GB2278615A - Metal spraying - Google Patents
Metal spraying Download PDFInfo
- Publication number
- GB2278615A GB2278615A GB9311627A GB9311627A GB2278615A GB 2278615 A GB2278615 A GB 2278615A GB 9311627 A GB9311627 A GB 9311627A GB 9311627 A GB9311627 A GB 9311627A GB 2278615 A GB2278615 A GB 2278615A
- Authority
- GB
- United Kingdom
- Prior art keywords
- target
- vapour
- metallising
- technique
- deposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/14—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using spraying techniques to apply the conductive material, e.g. vapour evaporation
- H05K3/146—By vapour deposition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physical Vapour Deposition (AREA)
Abstract
A method of using metal vapour spraying in order to deposit a film of metal onto a target material, where the target material may have a relatively low melting point, and without the use of adhesives. The rate of deposition and spacing between the vapour gun and target is controlled. The deposition is carried out in ambient conditions, rather than in vacuum. It provides a quick way of laying out conducting layers, in patterns, onto materials which may have an irregular or uneven shape as illustrated in Fig 1. The target may be plastic or glass reinforced plastic. A shadow mask may be placed near or on the surface of the target material and the method finds particular application is the manufacture of printed circuits. <IMAGE>
Description
MATERIAL METALLISATION
This invention relates to a method of applying metallic films to surfaces which may be uneven, without the use of adhesives, by means of vapour deposition in air.
There are many methods in current use for applying layers of metals to other materials.
Where the target material has a relatively low melting point (say 50 to 200"C) and may be thin, then current methods dictate either the attachment of a metal film using adhesives, or the use of metal vapour/plasma deposition in a vacuum. Both of these methods have their limitations; it can be difficult to impossible to apply a metal film with adhesives to an irregularly shaped target material. The vacuum vapour deposition method does require a vacuum chamber, with consequent cost and awkwardness of application.
A method has thus been devised using commercially available metal vapour spraying equipment, operating in air and under usual environmental conditions. The rate of metal deposition and temperature of the metal vapour / liquid droplets is controlled by the nozzle diameter of the vapourising gun, the rate of feed of the stock metal, the distance from the target material, and the rate of traverse with respect to this material.
Two examples of the method will now be described, with reference to the accompanying drawing in which :
Figure 1 shows an uneven material being metallised;
Figure 2 demonstrates the use of masking to produce a matallic pattern: and
Figure 3 illustrates a possible resulting pattern.
Referring to Figure 1, the metal vapour gun 1 (gas, power and wire feed via conduit 2, mainly not shown for clarity) is suspended at an approximately fixed distance from a target material 4. The example in this figure has an uneven surface, and may be a plastic or composite, for example glass reinforced plastic, Cobex, Bextrene, or other materials which may start to soften at temperatures as low as 500 C. Even materials as thin as 0.5mm have been successfully plated; there is no reason to believe that the method of vapour spraying, with the correct distance and traverse rate may not work on any thickness of target material. The vapour gun is traversed across the surface at a constant rate.This rate and the distance from the target are critical; too far from the surface and the metal forms a film lying on the surface of the target, which may become detached.
If the gun is too close, or the traverse rate too low. then the heat from the metal vapour causes the target to distort, or in excessive cases, burn or even vapourise. Between these two extremes, the vapour striking the surface partially and locally melts the target material, thus adhering to it, without bulk heat transfer to the target material. The metal thus deposited becomes a permanent, non-removeable laver. Experiments have shown that the two parameters mentioned may be varied by about 30-40%. After the first pass, repeated passes may be made to deposit a thicker layer. The traverse rate and distance of the gun are not so critical at this stage, as the metal already deposited protects the underlying material. The resulting film displays good conduction, and may be burnished if a fine finish is required. In the drawing, the direction of traverse is indicated 3, together with the deposited layer 5.
In Figure 2, the same method is applied to a material 6, (also show in Figure 3), with a shadow mask 7 being interposed between the vapour gun 1 and the target 6.
Complicated patterns can be applied in a single pass of the gun.
Among the potential applications are printed circuit manufacture, deposition of circuits on curved loudspeaker elements, EMC screening of sonar domes, EMC screening of composite materials used in modern aircraft manufacture, metallising of composite fuel tanks as part of static electricity avoidance and coppering the hulls of boats made of plastics and composites.
Claims (5)
- A method of efficiently applying permanent metallic layers to other substances, where the target may have a relatively low melting point, and without the use of adhesives. This method makes use of metal vapour spraying, controlling the adhesion of the vapour and avoiding melting of the target by controlling the rate of deposition, and spacing between vapour gun and target. The target may be irregular in shape.
- 2 A material metallising technique as claimed in Claim 1, where a shadow mask may be placed near or on the surface of the target material, thus enabling rapid deposition of conducting patterns.
- 3 A material metallising technique as claimed in Claim 1 or Claim 2 above, whereby printed circuits may be effected on many non-conductors for purposes of either electical conduction, EMC (electro-magnetic compatability) screening, or optical effects.
- 4 A material metallising technique as claimed in claim 1 or claim 2 above, where the metal deposit is made for aesthetic reasons.
- 5 A material metallising technique as claimed in claims 1 to 4 above, where the traverse rate and height of the vapour gun may be controlled by automatic equipment or manually.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9311627A GB2278615A (en) | 1993-06-04 | 1993-06-04 | Metal spraying |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9311627A GB2278615A (en) | 1993-06-04 | 1993-06-04 | Metal spraying |
Publications (2)
Publication Number | Publication Date |
---|---|
GB9311627D0 GB9311627D0 (en) | 1993-07-21 |
GB2278615A true GB2278615A (en) | 1994-12-07 |
Family
ID=10736686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9311627A Withdrawn GB2278615A (en) | 1993-06-04 | 1993-06-04 | Metal spraying |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2278615A (en) |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB433481A (en) * | 1933-03-22 | 1935-08-15 | Joseph Barry Brennan | Improvements in and relating to electrolytic devices |
GB818184A (en) * | 1955-07-11 | 1959-08-12 | Union Carbide Corp | Method of and apparatus for flame spraying |
GB1075655A (en) * | 1963-06-21 | 1967-07-12 | Norton Co | Process for applying a refractory coating and articles comprising such a coating |
GB1248601A (en) * | 1968-11-07 | 1971-10-06 | Thermonic Sa | Electric heating elements |
US4089293A (en) * | 1976-10-29 | 1978-05-16 | Eutectic Corporation | Multiple-coordinate means for applying a metal coating to a metal substrate |
GB1540121A (en) * | 1975-01-31 | 1979-02-07 | Gates Rubber Co | Liquid heat exchanger material and method |
GB2153392A (en) * | 1984-01-11 | 1985-08-21 | Nat Res Dev | Spray deposition of metal |
GB2163182A (en) * | 1984-08-15 | 1986-02-19 | Nat Res Dev | Flow coating of metals |
EP0246596A2 (en) * | 1986-05-20 | 1987-11-25 | The Perkin-Elmer Corporation | Composite wire for wear resistant coatings |
EP0254324A1 (en) * | 1984-04-05 | 1988-01-27 | The Perkin-Elmer Corporation | A thermal spray wire |
EP0522438A1 (en) * | 1991-07-09 | 1993-01-13 | Air Products And Chemicals, Inc. | Wear resistant titanium nitride coating and methods of application |
-
1993
- 1993-06-04 GB GB9311627A patent/GB2278615A/en not_active Withdrawn
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB433481A (en) * | 1933-03-22 | 1935-08-15 | Joseph Barry Brennan | Improvements in and relating to electrolytic devices |
GB818184A (en) * | 1955-07-11 | 1959-08-12 | Union Carbide Corp | Method of and apparatus for flame spraying |
GB1075655A (en) * | 1963-06-21 | 1967-07-12 | Norton Co | Process for applying a refractory coating and articles comprising such a coating |
GB1248601A (en) * | 1968-11-07 | 1971-10-06 | Thermonic Sa | Electric heating elements |
GB1540121A (en) * | 1975-01-31 | 1979-02-07 | Gates Rubber Co | Liquid heat exchanger material and method |
US4089293A (en) * | 1976-10-29 | 1978-05-16 | Eutectic Corporation | Multiple-coordinate means for applying a metal coating to a metal substrate |
GB2153392A (en) * | 1984-01-11 | 1985-08-21 | Nat Res Dev | Spray deposition of metal |
EP0254324A1 (en) * | 1984-04-05 | 1988-01-27 | The Perkin-Elmer Corporation | A thermal spray wire |
GB2163182A (en) * | 1984-08-15 | 1986-02-19 | Nat Res Dev | Flow coating of metals |
EP0246596A2 (en) * | 1986-05-20 | 1987-11-25 | The Perkin-Elmer Corporation | Composite wire for wear resistant coatings |
EP0522438A1 (en) * | 1991-07-09 | 1993-01-13 | Air Products And Chemicals, Inc. | Wear resistant titanium nitride coating and methods of application |
Also Published As
Publication number | Publication date |
---|---|
GB9311627D0 (en) | 1993-07-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |