009393A GB2361245A (en) | 2000-04-14 | 2000-04-14 | High conductivity indium-tin-oxide films |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0009393A GB2361245A (en) | 2000-04-14 | 2000-04-14 | High conductivity indium-tin-oxide films |
Publications (2)
Publication Number | Publication Date |
---|---|
GB0009393D0 GB0009393D0 (en) | 2000-06-07 |
GB2361245A true GB2361245A (en) | 2001-10-17 |
Family
ID=9890027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0009393A Withdrawn GB2361245A (en) | 2000-04-14 | 2000-04-14 | High conductivity indium-tin-oxide films |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2361245A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015034398A1 (en) | 2013-09-09 | 2015-03-12 | Общество С Ограниченной Ответственностью "Функциональные Наносистемы" | Mesh-like micro- and nanostructure and method for producing same |
WO2015183374A1 (en) * | 2014-05-30 | 2015-12-03 | Ppg Industries Ohio, Inc. | Transparent conducting indium doped tin oxide |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4345000A (en) * | 1979-12-15 | 1982-08-17 | Nitto Electric Industrial Co., Ltd. | Transparent electrically conductive film |
US4690745A (en) * | 1983-01-10 | 1987-09-01 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Targets for cathode sputtering |
US4842705A (en) * | 1987-06-04 | 1989-06-27 | Siemens Aktiengesellschaft | Method for manufacturing transparent conductive indium-tin oxide layers |
US5116479A (en) * | 1989-03-03 | 1992-05-26 | Nihon Shinku Gijutsu Kabushiki Kaisha | Process for producing transparent conductive film comprising indium oxide |
US5603778A (en) * | 1994-04-27 | 1997-02-18 | Canon Kabushiki Kaisha | Method of forming transparent conductive layer, photoelectric conversion device using the transparent conductive layer, and manufacturing method for the photoelectric conversion device |
US5605610A (en) * | 1994-12-17 | 1997-02-25 | Anelva Corporation | Method of fabricating transparent conductive ito films |
US5630918A (en) * | 1994-06-13 | 1997-05-20 | Tosoh Corporation | ITO sputtering target |
-
2000
- 2000-04-14 GB GB0009393A patent/GB2361245A/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4345000A (en) * | 1979-12-15 | 1982-08-17 | Nitto Electric Industrial Co., Ltd. | Transparent electrically conductive film |
US4690745A (en) * | 1983-01-10 | 1987-09-01 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Targets for cathode sputtering |
US4842705A (en) * | 1987-06-04 | 1989-06-27 | Siemens Aktiengesellschaft | Method for manufacturing transparent conductive indium-tin oxide layers |
US5116479A (en) * | 1989-03-03 | 1992-05-26 | Nihon Shinku Gijutsu Kabushiki Kaisha | Process for producing transparent conductive film comprising indium oxide |
US5603778A (en) * | 1994-04-27 | 1997-02-18 | Canon Kabushiki Kaisha | Method of forming transparent conductive layer, photoelectric conversion device using the transparent conductive layer, and manufacturing method for the photoelectric conversion device |
US5630918A (en) * | 1994-06-13 | 1997-05-20 | Tosoh Corporation | ITO sputtering target |
US5605610A (en) * | 1994-12-17 | 1997-02-25 | Anelva Corporation | Method of fabricating transparent conductive ito films |
Non-Patent Citations (1)
Title |
---|
DE004000664 A1 & WPI Accession no 91-216066 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015034398A1 (en) | 2013-09-09 | 2015-03-12 | Общество С Ограниченной Ответственностью "Функциональные Наносистемы" | Mesh-like micro- and nanostructure and method for producing same |
WO2015183374A1 (en) * | 2014-05-30 | 2015-12-03 | Ppg Industries Ohio, Inc. | Transparent conducting indium doped tin oxide |
CN106460154A (en) * | 2014-05-30 | 2017-02-22 | Ppg工业俄亥俄公司 | Transparent conducting indium doped tin oxide |
US9988707B2 (en) | 2014-05-30 | 2018-06-05 | Ppg Industries Ohio, Inc. | Transparent conducting indium doped tin oxide |
RU2693982C2 (en) * | 2014-05-30 | 2019-07-08 | ПиПиДжи ИНДАСТРИЗ ОГАЙО, ИНК. | Transparent conductive alloy which is alloyed with indium |
Also Published As
Publication number | Publication date |
---|---|
GB0009393D0 (en) | 2000-06-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6351068B2 (en) | Transparent conductive laminate and electroluminescence light-emitting element using same | |
US6630980B2 (en) | Transparent flexible barrier for liquid crystal display devices and method of making the same | |
JP4896854B2 (en) | Method for producing transparent conductive film | |
JPH0765954A (en) | Manufacture of electroluminescence element | |
JP2000128698A (en) | Ito material, ito film and its formation, and el element | |
Sujatha et al. | Characteristics of indium tin oxide films deposited by bias magnetron sputtering | |
KR101700884B1 (en) | Maganese tin oxide Transparent Conducting Oxide and transparent conductive film using the same and method for fabricating transparent conductive film | |
JP4622075B2 (en) | Transparent conductive material and method for producing the same | |
JP4010587B2 (en) | Transparent conductive laminate and electroluminescence light emitting device using the same | |
GB2361245A (en) | High conductivity indium-tin-oxide films | |
KR101297432B1 (en) | A transparent flexible board having layer for high flexible layer and transparency conductive layer and Manufacturing method of the same | |
JPH06251632A (en) | Transparent conductive film having high flexibility and manufacture thereof | |
KR20120071100A (en) | Method for fabricating transparent conductive film and transparent conductive film by thereof | |
JP3489844B2 (en) | Transparent conductive film and method for producing the same | |
US20140144770A1 (en) | Method of fabricating zinc oxide thin film | |
JP2000056321A (en) | Production of transparent electroconductive laminate for liquid crystal display | |
JP2001030409A (en) | Production of transparent conductive laminate | |
KR20020008352A (en) | electroluminescent dispay | |
CN114188446B (en) | Conductive glass and preparation method and application thereof | |
KR20080006812A (en) | Bi-layer ito film deposition method and bi-layer ito film prepared by the same | |
JPS6463297A (en) | El element | |
CN109075263A (en) | The deposition method of the protective film of light emitting diode | |
US4040927A (en) | Cadmium tellurite thin films | |
KR20100033434A (en) | Color filter manufacturing method, color filter, liquid crystal display device and manufacturing apparatus | |
KR100965847B1 (en) | A board having layer for preventing humidity |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |