GB2213495A - Cleaning liquids - Google Patents
Cleaning liquids Download PDFInfo
- Publication number
- GB2213495A GB2213495A GB8828674A GB8828674A GB2213495A GB 2213495 A GB2213495 A GB 2213495A GB 8828674 A GB8828674 A GB 8828674A GB 8828674 A GB8828674 A GB 8828674A GB 2213495 A GB2213495 A GB 2213495A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- stain
- solution
- added
- glycerol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Abstract
Improved cleaning liquids, suitable for use in the removal of stains and dirt from a wide variety of fabrics and textile materials, comprise an aqueous solution of an alkyl sulphate or sulphonate detergent to which has been added a quantity of glycerol in the range 1 - 6.5% by weight. The detergent solution may also contain other solvents and dirt-removing constituents together with appropriate colouring and perfume. The solution may be used as such for the removal of spot stains or soiling or may be diluted for general application such as for example, a carpet shampoo.
Description
CLEANING LIQUIDS
The invention is concerned with improvements in or relating to liquid cleaning compositions, in particular but not exclusively, cleaning compositions for use in stain and dirt removal from fabric upholstery, soft furnishing materials and other textiles, carpets, paintwork and the like.
Various substances such as detergents are known which will remove or reduce the degree of staining or soiling from fabrics or other materials where there has been a certain amount of penetration of staining or soiling into the structure formed by the fibres or even into the fibres themselves. Careful selection is necessary to ensure success in stain removal without damage to the fibre or dye of the material.
It is therefore an object of the invention to provide liquid cleaning compositions, the use of which will not harm the majority of materials or surfaces but will give efficient cleaning of the same.
The invention provides a liquid cleaning composition for use as above comprising an aqueous solution of-an alkyl sulphate or sulphonate detergent to which has been added a quantity of glycerol in the range 1 - 6.5% by weight of active components.
Preferably there is added between 2 - 5%, for example approximately 3%, by weight of glycerol. The detergent solution may also contain other solvents and dirt-removing constituents together with appropriate colouring and perfume.
The detergent solution according to the invention may be used in a concentrated form for the removal of spot staining or soiling or in a more dilute form for general application such as for example as a carpet shampoo.
There will now be described two examples of cleaning fluids according to the invention. It will be understood that the description is given by way of example only and not by way of limitation.
EXAMPLE I A detergent solution comprising the following constituents was placed in a container which was provided with a mixing device.
Sodium alkyl benzene sulphonate
Tetra potassium pyrophosphate
Ethylene diamine tetra-acetic acid
Ethylene or propylene glycol monobutyl ether
Alcohol ethoxylate.
The solution is a free-running yellow liquid marketed by Dychem International (U.K.) limited under the trade name ELBOW GREASE and having a pH value of approximately 12 and a specific gravity of 1.04. A sample of this solution was retained to act as a control.
An addition was made to the container of 38 by volume of glycerol and the constituents thoroughly mixed to give a liquid having increased viscosity. Samples of carpeting were then taken which had been heavily stained with coffee and allowed to dry naturally. Those samples which were spot-cleaned by the control liquid retained a faint yellow-brown discoloration. However, no staining remained on those spot-cleaned with the glycerol-containing solution.
A further batch of glycerol-containing mixture was diluted with water and a de-foaming agent added, in the present example, 3% by volume polydimethyl siloxane. A room-sized area was then given a "shampoo" treatment using a conventional carpet cleaning machine and the standard of cleaning efficiency seen to be excellent.
EXAMPLE II A detergent solution comprising the following constitutents was placed in a container having a mixing device provided therein. All percentages are by weight of solution.
2% Sodium tripolyphosphate (STP)
6% Dipropylene glycol monobutyl ether
2% Sodium alkyl ether sulphate 0.58 (Tri) Sodium salt of nitrilo triacetic acid (KSM70) 3% glycerol
5% Brightener solution (NP9) with small additions of lemon and pine perfume (0.002%) and dye.
The above ingredients were made up in an aqueous solution (approx. 81% water).
A comparative trial was carried out to compare the stain removing efficiency of the glycerol containing solution obtained in Example II with the performance of a conventional liquid detergent of the type marketed under the trade mark "Fairy Liquid".
A number of differing types of fabric, cotton, polyester/cotton mixture and a white woollen fabric were taken and samples of each divided into four groups, each group including two portions of each type of fabric.
The fabric portions of each group were subjected to staining by a variety of commonly occurring stain-forming materials, coffee, tomato sauce, curry sauce (turmeric) and household lubricating oil, and allow to dry. One portion of each type of fabric from each group was then treated with the solution of Example II and the other portion of each type of fabric from each group was treated with the conventional detergent. All fabric portions were then rinsed in cold,water and dried.
A visual assessment was then carried out on each group of fabric portions. The trials showed that the solution of Example II exhibited superior stain-removing capability.
Results
Fabric Type
Cotton Polyester/ White
Cotton Wool
Coffee
Ex. II solution Stain removed Stain removed Stain
removed
Conventional Faint brown Faint brown Faint brown detergent stain stain stain
Tomato Sauce
Ex. II solution Stain removed Stain removed Stain
removed
Conventional Faint brown Stain removed Faint brown detergent stain stain
Curry Sauce
Ex. II solution Stain removed Stain removed Faint red
dish stain
Conventional Yellow stain Yellow stain Yellow detergent stain
Lubricating Oil EX. II solution Stain removed Stain removed Stain
removed
Conventional Stain removed Stain removed Stain detergent removed
Various modifications may be made within the scope of the invention as defined by the following claims.
Claims (11)
1. A liquid cleaning composition for use in stain and dirt removal comprising an aqueous solution of an alkyl sulphate or sulphonate detergent to which has been added a quantity of glycerol in the range 1 - 6.5 per cent by weight of active components.
2. A composition as claimed in claim 1, wherein the quantity of glycerol added is in the range of 2 - 5 per cent by weight of active conponents.
3. A composition as claimed in claim 1, wherein the quantity of glycerol added is approximately 3% by weight of active components.
4. A composition as claimed in any one of the preceding claims, wherein a de-foaming agent is added thereto.
5. A composition as claimed in claim 4 wherein the de-foaming agent is polydimethyl siloxane.
6. A composition as claimed in claim 5 wherein the agent is added is 3% by weight of the active components.
7. A composition as claimed in any one of the preceding claims wherein the active components form at least substantially 18% of an aqueous solution.
8. A composition as claimed in any one of the preceding claims whereing the alkyl sulphate is a sodium alkyl ether sulphate.
9. A composition as claimed in any one of claims 1 to 7, wherein the alkyl sulphonate is sodium alkyl benzene sulphonate.
10. A liquid cleaning composition for use in stain and dirt removal substantially as hereinbefore described with reference to a) Example I and
b) Example
II.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB878728610A GB8728610D0 (en) | 1987-12-08 | 1987-12-08 | Cleaning liquids |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8828674D0 GB8828674D0 (en) | 1989-01-11 |
GB2213495A true GB2213495A (en) | 1989-08-16 |
GB2213495B GB2213495B (en) | 1992-09-16 |
Family
ID=10628132
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB878728610A Pending GB8728610D0 (en) | 1987-12-08 | 1987-12-08 | Cleaning liquids |
GB8828674A Expired - Lifetime GB2213495B (en) | 1987-12-08 | 1988-12-08 | Cleaning liquids |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB878728610A Pending GB8728610D0 (en) | 1987-12-08 | 1987-12-08 | Cleaning liquids |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB8728610D0 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0281881A2 (en) * | 1987-03-07 | 1988-09-14 | Henkel Kommanditgesellschaft auf Aktien | Process for removing stains from textiles |
GB2353288A (en) * | 1999-06-23 | 2001-02-21 | Reckitt Benckiser Inc | Spot cleaning compositions useful for cleaning garments and textiles |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB815850A (en) * | 1957-01-23 | 1959-07-01 | Hedley Thomas & Co Ltd | Improvements in or relating to liquid detergent compositions |
GB1461775A (en) * | 1973-04-27 | 1977-01-19 | Unilever Ltd | Detergent composition |
GB1542387A (en) * | 1976-05-11 | 1979-03-21 | Kao Corp | Detergent composition |
GB1582200A (en) * | 1976-07-27 | 1980-12-31 | Henkel Kgaa | Liquid enzyme-containing concentrates usable as washing and cleaning agents |
GB2079305A (en) * | 1980-07-02 | 1982-01-20 | Unilever Plc | Liquid enzyme detergent |
EP0079641A1 (en) * | 1981-11-13 | 1983-05-25 | Unilever N.V. | Built liquid detergent compositions |
EP0197649A2 (en) * | 1985-03-06 | 1986-10-15 | The Procter & Gamble Company | Liquid cleansing composition |
-
1987
- 1987-12-08 GB GB878728610A patent/GB8728610D0/en active Pending
-
1988
- 1988-12-08 GB GB8828674A patent/GB2213495B/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB815850A (en) * | 1957-01-23 | 1959-07-01 | Hedley Thomas & Co Ltd | Improvements in or relating to liquid detergent compositions |
GB1461775A (en) * | 1973-04-27 | 1977-01-19 | Unilever Ltd | Detergent composition |
GB1542387A (en) * | 1976-05-11 | 1979-03-21 | Kao Corp | Detergent composition |
GB1582200A (en) * | 1976-07-27 | 1980-12-31 | Henkel Kgaa | Liquid enzyme-containing concentrates usable as washing and cleaning agents |
GB2079305A (en) * | 1980-07-02 | 1982-01-20 | Unilever Plc | Liquid enzyme detergent |
EP0079641A1 (en) * | 1981-11-13 | 1983-05-25 | Unilever N.V. | Built liquid detergent compositions |
EP0197649A2 (en) * | 1985-03-06 | 1986-10-15 | The Procter & Gamble Company | Liquid cleansing composition |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0281881A2 (en) * | 1987-03-07 | 1988-09-14 | Henkel Kommanditgesellschaft auf Aktien | Process for removing stains from textiles |
EP0281881A3 (en) * | 1987-03-07 | 1990-05-30 | Henkel Kommanditgesellschaft auf Aktien | Process for removing stains from textiles |
GB2353288A (en) * | 1999-06-23 | 2001-02-21 | Reckitt Benckiser Inc | Spot cleaning compositions useful for cleaning garments and textiles |
Also Published As
Publication number | Publication date |
---|---|
GB8828674D0 (en) | 1989-01-11 |
GB8728610D0 (en) | 1988-01-13 |
GB2213495B (en) | 1992-09-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4685930A (en) | Method for cleaning textiles with cyclic siloxanes | |
US3935129A (en) | Liquid cleaning compositions | |
EP0182583B1 (en) | Method for cleaning textiles with cyclic siloxanes | |
US4457857A (en) | Pretreatment composition for stain removal | |
US4363756A (en) | Pretreatment composition for stain removal | |
US4295845A (en) | Pretreatment composition for stain removal | |
EP0666308B1 (en) | Multi-purpose liquid cleaning compositions | |
US5534167A (en) | Carpet cleaning and restoring composition | |
EP0272574B1 (en) | Mixtures of liquid non-ionic surfactants | |
DE69630577T2 (en) | Prewash stain remover composition with surfactant based on siloxane | |
US5908473A (en) | Spot pretreatment compositions for home dry cleaning | |
AU704895B2 (en) | Aqueous emulsions containing a hydrophobic brightener, a hydrophilic surfactant and a hydrophobic surfactant | |
US4564463A (en) | Liquid laundry detergents with improved soil release properties | |
US6146427A (en) | Method for cleaning hydrocarbon-containing greases and oils from fabric in laundry washing applications | |
JP4491528B2 (en) | Cleaning solution and cleaning method | |
KR890013268A (en) | How to Improve Machine Cleaning of Stained Textiles | |
JPH093492A (en) | Detergent composition | |
GB2213495A (en) | Cleaning liquids | |
CN104862112A (en) | Clothes oil removal agent and preparation method thereof | |
US4637892A (en) | Cleaning solution | |
US3839214A (en) | Tetraborate composition | |
EP2404988B1 (en) | Laundry pre-spotting composition | |
US6080713A (en) | Method for cleaning hydrocarbon-containing greases and oils from fabric in laundry washing applications | |
WO2000029527A2 (en) | Environmentally safe detergent composition and method of use | |
CN1354245A (en) | Water base type liquid clothes-washing precleaning agent containing polyenzyme |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19931208 |