GB2245001A - Catalyst compositions containing metal ion-exchanged zeolites - Google Patents
Catalyst compositions containing metal ion-exchanged zeolites Download PDFInfo
- Publication number
- GB2245001A GB2245001A GB9012991A GB9012991A GB2245001A GB 2245001 A GB2245001 A GB 2245001A GB 9012991 A GB9012991 A GB 9012991A GB 9012991 A GB9012991 A GB 9012991A GB 2245001 A GB2245001 A GB 2245001A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zeolite
- metal
- catalyst composition
- zinc
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000010457 zeolite Substances 0.000 title claims description 101
- 239000003054 catalyst Substances 0.000 title claims description 92
- 239000000203 mixture Substances 0.000 title claims description 68
- 229910052751 metal Inorganic materials 0.000 title claims description 27
- 239000002184 metal Substances 0.000 title claims description 27
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 94
- 229910021536 Zeolite Inorganic materials 0.000 claims description 87
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 33
- 239000011701 zinc Substances 0.000 claims description 30
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 28
- 229910052725 zinc Inorganic materials 0.000 claims description 28
- 238000005342 ion exchange Methods 0.000 claims description 26
- 229910021645 metal ion Inorganic materials 0.000 claims description 26
- 229910052759 nickel Inorganic materials 0.000 claims description 24
- 239000011159 matrix material Substances 0.000 claims description 21
- 229910052720 vanadium Inorganic materials 0.000 claims description 20
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000005336 cracking Methods 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 238000002161 passivation Methods 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 229910052733 gallium Inorganic materials 0.000 claims description 7
- 229910052732 germanium Inorganic materials 0.000 claims description 7
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052738 indium Inorganic materials 0.000 claims description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 229910052718 tin Inorganic materials 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical group [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 4
- 238000005899 aromatization reaction Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000009849 deactivation Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005194 fractionation Methods 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000571 coke Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- -1 offretite Inorganic materials 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002910 rare earth metals Chemical class 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 239000012013 faujasite Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000269350 Anura Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9012991A GB2245001A (en) | 1990-06-11 | 1990-06-11 | Catalyst compositions containing metal ion-exchanged zeolites |
| EP19910305241 EP0461851A3 (en) | 1990-06-11 | 1991-06-11 | Fcc processing using catalyst compositions containing metal ion-exchanged zeolites |
| IN172BO1991 IN172882B (enrdf_load_stackoverflow) | 1990-06-11 | 1991-06-11 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9012991A GB2245001A (en) | 1990-06-11 | 1990-06-11 | Catalyst compositions containing metal ion-exchanged zeolites |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB9012991D0 GB9012991D0 (en) | 1990-08-01 |
| GB2245001A true GB2245001A (en) | 1991-12-18 |
Family
ID=10677419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9012991A Withdrawn GB2245001A (en) | 1990-06-11 | 1990-06-11 | Catalyst compositions containing metal ion-exchanged zeolites |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0461851A3 (enrdf_load_stackoverflow) |
| GB (1) | GB2245001A (enrdf_load_stackoverflow) |
| IN (1) | IN172882B (enrdf_load_stackoverflow) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6846403B2 (en) | 1998-12-28 | 2005-01-25 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US6974787B2 (en) | 1998-08-31 | 2005-12-13 | Exxonmobil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US20020153283A1 (en) | 1998-12-28 | 2002-10-24 | Arthur W Chester | Gasoline sulfur reduction in fluid catalytic cracking |
| US6852214B1 (en) | 1998-08-31 | 2005-02-08 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US7803267B2 (en) | 1998-12-28 | 2010-09-28 | W. R. Grace & Co.-Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| US7507686B2 (en) | 2002-12-03 | 2009-03-24 | W. R. Grace & Co. - Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| US8084383B2 (en) * | 2004-03-16 | 2011-12-27 | W.R. Grace & Co.-Conn. | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
| JP5982496B2 (ja) * | 2011-11-21 | 2016-08-31 | ビーエーエスエフ コーポレーション | 不動態化／捕捉方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1982003225A1 (en) * | 1981-03-19 | 1982-09-30 | Wayne H Beck | Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion |
| EP0063712A2 (en) * | 1981-04-10 | 1982-11-03 | Ashland Oil, Inc. | Immobilisation of vanadium deposited on catalytic materials during conversion of oil containing coke precursors and heavy metals |
| US4363720A (en) * | 1981-05-13 | 1982-12-14 | Standard Oil Company (Indiana) | Passivating metals on cracking catalysts with zinc |
| EP0073874A1 (en) * | 1981-03-19 | 1983-03-16 | Ashland Oil, Inc. | Immobilisation of vanadia deposited on catalytic materials during the conversion of oil that contains coke precursors and heavy metals |
| EP0158969A1 (en) * | 1984-04-13 | 1985-10-23 | Phillips Petroleum Company | Metal passivation additive |
| WO1988008872A1 (en) * | 1987-05-05 | 1988-11-17 | Chevron Research Company | Method for suppressing the poisoning effects of contaminant metals on cracking catalysts in fluid catalytic cracking |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3804780A (en) * | 1972-03-15 | 1974-04-16 | Mobil Oil Corp | Catalyst of zinc-rare earth exchanged zeolite |
| US4153534A (en) * | 1975-12-19 | 1979-05-08 | Standard Oil Company (Indiana) | Catalytic cracking with reduced emission of noxious gases |
| US4083807A (en) * | 1976-01-13 | 1978-04-11 | Gulf Research & Development Company | Method for preparing crystalline aluminosilicate cracking catalysts |
| BR8100953A (pt) * | 1980-04-14 | 1982-01-12 | Grace W R & Co | Aperfeicoamento em processo para craquear cataliticamente hidrocarbonetos |
-
1990
- 1990-06-11 GB GB9012991A patent/GB2245001A/en not_active Withdrawn
-
1991
- 1991-06-11 EP EP19910305241 patent/EP0461851A3/en not_active Withdrawn
- 1991-06-11 IN IN172BO1991 patent/IN172882B/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1982003225A1 (en) * | 1981-03-19 | 1982-09-30 | Wayne H Beck | Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion |
| EP0073874A1 (en) * | 1981-03-19 | 1983-03-16 | Ashland Oil, Inc. | Immobilisation of vanadia deposited on catalytic materials during the conversion of oil that contains coke precursors and heavy metals |
| EP0063712A2 (en) * | 1981-04-10 | 1982-11-03 | Ashland Oil, Inc. | Immobilisation of vanadium deposited on catalytic materials during conversion of oil containing coke precursors and heavy metals |
| US4363720A (en) * | 1981-05-13 | 1982-12-14 | Standard Oil Company (Indiana) | Passivating metals on cracking catalysts with zinc |
| EP0158969A1 (en) * | 1984-04-13 | 1985-10-23 | Phillips Petroleum Company | Metal passivation additive |
| WO1988008872A1 (en) * | 1987-05-05 | 1988-11-17 | Chevron Research Company | Method for suppressing the poisoning effects of contaminant metals on cracking catalysts in fluid catalytic cracking |
Also Published As
| Publication number | Publication date |
|---|---|
| IN172882B (enrdf_load_stackoverflow) | 1993-12-25 |
| EP0461851A2 (en) | 1991-12-18 |
| EP0461851A3 (en) | 1992-04-29 |
| GB9012991D0 (en) | 1990-08-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |