GB2228824A - Radiation detectors - Google Patents

Radiation detectors Download PDF

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Publication number
GB2228824A
GB2228824A GB8904649A GB8904649A GB2228824A GB 2228824 A GB2228824 A GB 2228824A GB 8904649 A GB8904649 A GB 8904649A GB 8904649 A GB8904649 A GB 8904649A GB 2228824 A GB2228824 A GB 2228824A
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United Kingdom
Prior art keywords
radiation
radiation detector
detector
layers
quantum well
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GB8904649A
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GB8904649D0 (en
Inventor
Steven Richard Andrews
Michael Joseph Kelly
Cyril Hilsum
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General Electric Co PLC
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General Electric Co PLC
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Priority to GB8904649A priority Critical patent/GB2228824A/en
Publication of GB8904649D0 publication Critical patent/GB8904649D0/en
Publication of GB2228824A publication Critical patent/GB2228824A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Light Receiving Elements (AREA)

Abstract

An infrared detector (1) for detecting radiation of different wavelengths (e.g. 3 mu m and 10 mu m) comprises a number of detector sections (2, 3) connected in series, the sections being made operable separately by application of a control voltage to the selected section. The current flow through the series circuit is monitored, and the current level will be dominated by the photocarriers generated by the 3 mu m radiation or the 10 mu m radiation impinging on the detector, in dependence upon which of the sections is selected for operation. The detector may comprise a stack of alternating layers (5, 6; 8, 9) of semiconductor materials of different band gaps (e.g. AlGaAs and GaAs) forming a multiple quantum well structure. Alternatively, the detector may comprise a number of superlattice structures in series. In each case, the layer structure of each section determines the wavelength to which the section responds. <IMAGE>

Description

Radiation Detectors This invention relates to radiation detectors, and particularly to detectors for infrared wavelengths.
The detection of an object in a static scene or in a moving scene by detecting thermal radiation from the object at lOpm wavelength is well-known. A number of detection devices have been proposed, including devices which involve the use of narrow bandgap II-VI semiconductors, such as CdHgTe alloys. Such devices suffer from a number of problems. Firstly, it is difficult to grow crystals which are of satisfactory quality and which can sustain the various processing steps which are needed to fabricate useful devices.
Furthermore, wafer integration of these delicate devices with the semiconductor devices required for signal processing is difficult.
It has therefore been proposed to produce a long-wavelength infrared photo detector device based on the principle of inter-subband absorption in multiple quantum wells in III-V semiconductor devices.
Such devices have the advantages over the Group Il-Vi devices that (i) the materials system used, such as GaAs/AlGaAs, is more mature and the required signal processing devices are available, and (ii) the precise conditions for the absorption can be tailored by, for example, varying the width of the quantum wells and the aluminium composition in the barriers. Such devices operate only at a single radiation wavelength.
It is an object of the present invention to provide an improved radiation detector which is capable of detecting radiation of a plurality of different wavelengths.
According to the invention there is provided a radiation detector comprising first and second radiation-responsive devices electrically connected together in series and operative to pass current therethrough in response to radiation impinging thereon, said first and second devices being responsive to first and second radiation wavelengths, respectively, which are different from each other, one or the other of said devices being selectable for operation, as required, by the application of a control voltage to that device.
Preferably, the first and second devices are formed as a single structure, which structure is preferably monolithic.
Embodiments of the invention will now be described, by way of example, with reference to the accompanying drawing, in which Figure 1 shows a schematic cross section of a two-frequency multiple quantum well radiation detector in accordance with the invention, and Figure 2 shows a schematic cross section of a two-frequency superlattice radiation detector in accordance with the invention.
Referring to Figure 1, a first two-frequency radiation detector 1 comprises first and second multiple quantum well (MQW) structures 2 and 3, separated by a relatively thick n+ doped GaAs layer 4 of, say, at least 100nm thickness.
The MQW structure 2 comprises four GaAs layers 5 of 6nm thickness interleaved with five AlGaAs layers 6 of IOnm or greater thickness and of 23.5% Al composition. The thickness of each layer is such that the wells are not significantly intercoupled. This constitutes a detector for infrared radiation of 10pom wavelength.
The structure 2 is formed on a semi-insulating GaAs substrate 14, with an intervening n+ doped GaAs contact layer 7 of thickness greater than 100nm.
The MQW structure 3 comprises four GaAs layers 8 of 3.2nm thickness, interleaved with five AlGaAs layers 9 of lOnm or greater thickness and of 80% Al composition. This constitutes a detector for infrared radiation of 3pm wavelength.
A layer 10 of nf GaAs of thickness greater than 100nm is deposited over the upper AlGaAs layer, and an ohmic contact 11 is formed thereon. Ohmic contacts 12 and 13 are also provided on the GaAs layers 7 and 4, respectively.
Each of the quantum wells is arranged so that the lowest confined state is bound and, due to doping, is occupied. The first excited state is arranged to have an extra energy of 0.12eV equivalent to the energy of 10pm radiation. This excited state is arranged to be close to the conduction band energy of the confining barrier. In other realisations, this energy may be just below or just above the barrier height. The barrier height is determined by the fractional Al composition and is approximately given by 0.65 x 1.24 x X eV, where 1.24 is the factor by which the total bandgap of subscripts increases with X, and 0.65 being the proportion of this increase associated with the conduction band.The use of a simple parabolic bandstructure for GaAs shows that a well width of 6.0nm and 23.5% Al composition in the barriers provides for the excited level to be coincident with the top of the barrier. The same calculation shows that a 3.2nm wide well with 80% Al composition in the barriers gives a structure in which the excited level is now 0.41eV above the lowest level, i.e. is equivalent to the energy of 3ym radiation, and still has its excited energy close to the top of the potential barrier.
In operation of the detector, a bias voltage is applied to the contacts 12 and 13 or to the contacts 13 and 11 and the total current through the structure is monitored. Depending upon whether the bias is applied across the structure 3 or the structure 2, the monitored current will be dominated by the photocarriers generated by the 3pm or the 10pm radiation impinging thereon.
Although four GaAs layers 5 and five AlGaAs layers 6 are provided in the above-described embodiment, any desired number of GaAs layers, from one upwards, may be used, provided that each GaAs layer is bounded by two AlGaAs layers.
Referring to Figure 2, a second two-frequency radiation detector comprises two superlattice structures 15 and 16, separated by an n+ doped GaAs collector layer 17, the structures being supported by a semi-insulating substrate 30.
The structure 15 comprises four or more periods of alternate n doped GaAs layers 18 of 70t thickness and undoped AlxGa1#As barrier layers 19 of 20t thickness. In the latter layers x = 0.3. The barrier layers 19 are sufficiently thin so that the adjacent GaAs layers 12 are strongly coupled. A layer 20 of AlxGal xAs of thickness greater than 1000 and in which x = 0.3, prevents transport between the lowest miniband and the collector layer. This structure constitutes a detector for 10pom wavelength radiation, calculated assuming a parabolic band structure. An n+AlxGa1#xAs contact layer 21 (where x#0.05) is interposed between the structure 15 and the substrate 30.
The structure 16 comprises a layer 22 of AlAs of thickness greater than 10nm followed by at least four periods of alternate n+ doped GaAs layers 23 of 30R thickness and undoped AlAs layers 24 of 200 thickness. The layer 22 ensures a low dark current by impeding conduction via the first miniband. This structure constitutes a detector for 3#m wavelength radiation. The highest energy miniband is arranged to have an energy near the bulk AlAs conduction band. A contact layer 25 of n+AlxGa1#xAs (where x#0.22) is deposited on the uppermost layer of the structure 16, followed by a contact layer 26 of n+GaAs.
In the structures 15 and 16 the maximum number of superlattice periods should not exceed the diffusion length in the upper miniband.
Ohmic contacts 27, 28 and 29 are formed on the layers 21, 17 and 26, respectively.
In operation of the detector, a bias voltage is applied to the contacts 27 and 28 or to the contacts 28 and 29, and the total current through the detector is monitored. Depending upon whether the bias is applied across the structure 15 or across the structure 16, the monitored current will be dominated by the photocarriers generated by the 10ym radiation or the 3#m radiation impinging thereon.
The latter embodiment using superlattices has some possible advantages over the multiple quantum well configuration. The superlattice configuration is more tolerant to variation in growth parameters than the MQW configuration, so the correct operating wavelength is more readily achieved. Furthermore, the superlattice configuration possibly has lower noise and more tailorable bandwidth than the MQW configuration.
It will be appreciated that each of the above-described embodiments provides an easily fabricated and easily operated two-frequency infrared detection. In order to change the frequency detected it is merely necessary to switch over the d.c. bias voltage from one MQW or superlattice structure to the other.
Although the detectors in the above-described embodiments are constructed to detect 3pm and 10pm wavelength radiation, it would be possible to construct detectors to detect radiation of other wavelengths.
Further MQW or superlattice structures could be added, to make the detector switchable between three or more frequencies.
Although a detector is conveniently fabricated as a single unit as described above, it would be possible to provide two or more separate sections, such as the structures 2 and 3 or the structures 15 and 16, either side-by-side on a substrate or even on separate substrates. The sections must, of course, be electrically connected in series.
Other semiconductor materials could be used for the layers 5, 6 and 8, 9 in the above embodiments, provided that the alternate layers have different bandgaps such that a sufficiently large conduction band discontinuity exists to support intersubband or interminiband transitions, as the case may be.
In order that the structures can function efficiently as detectors, the radiation must be coupled into the structures in such a way that there is a component of the electric field vector perpendicular to the planes of the layers, so that intersubband and interminiband absorption of the radiation can take place. The method of coupling the radiation into the structures, and the number of layers used, should be optimised to ensure efficient absorption, so as to obtain high responsivity of the device.

Claims (15)

1. A radiation detector comprising first and second radiation-responsive devices electrically connected together in series and operative to pass current therethrough in response to radiation impinging thereon, said first and second devices being responsive to first and second radiation wavelengths, respectively, which are different from each other, one or the other of said devices being selectable for operation, as required, by the application of a control voltage to that device.
2. A radiation detector as claimed in Claim 1, wherein said first and second radiation-responsive devices together constitute a single structure.
3. A radiation detector as claimed in Claim 1 or Claim 2, wherein said first and second radiation-responsive devices are of monolithic construction.
4. A radiation detector as claimed in any preceding claim, wherein said first radiation-responsive device comprises a multiple quantum well structure.
5. A radiation detector as claimed in any preceding claim, wherein said second radiation-responsive device comprises a multiple quantum well structure.
6. A radiation detector as claimed in Claim 4 or Claim 5, wherein the or each multiple quantum well structure comprises alternating layers of semiconductor materials having mutually different band gaps whereby a sufficiently large conduction band discontinuity exists to support intersubband transitions.
7. A radiation detector as claimed in Claim 6, wherein the or each multiple quantum well structure comprises layers of AlGaAs interleaved with layers of GaAs.
8. A radiation detector as claimed in Claim 7, comprising two of said multiple quantum well structures separated by a layer of n+ doped AlGaAs.
9. A radiation detector as claimed in any one of Claims 1-3, wherein said first radiation-responsive device comprises a first superlattice structure.
10. A radiation detector as claimed in any one of Claims 1, 2, 3 or 9 wherein said second radiation-responsive device comprises a second superlattice structure.
11. A radiation detector as claimed in Claim 9 or Claim 10, wherein the or each superlattice structure comprises alternating layers of semiconductor materials having mutually different band gaps whereby a sufficiently large conduction band discontinuity exists to support interminiband transitions.
12. A radiation detector as claimed in Claim 11, wherein said first superlattice structure comprises at least four periods of alternate layers of n doped GaAs and undoped AlxGa1#xAs.
13. A radiation detector as claimed in Claim 12, wherein x = 0.3.
14. A radiation detector as claimed in Claim 11, wherein said second superlattice structure comprises at least four periods of alternate layers of n doped GaAs and undoped AlAs.
15. A radiation detector substantially as hereinbefore described with reference to Figure 1 or Figure 2 of the accompanying drawing.
GB8904649A 1989-03-01 1989-03-01 Radiation detectors Withdrawn GB2228824A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5329136A (en) * 1993-04-30 1994-07-12 At&T Bell Laboratories Voltage-tunable photodetector
US5479032A (en) * 1994-07-21 1995-12-26 Trustees Of Princeton University Multiwavelength infrared focal plane array detector
US5539206A (en) * 1995-04-20 1996-07-23 Loral Vought Systems Corporation Enhanced quantum well infrared photodetector
US5552603A (en) * 1994-09-15 1996-09-03 Martin Marietta Corporation Bias and readout for multicolor quantum well detectors
FR2766919A1 (en) * 1997-07-30 1999-02-05 Schlumberger Services Petrol Hydrostatic pressure and-or temperature transducer useful for oil well pressure sensor
US6054718A (en) * 1998-03-31 2000-04-25 Lockheed Martin Corporation Quantum well infrared photocathode having negative electron affinity surface
DE102005001280A1 (en) * 2004-09-30 2006-04-13 Osram Opto Semiconductors Gmbh radiation detector
US7525083B2 (en) 2004-09-30 2009-04-28 Osram Opto Semiconductors Gmbh Radiation detector with an epitaxially grown semiconductor body
WO2009094966A2 (en) 2008-01-31 2009-08-06 Osram Opto Semiconductors Gmbh Radiation receptor, and method for the production thereof

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GB1220333A (en) * 1967-08-09 1971-01-27 Parnall & Sons Ltd Improvements for electrical circuits
GB1290637A (en) * 1970-06-29 1972-09-27
GB1414169A (en) * 1971-10-05 1975-11-19 Eastman Kodak Co Photoelectric transducer
GB1519466A (en) * 1974-09-17 1978-07-26 Northern Telecom Ltd Photodiode detector
GB2030359A (en) * 1978-07-21 1980-04-02 Sumitomo Electric Industries Integrated multi-photodiodes
US4238760A (en) * 1978-10-06 1980-12-09 Recognition Equipment Incorporated Multi-spectrum photodiode devices
GB2082763A (en) * 1980-07-31 1982-03-10 Zeiss Jena Veb Carl Infrared-sensitive Multiple Photon Detector
GB2136202A (en) * 1983-03-02 1984-09-12 Int Standard Electric Corp Photodiode
US4513305A (en) * 1982-12-06 1985-04-23 Gte Laboratories Incorporated Multi-wavelength demultiplexer for fiber optical communication
EP0146375A2 (en) * 1983-12-19 1985-06-26 Kabushiki Kaisha Toshiba Visible/infrared imaging device with stacked cell structure
GB2164792A (en) * 1984-07-24 1986-03-26 Sharp Kk A semiconductor device
US4656109A (en) * 1984-09-19 1987-04-07 Fuji Electric Co., Ltd. Layered solid state color photosensitive device

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1220333A (en) * 1967-08-09 1971-01-27 Parnall & Sons Ltd Improvements for electrical circuits
GB1290637A (en) * 1970-06-29 1972-09-27
GB1414169A (en) * 1971-10-05 1975-11-19 Eastman Kodak Co Photoelectric transducer
GB1519466A (en) * 1974-09-17 1978-07-26 Northern Telecom Ltd Photodiode detector
GB2030359A (en) * 1978-07-21 1980-04-02 Sumitomo Electric Industries Integrated multi-photodiodes
US4238760A (en) * 1978-10-06 1980-12-09 Recognition Equipment Incorporated Multi-spectrum photodiode devices
GB2082763A (en) * 1980-07-31 1982-03-10 Zeiss Jena Veb Carl Infrared-sensitive Multiple Photon Detector
US4513305A (en) * 1982-12-06 1985-04-23 Gte Laboratories Incorporated Multi-wavelength demultiplexer for fiber optical communication
GB2136202A (en) * 1983-03-02 1984-09-12 Int Standard Electric Corp Photodiode
EP0146375A2 (en) * 1983-12-19 1985-06-26 Kabushiki Kaisha Toshiba Visible/infrared imaging device with stacked cell structure
GB2164792A (en) * 1984-07-24 1986-03-26 Sharp Kk A semiconductor device
US4656109A (en) * 1984-09-19 1987-04-07 Fuji Electric Co., Ltd. Layered solid state color photosensitive device

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5329136A (en) * 1993-04-30 1994-07-12 At&T Bell Laboratories Voltage-tunable photodetector
US5479032A (en) * 1994-07-21 1995-12-26 Trustees Of Princeton University Multiwavelength infrared focal plane array detector
US5552603A (en) * 1994-09-15 1996-09-03 Martin Marietta Corporation Bias and readout for multicolor quantum well detectors
US5539206A (en) * 1995-04-20 1996-07-23 Loral Vought Systems Corporation Enhanced quantum well infrared photodetector
FR2766919A1 (en) * 1997-07-30 1999-02-05 Schlumberger Services Petrol Hydrostatic pressure and-or temperature transducer useful for oil well pressure sensor
US6054718A (en) * 1998-03-31 2000-04-25 Lockheed Martin Corporation Quantum well infrared photocathode having negative electron affinity surface
DE102005001280A1 (en) * 2004-09-30 2006-04-13 Osram Opto Semiconductors Gmbh radiation detector
US7525083B2 (en) 2004-09-30 2009-04-28 Osram Opto Semiconductors Gmbh Radiation detector with an epitaxially grown semiconductor body
DE102005001280B4 (en) 2004-09-30 2022-03-03 OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung radiation detector
WO2009094966A2 (en) 2008-01-31 2009-08-06 Osram Opto Semiconductors Gmbh Radiation receptor, and method for the production thereof
WO2009094966A3 (en) * 2008-01-31 2009-10-08 Osram Opto Semiconductors Gmbh Radiation receptor, and method for the production of a radiation receptor
US8659107B2 (en) 2008-01-31 2014-02-25 Osram Opto Semiconductors Gmbh Radiation receiver and method of producing a radiation receiver

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Publication number Publication date
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