GB229714A - Improvements in the manufacture and production of oxygenated organic compounds - Google Patents
Improvements in the manufacture and production of oxygenated organic compoundsInfo
- Publication number
- GB229714A GB229714A GB2138623A GB2138623A GB229714A GB 229714 A GB229714 A GB 229714A GB 2138623 A GB2138623 A GB 2138623A GB 2138623 A GB2138623 A GB 2138623A GB 229714 A GB229714 A GB 229714A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxides
- oxide
- mixtures
- compounds
- thorium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Catalytic materials for the manufacture of methyl alcohol or other oxygenated organic compounds by interaction of oxides of carbon and hydrogen are prepared by igniting a mixture of copper oxide and powdered aluminium either in the air or in an inert gas, or by adding an oxide of zinc, manganese, thallium, cerium, uranium, thorium or zirconium to molten potassium dichromate, breaking up the cooled mass and reducing it. Reference has been directed by the Comptroller to Specification 20488/13.ALSO:Methyl alcohol together with other oxygenated organic compounds are prepared by passing mixtures of carbon monoxide or carbon dioxide or both with hydrogen at increased temperature and pressure over a catalytic material containing non-reducible metal oxides or compounds thereof. By non-reducible metal oxides are meant those oxides which are not reduced by hydrogen or carbon monoxide or mixtures thereof under ordinary or increased pressure at temperatures up to 550 DEG C. Iron, nickel and cobalt must be excluded from the catalytic material. To the non-reducible metal oxide or oxides may be added inert materials or reducible metal oxides or the metals of the reducible or non-reducible oxides. The following are examples of the catalytic materials employed:-the oxides, hydroxides or carbonates of the alkali, alkaline earth or earth and rare earth materials (i.e. aluminium, glucinum, zirconium, thorium, cerium, &c.); mixtures or compounds of magnesia or alumina with oxides of lead, bismuth, thallium, zinc, cadmium, copper, tin, antimony, silicon, boron and titanium; potash-lime, or a mixture of caustic potash and alumina, or magnesium chromate; a mixture of lead chromate with alumina, together with a little caustic potash; magnesium or zinc oxide mixed with potassium or rubidium hydroxide or carbonate; the product obtained by igniting in the air or in an inert gas a mixture of copper oxide and powdered aluminium; mixtures of potassium, caesium or rubidium compounds with one or more oxides of uranium, aluminium, chromium, manganese, or of rare earth metals such as cerium, lanthanum, thorium, zirconium of yxttrium; mixtures or compounds of zinc oxide with oxides of aluminum, barium, rare earth metals, chromium, magnesium, manganese, tantalum, titanium, tungsten or vanadium; antimony oxide mixed with glucinum oxide; tungsten threads containing thoria; metallic molybdenum or thallium containing alumina; the product obtained by melting potassium dichromate and adding zinc oxide or an oxide of manganese, thallium, cerium, uranium, thorium or zirconium and breaking up the cooled mass, with or without subsequent leaching or reduction. The hydrogen should exceed in volume the oxides of carbon employed; the pressure should preferably be higher than 50 atmospheres and temperatures of 300-600 DEG C. are employed. The velocity of flow of the gases may vary between 5 and 200 cubic metres, calculated on atmospheric pressure, per hour for each kilogram of contact mass. Examples of the production of alcohols, chiefly methyl alcohol, are given. Reference has been directed by the Comptroller to Specification 20488/13.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2138623A GB229714A (en) | 1923-08-23 | 1923-08-23 | Improvements in the manufacture and production of oxygenated organic compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2138623A GB229714A (en) | 1923-08-23 | 1923-08-23 | Improvements in the manufacture and production of oxygenated organic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB229714A true GB229714A (en) | 1925-02-23 |
Family
ID=10162034
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2138623A Expired GB229714A (en) | 1923-08-23 | 1923-08-23 | Improvements in the manufacture and production of oxygenated organic compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB229714A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2438449A (en) * | 1946-12-20 | 1948-03-23 | Standard Oil Dev Co | Synthesis of hydrocarbons and oxygenated compounds |
US2698862A (en) * | 1951-10-15 | 1955-01-04 | Standard Oil Co | Hydrogenation of carbon monoxide utilizing an alloy catalyst |
US2787628A (en) * | 1951-03-13 | 1957-04-02 | Basf Ag | Reaction of carbon monoxide with hydrogen to form alcohols |
DE3307091A1 (en) * | 1983-03-01 | 1984-09-06 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | FUEL AND USE THEREOF |
CN114591574A (en) * | 2022-04-12 | 2022-06-07 | 瑞安市大虎鞋业有限公司 | Light wear-resistant sole material and preparation method thereof |
-
1923
- 1923-08-23 GB GB2138623A patent/GB229714A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2438449A (en) * | 1946-12-20 | 1948-03-23 | Standard Oil Dev Co | Synthesis of hydrocarbons and oxygenated compounds |
US2787628A (en) * | 1951-03-13 | 1957-04-02 | Basf Ag | Reaction of carbon monoxide with hydrogen to form alcohols |
US2698862A (en) * | 1951-10-15 | 1955-01-04 | Standard Oil Co | Hydrogenation of carbon monoxide utilizing an alloy catalyst |
DE3307091A1 (en) * | 1983-03-01 | 1984-09-06 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | FUEL AND USE THEREOF |
CN114591574A (en) * | 2022-04-12 | 2022-06-07 | 瑞安市大虎鞋业有限公司 | Light wear-resistant sole material and preparation method thereof |
CN114591574B (en) * | 2022-04-12 | 2023-07-21 | 瑞安市大虎鞋业有限公司 | Light wear-resistant sole material and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2287891A (en) | Production of hydrocarbons and their derivatives from mixtures of hydrogen and oxides of carbon | |
US2183145A (en) | Process for producing hydrocarbons | |
GB229714A (en) | Improvements in the manufacture and production of oxygenated organic compounds | |
GB229715A (en) | The synthetic manufacture of methanol | |
US2925709A (en) | Decomposition of hydrazine | |
US2472493A (en) | Catalytic dehydrogenation of alcohols | |
US3755556A (en) | Low temperature shift reaction involving an alkali metal compound anda hydrogenation dehydrogenation component | |
US1569775A (en) | Synthetic manufacture of methanol | |
US4843101A (en) | Catalyst and method for producing methanol | |
US1844963A (en) | Ammonia synthesis process | |
US4167527A (en) | Methanol oxidation/dehydrogenation over silver-gold alloy | |
US4219509A (en) | Methanol oxidation/dehydrogenation over silver-gold alloy | |
GB238319A (en) | Improvements in the manufacture and production of oxygenated organic compounds | |
GB575380A (en) | Improvements in and relating to the production of ethylene glycol | |
US2552300A (en) | Catalytic conversion of cyclohexyl formate to cyclohexanone | |
US1791568A (en) | Manufacture of oxygenated organic compounds | |
US2818418A (en) | Catalytic hydrogenation of carbon monoxide | |
GB824091A (en) | Improvements in or relating to composite metal powder | |
US2583452A (en) | Manufacture of hollow magnetite bead catalyst | |
GB240955A (en) | Improvements in the synthetic manufacture of methanol and higher alcohols | |
US2513994A (en) | Production of synthesis gas | |
US5021233A (en) | Water gas shift reaction with alkali-doped catalyst | |
US2475965A (en) | Process of preparing a copper catalyst | |
US3337327A (en) | Process for producing finely-divided metal products | |
CA1107298A (en) | Methanol oxidation/dehydrogenation over silver-gold alloy |