GB2255936A - Tungsten projectiles - Google Patents

Tungsten projectiles Download PDF

Info

Publication number
GB2255936A
GB2255936A GB9202528A GB9202528A GB2255936A GB 2255936 A GB2255936 A GB 2255936A GB 9202528 A GB9202528 A GB 9202528A GB 9202528 A GB9202528 A GB 9202528A GB 2255936 A GB2255936 A GB 2255936A
Authority
GB
United Kingdom
Prior art keywords
penetrator
tungsten
accordance
weight
acid mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9202528A
Other versions
GB9202528D0 (en
Inventor
Cornelis Taal
Rene Oudelhoven
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rheinmetall Industrie AG
NWM de Kruithoorn BV
Original Assignee
Rheinmetall GmbH
NWM de Kruithoorn BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rheinmetall GmbH, NWM de Kruithoorn BV filed Critical Rheinmetall GmbH
Publication of GB9202528D0 publication Critical patent/GB9202528D0/en
Publication of GB2255936A publication Critical patent/GB2255936A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/10Etching compositions
    • C23F1/14Aqueous compositions
    • C23F1/16Acidic compositions
    • C23F1/26Acidic compositions for etching refractory metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B12/00Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
    • F42B12/72Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material
    • F42B12/74Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the material of the core or solid body

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Powder Metallurgy (AREA)
  • ing And Chemical Polishing (AREA)
  • Weting (AREA)

Description

2 2 5 -SY 3 0 1 - TITLE ProJectiles This invention relates to a method for
the production of a penetrator projectile primarily intended for use against armour.
In DE 3438 547-C2 there is described a heat treatment process for a prealloyed two-phase tungsten powder having a high. proportion of tungsten wherein a porous pre-form of compressed powder is sintered in the solid phase, with the sintering being followed by a heat treatment of between two and ten minutes in or with a liquid phase. The heat treatment in the liquid phase causes a rounding of the tungsten particles in order to increase their strength which is not accompanied by any appreciable granular growth.
Despite the increase in the strength of the starting material of the penetrator, however, mechanical processing such as turning or grinding unavoidably causes cracks in the tungsten particles close -'L.o the surface, and these fractures propagate themselves undbr loads so that the penetrator prematurely becomes useless.
An object of this invention is to provide a simple and economical process L?y which the propagation of cracks r_ in a penetrator can be avoided.
According to this invention there is provided a method for the production of a penetrator from tungsten heavy metal, in which method outer tungsten particle layers are removed by a corrosive process from the surface of the penetrator after processing to the final external geometrical shape.
This invention is primarily based on a simple method of removing the outer tungsten layers from the surface of the penetrator after the latter has been machined. Cutting operations on the external geometry of the penetrator can cause surface cracks in individual tungsten particles. Particularly with slender penetrators having a considerable length-todiameter ratio, the cracks in the particles concerned propagate themselves under tensile stresses accompanying the firing operation, under vbrational and flexural stresses occurring during the flight and also as a result of impact with a target, so that they cause the penetrator to fail prematurely. Laboratory tests have shown that when the outer granular layers are removed by a corrosive action process in accordance with the invention the notch impact strength of the penetrator is increased by about 20%.
This invention is explained and described in greater i 1 3 detail with reference to an example and the accompanying drawings.
In the drawings:
Figure 1 shows a penetrator wherein the external surface has undergone the final processing, and Figure 2 shows an enlarged diagram of a section of the penetrator referenced 1 in Figure 1.
Figure 1 shows a penetrator 10 which is made of bungsten heavy metal and of which the outer contour has been subject to a finishing process. The penetrator has a nose 12 and is---Laperedin a rear zone 14 to enable- a. tail unit (not shown) to be secured thereto. For force transmission by means of a sabot (not shown) the central part 16 of the penetrator is provided with positive interlocking means 18 comprising, for example, screw threading or annular grooves. The penetrator 10 is produced by a cutting process from a cylindrical body. This process is accompanied by the formation of notches and cracks in tungsten particles close to the surface and when subjected to stresses the cracks propagate themselves from these particles so that the penetrator shatters prematurely. Microscopic examination shows that particles in which initial cracks occur are mainly to be found in the two uppermost layers while the processing machinery causes no damage to the layers situated lower down. This is illustrated in Figure which is an enlarged diagram of the zone 1 of the penetrator 10 which is adjacent to the surface. The reference number 22 denotes the tungsten particles which are situated in the top two layers and which have suffered initial cracking, while the number 24 indicates the undamaged tungsten particles in the layers lower down.
According to this invention two layers are etched away from the surface of the penetrator. A chemical erosion process which has proved particularly advantageous is one with which the choice of acid mixture and the time for which it reacts with the penetrator material enables a certain defined rate of surface removal to be achieved.
The element tungsten is highly acid-resi-Sting. The maximum attack on the material is effected by a mixture of nitric acid (HNO3) and hydrofluoric acid (HF), the rate of removal depending largely on the concentration. A mixed acid of 50% by weight of HF and 50% by weight of HNO3 for example, is found to attack the heavy metal structure excessively, so that a corrosion process intended to ensure a defined rate of removal is difficult to control. An easily controllable reaction, on the 0 other hand, can be achieved by the use of the acid with a composition of 90% by weight of HF (industrial purity) and 10% by weight of HNO3 (industrial purity) for the corrosive processing.
During the said corrosion operation the acid mixture is at a temperature of between 20 and 50o C. This offers the advantage of enabling any change in the original strength properties in consequence of thermal action on the material to be avoided. The removal of material from the surface is governed not only by the composition of the acid mixture but also by the reaction time. For the corrosive removal of at least two tungsten granular layers, corresponding to a reduction of 100,,mrri in a penetrator of 120 mm calibre, a suitable time d be about 3 for the reaction with the acid mixture minutes. The penetrator is then rinsed under running water, and any tungsten particles not adhering thereto are removed with a brush.
6

Claims (7)

1. Method for the production of a penetrator from tungsten heavy metal, in which method outer tungsten particle layers are removed by a corrosive process from the surface of the penetrator after processing to the final external geometrical shape.
2. Method in accordance with Claim 1, wherein at least two tungsten particle layers are etched away from the surface.
3. Method in accordance with Claim 'L or 2, wherein the corrosion process is effected chemically.
4. Method in accordance with any one of Claims 1, 2 or 3, wherein the corrosive process is carried out at a temperature of between 20 and 50o C.
5. Method in accordance with any one of the preceding claims, wherein the penetrator which has been finally processed in the required external geometry is immersed in an acid mixture, removed from the said mixture after a preselected period and rinsed with water, any tungsten particles riot adhering to the surface of the penetrator being removed from the said surface by brushing.
6. Method in accordance with any preceding claim, wherein the corrosive process is effected by an acid mixture prepared from 1-0% by weight of HNOs and 90% by weight of HF.
7. Method for the production of a penetrator substantially as described herein and exemplified with reference to the drawings.
8 A penetrator produced by the method of any preceding claim.
GB9202528A 1991-04-23 1992-02-06 Tungsten projectiles Withdrawn GB2255936A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19914113177 DE4113177C2 (en) 1991-04-23 1991-04-23 Process for making a penetrator

Publications (2)

Publication Number Publication Date
GB9202528D0 GB9202528D0 (en) 1992-03-25
GB2255936A true GB2255936A (en) 1992-11-25

Family

ID=6430147

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9202528A Withdrawn GB2255936A (en) 1991-04-23 1992-02-06 Tungsten projectiles

Country Status (2)

Country Link
DE (1) DE4113177C2 (en)
GB (1) GB2255936A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8580188B2 (en) 2005-10-18 2013-11-12 Rheinmetall Waffe Munition Gmbh Method for producing a penetrator

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005021982B4 (en) * 2005-05-12 2007-04-05 Rheinmetall Waffe Munition Gmbh Process for the preparation of a penetrator

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3232803A (en) * 1963-04-16 1966-02-01 North American Aviation Inc Chemical etching of tungsten
GB1074203A (en) * 1963-06-24 1967-06-28 Egyesuelt Izzolampa Polishing the surface of tungsten bodies
DE2534213A1 (en) * 1975-07-31 1977-02-17 Licentia Gmbh Alkaline hexacyanoferrate etch soln. - contains a silicate for etching and forming chromium, molybdenum and tungsten
US4353780A (en) * 1980-10-01 1982-10-12 United Technologies Corporation Chemical milling of high tungsten content superalloys
DE3438547C2 (en) * 1984-10-20 1986-10-02 Dornier System Gmbh, 7990 Friedrichshafen Heat treatment process for pre-alloyed, two-phase tungsten powder
DE3932383C2 (en) * 1989-09-28 1995-01-05 Rheinmetall Gmbh Projectile body

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8580188B2 (en) 2005-10-18 2013-11-12 Rheinmetall Waffe Munition Gmbh Method for producing a penetrator

Also Published As

Publication number Publication date
DE4113177C2 (en) 1993-10-21
GB9202528D0 (en) 1992-03-25
DE4113177A1 (en) 1992-10-29

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)