GB2278615A - Metal spraying - Google Patents

Metal spraying Download PDF

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Publication number
GB2278615A
GB2278615A GB9311627A GB9311627A GB2278615A GB 2278615 A GB2278615 A GB 2278615A GB 9311627 A GB9311627 A GB 9311627A GB 9311627 A GB9311627 A GB 9311627A GB 2278615 A GB2278615 A GB 2278615A
Authority
GB
United Kingdom
Prior art keywords
target
vapour
metallising
technique
deposition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9311627A
Other versions
GB9311627D0 (en
Inventor
Timothy James Fortune
Jonathan Neil Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB9311627A priority Critical patent/GB2278615A/en
Publication of GB9311627D0 publication Critical patent/GB9311627D0/en
Publication of GB2278615A publication Critical patent/GB2278615A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/10Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
    • H05K3/14Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using spraying techniques to apply the conductive material, e.g. vapour evaporation
    • H05K3/146By vapour deposition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

A method of using metal vapour spraying in order to deposit a film of metal onto a target material, where the target material may have a relatively low melting point, and without the use of adhesives. The rate of deposition and spacing between the vapour gun and target is controlled. The deposition is carried out in ambient conditions, rather than in vacuum. It provides a quick way of laying out conducting layers, in patterns, onto materials which may have an irregular or uneven shape as illustrated in Fig 1. The target may be plastic or glass reinforced plastic. A shadow mask may be placed near or on the surface of the target material and the method finds particular application is the manufacture of printed circuits. <IMAGE>

Description

MATERIAL METALLISATION This invention relates to a method of applying metallic films to surfaces which may be uneven, without the use of adhesives, by means of vapour deposition in air.
There are many methods in current use for applying layers of metals to other materials.
Where the target material has a relatively low melting point (say 50 to 200"C) and may be thin, then current methods dictate either the attachment of a metal film using adhesives, or the use of metal vapour/plasma deposition in a vacuum. Both of these methods have their limitations; it can be difficult to impossible to apply a metal film with adhesives to an irregularly shaped target material. The vacuum vapour deposition method does require a vacuum chamber, with consequent cost and awkwardness of application.
A method has thus been devised using commercially available metal vapour spraying equipment, operating in air and under usual environmental conditions. The rate of metal deposition and temperature of the metal vapour / liquid droplets is controlled by the nozzle diameter of the vapourising gun, the rate of feed of the stock metal, the distance from the target material, and the rate of traverse with respect to this material.
Two examples of the method will now be described, with reference to the accompanying drawing in which : Figure 1 shows an uneven material being metallised; Figure 2 demonstrates the use of masking to produce a matallic pattern: and Figure 3 illustrates a possible resulting pattern.
Referring to Figure 1, the metal vapour gun 1 (gas, power and wire feed via conduit 2, mainly not shown for clarity) is suspended at an approximately fixed distance from a target material 4. The example in this figure has an uneven surface, and may be a plastic or composite, for example glass reinforced plastic, Cobex, Bextrene, or other materials which may start to soften at temperatures as low as 500 C. Even materials as thin as 0.5mm have been successfully plated; there is no reason to believe that the method of vapour spraying, with the correct distance and traverse rate may not work on any thickness of target material. The vapour gun is traversed across the surface at a constant rate.This rate and the distance from the target are critical; too far from the surface and the metal forms a film lying on the surface of the target, which may become detached.
If the gun is too close, or the traverse rate too low. then the heat from the metal vapour causes the target to distort, or in excessive cases, burn or even vapourise. Between these two extremes, the vapour striking the surface partially and locally melts the target material, thus adhering to it, without bulk heat transfer to the target material. The metal thus deposited becomes a permanent, non-removeable laver. Experiments have shown that the two parameters mentioned may be varied by about 30-40%. After the first pass, repeated passes may be made to deposit a thicker layer. The traverse rate and distance of the gun are not so critical at this stage, as the metal already deposited protects the underlying material. The resulting film displays good conduction, and may be burnished if a fine finish is required. In the drawing, the direction of traverse is indicated 3, together with the deposited layer 5.
In Figure 2, the same method is applied to a material 6, (also show in Figure 3), with a shadow mask 7 being interposed between the vapour gun 1 and the target 6.
Complicated patterns can be applied in a single pass of the gun.
Among the potential applications are printed circuit manufacture, deposition of circuits on curved loudspeaker elements, EMC screening of sonar domes, EMC screening of composite materials used in modern aircraft manufacture, metallising of composite fuel tanks as part of static electricity avoidance and coppering the hulls of boats made of plastics and composites.

