GB2250215A - A catalytic converter - Google Patents

A catalytic converter Download PDF

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Publication number
GB2250215A
GB2250215A GB9025991A GB9025991A GB2250215A GB 2250215 A GB2250215 A GB 2250215A GB 9025991 A GB9025991 A GB 9025991A GB 9025991 A GB9025991 A GB 9025991A GB 2250215 A GB2250215 A GB 2250215A
Authority
GB
United Kingdom
Prior art keywords
catalytic converter
matrix
passages
converter according
side walls
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9025991A
Other versions
GB9025991D0 (en
Inventor
Geoffrey Keene Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MG Rover Group Ltd
Original Assignee
MG Rover Group Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MG Rover Group Ltd filed Critical MG Rover Group Ltd
Priority to GB9025991A priority Critical patent/GB2250215A/en
Publication of GB9025991D0 publication Critical patent/GB9025991D0/en
Publication of GB2250215A publication Critical patent/GB2250215A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/9454Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2853Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/14Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2310/00Selection of sound absorbing or insulating material
    • F01N2310/14Wire mesh fabric, woven glass cloth or the like
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/02Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2892Exhaust flow directors or the like, e.g. upstream of catalytic device
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)

Abstract

A catalytic converter includes a matrix (15) comprising a metal substrate formed by rolling corrugated strip (19) interleaved with smooth strip (21) to form a plurality of passages (18). The cross-sectional area of each passage in a central portion of the matrix is less than that of each passage closer to the side walls. <IMAGE>

Description

A CATALYTIC CONVERTER The invention relates to catalytic converters for the exhaust gas of internal combustion engines.
Catalytic converters are required to ensure the complete combustion of carbon monoxide and hydrocarbons and to chemically reduce oxides of nitrogen. A known type of catalytic converter includes a matrix comprising a substrate in the form of a regular solid of uniform cross-section having a plurality of longitudinally extending passages lying parallel to the side walls of the matrix, each passage having a catalytically active coating or layer.
In the known type of catalytic converter the passages are of uniform size and distribution. This creates an uneven flow distribution, with the greater flow concentrated in the passages in a central portion further from the side walls of the matrix. This leads to greater attrition of the catalyst in the passages in the central portion, either due to abrasion or due to temperature effects which lock the catalyst below the surface of the active coating.
The present invention provides a catalytic converter including a matrix comprising a substrate in the form of a regular solid of uniform cross-section and having a plurality of longitudinally extending passages parallel to the side walls of the matrix, each passage having a catalytically active coating or layer, wherein the cross-sectional area of each passage in a central portion of the matrix is less than the cross-sectional area of each passage closer to the side walls.
The catalytic converter according to the invention gives a more even flow distribution and, by better matching of the passage area to the flow requirements, allows the converter to be designed with a lower pressure drop and more economic utilisation of costly catalysts.
Preferably the cross-section of the passages reduces progressively from the side walls towards the centre of the matrix.
The substrate may be formed from an extrusion, eg of a ceramic material. Alternatively, the substrate is formed from corrugated strip, interleaved with a smooth strip.
The strips may be metallic or ceramic and may be formed by rolling the strips to form a volute. The amplitude and/or pitch of the corrugations may progressively increase from the centre of the volute.
The invention will now be described by way of example and with reference to the accompanying drawings, of which: Figure 1 is a longitudinal cross-section through a catalytic converter according to the invention, and Figure 2 is a cross-section on the line Il-Il in Figure 1 on a slightly enlarged scale.
The catalytic converter 11 is of generally conventional construction. A metal casing 12 has inlet and outlet ducts 13 and 14 respectively and houses two matrices 15 and 16 insulated from the casing 12 by fibrous mats 17.
The first matrix 15 is formed from corrugated metal strip 19 interleaved with smooth metal strip 21, the strips being rolled into a volute to form a substrate with a plurality of longitudinally extending passages 18. In Figure 2 parts of the first matrix 15 are shown magnified to illustrate this construction which is generally known, whereas in Figure 1 the passages 18 are shown diagrammatically as cutaway portions of the matrix 15.
The walls of each passage 18 are lined with a catalytically active coating or layer, typically comprising a platinum group metal so that in use hot exhaust gases from an internal combustion engine pass through the passages and the harmful contents are converted to innocuous gases.
In a conventional matrix of the construction outlined, the corrugations are of equal pitch and amplitude to give a density of passages 18 (often referred to as the cell density) in the region of 300 per square inch (46 per square cm) and this is the construction of the second matrix 16. However, in the first matrix 15 the corrugations are of progressively increasing amplitude and pitch the further the passages are from the centre of the volute.
This is illustrated in Figure 2 by the magnified region A near the centre of the matrix 15 and the magnified region B near the side wall 22 of the matrix. These are drawn to the same scale but not to any particular magnification.
In the centre of the first matrix 15 the passages have a cell density of 300 per square inch (46 cells/cm2) but at the outside the cell density is 100 per square inch 2 (15 cells/cm ) , a passage nominal cross-sectional area of 2.15mm2 on the inside and 6.70mm2 on the outside.
However, it is envisaged that the passages in the central region could have a cell density in the range 200 to 500 2 per square inch (31 to 77 cells/cm ) and the passages closer to the side walls a cell density in the range 50 to 200 per square inch (8 to 31 cells/cm2) Instead of being fabricated from metal strip the substrate could be formed from ceramic extrusions. These may take the same form as the substrates of matrices 15 and 16 or, more likely, would be monolith extrusions with square section passages.
The variation in cross-sectional area of the passages 18 in the first matrix 15 gives a more even flow distribution so that the second matrix 16 can be of conventional construction with a uniform cell density. However, it may be beneficial to provide for a variable cell density in the second matrix or to make it identical to the first matrix to benefit from rationalisation of components.
Instead of the corrugations increasing progressively in amplitude and pitch they may increase in pitch only, for example if the corrugations are produced by bending knives. Alternatively, two or more distinct regions may be produced by using two or more corrugating rollers of different pitch and/or amplitude over separate portions of the corrugated strip.

Claims (8)

1. A catalytic converter including a matrix comprising a substrate in the form of a regular solid of uniform cross-section and having a plurality of longitudinally extending passages parallel to the side walls of the matrix, each passage having a catalytically active coating or layer, wherein the cross-sectional area of each passage in a central portion of the matrix is less than the cross-sectional area of each passage closer to the side walls.
2. A catalytic converter according to Claim 1, wherein the cross-section of the passages reduces progressively from the side walls towards the centre of the matrix.
3. A catalytic converter according to Claim 1 or Claim 2, wherein the substrate is formed from an extrusion.
4. A catalytic converter according to Claim 1 or Claim 2, wherein the substrate is formed from corrugated strip interleaved with smooth strip.
5. A catalytic converter according to Claim 4, wherein the substrate is formed by rolling the strips to form a volute.
6. A catalytic converter according to Claim 5 when dependent from Claim 2, wherein the corrugations are of progressively increasing amplitude and/or pitch from the centre of the volute.
7. A catalytic converter according to any preceding claim, wherein the passages in the central portion have a cell density in the range 31 to 77 cells/cm2 and the passages closer to the side walls have a cell 2 density in the range 8 to 31 cells/cm2.
8. A catalytic converter substantially as described herein with reference to the drawings.
GB9025991A 1990-11-29 1990-11-29 A catalytic converter Withdrawn GB2250215A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB9025991A GB2250215A (en) 1990-11-29 1990-11-29 A catalytic converter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9025991A GB2250215A (en) 1990-11-29 1990-11-29 A catalytic converter

Publications (2)

Publication Number Publication Date
GB9025991D0 GB9025991D0 (en) 1991-01-16
GB2250215A true GB2250215A (en) 1992-06-03

Family

ID=10686204

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9025991A Withdrawn GB2250215A (en) 1990-11-29 1990-11-29 A catalytic converter

Country Status (1)

Country Link
GB (1) GB2250215A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000052311A1 (en) * 1999-03-01 2000-09-08 Emitec Gesellschaft Für Emissionstechnologie Mbh Catalytic converter unit with catalyst substrate and device and method for producing same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2066692A (en) * 1979-11-27 1981-07-15 Bremshey Ag Producing catalytic reactor matrix by sintering metal strips
EP0243952A1 (en) * 1986-04-29 1987-11-04 Kemira Oy A method for manufacturing and reinforcing a catalytic unit intended for purifying exhaust gases
US4740408A (en) * 1985-01-21 1988-04-26 Ngk Insulators, Ltd. Ceramic honeycomb body

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2066692A (en) * 1979-11-27 1981-07-15 Bremshey Ag Producing catalytic reactor matrix by sintering metal strips
US4740408A (en) * 1985-01-21 1988-04-26 Ngk Insulators, Ltd. Ceramic honeycomb body
EP0243952A1 (en) * 1986-04-29 1987-11-04 Kemira Oy A method for manufacturing and reinforcing a catalytic unit intended for purifying exhaust gases

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000052311A1 (en) * 1999-03-01 2000-09-08 Emitec Gesellschaft Für Emissionstechnologie Mbh Catalytic converter unit with catalyst substrate and device and method for producing same

Also Published As

Publication number Publication date
GB9025991D0 (en) 1991-01-16

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