Claims (5)

  1. A method of efficiently applying permanent metallic layers to other substances, where the target may have a relatively low melting point, and without the use of adhesives. This method makes use of metal vapour spraying, controlling the adhesion of the vapour and avoiding melting of the target by controlling the rate of deposition, and spacing between vapour gun and target. The target may be irregular in shape.
  2. 2 A material metallising technique as claimed in Claim 1, where a shadow mask may be placed near or on the surface of the target material, thus enabling rapid deposition of conducting patterns.
  3. 3 A material metallising technique as claimed in Claim 1 or Claim 2 above, whereby printed circuits may be effected on many non-conductors for purposes of either electical conduction, EMC (electro-magnetic compatability) screening, or optical effects.
  4. 4 A material metallising technique as claimed in claim 1 or claim 2 above, where the metal deposit is made for aesthetic reasons.
  5. 5 A material metallising technique as claimed in claims 1 to 4 above, where the traverse rate and height of the vapour gun may be controlled by automatic equipment or manually.
GB9311627A 1993-06-04 1993-06-04 Metal spraying Withdrawn GB2278615A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB9311627A GB2278615A (en) 1993-06-04 1993-06-04 Metal spraying

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9311627A GB2278615A (en) 1993-06-04 1993-06-04 Metal spraying

Publications (2)

Publication Number Publication Date
GB9311627D0 GB9311627D0 (en) 1993-07-21
GB2278615A true GB2278615A (en) 1994-12-07

Family

ID=10736686

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9311627A Withdrawn GB2278615A (en) 1993-06-04 1993-06-04 Metal spraying

Country Status (1)

Country Link
GB (1) GB2278615A (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB433481A (en) * 1933-03-22 1935-08-15 Joseph Barry Brennan Improvements in and relating to electrolytic devices
GB818184A (en) * 1955-07-11 1959-08-12 Union Carbide Corp Method of and apparatus for flame spraying
GB1075655A (en) * 1963-06-21 1967-07-12 Norton Co Process for applying a refractory coating and articles comprising such a coating
GB1248601A (en) * 1968-11-07 1971-10-06 Thermonic Sa Electric heating elements
US4089293A (en) * 1976-10-29 1978-05-16 Eutectic Corporation Multiple-coordinate means for applying a metal coating to a metal substrate
GB1540121A (en) * 1975-01-31 1979-02-07 Gates Rubber Co Liquid heat exchanger material and method
GB2153392A (en) * 1984-01-11 1985-08-21 Nat Res Dev Spray deposition of metal
GB2163182A (en) * 1984-08-15 1986-02-19 Nat Res Dev Flow coating of metals
EP0246596A2 (en) * 1986-05-20 1987-11-25 The Perkin-Elmer Corporation Composite wire for wear resistant coatings
EP0254324A1 (en) * 1984-04-05 1988-01-27 The Perkin-Elmer Corporation A thermal spray wire
EP0522438A1 (en) * 1991-07-09 1993-01-13 Air Products And Chemicals, Inc. Wear resistant titanium nitride coating and methods of application

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB433481A (en) * 1933-03-22 1935-08-15 Joseph Barry Brennan Improvements in and relating to electrolytic devices
GB818184A (en) * 1955-07-11 1959-08-12 Union Carbide Corp Method of and apparatus for flame spraying
GB1075655A (en) * 1963-06-21 1967-07-12 Norton Co Process for applying a refractory coating and articles comprising such a coating
GB1248601A (en) * 1968-11-07 1971-10-06 Thermonic Sa Electric heating elements
GB1540121A (en) * 1975-01-31 1979-02-07 Gates Rubber Co Liquid heat exchanger material and method
US4089293A (en) * 1976-10-29 1978-05-16 Eutectic Corporation Multiple-coordinate means for applying a metal coating to a metal substrate
GB2153392A (en) * 1984-01-11 1985-08-21 Nat Res Dev Spray deposition of metal
EP0254324A1 (en) * 1984-04-05 1988-01-27 The Perkin-Elmer Corporation A thermal spray wire
GB2163182A (en) * 1984-08-15 1986-02-19 Nat Res Dev Flow coating of metals
EP0246596A2 (en) * 1986-05-20 1987-11-25 The Perkin-Elmer Corporation Composite wire for wear resistant coatings
EP0522438A1 (en) * 1991-07-09 1993-01-13 Air Products And Chemicals, Inc. Wear resistant titanium nitride coating and methods of application

Also Published As

Publication number Publication date
GB9311627D0 (en) 1993-07-21

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)