GB2160545A - Electrolytic cleaning of filters in situ - Google Patents
Electrolytic cleaning of filters in situ Download PDFInfo
- Publication number
- GB2160545A GB2160545A GB08513917A GB8513917A GB2160545A GB 2160545 A GB2160545 A GB 2160545A GB 08513917 A GB08513917 A GB 08513917A GB 8513917 A GB8513917 A GB 8513917A GB 2160545 A GB2160545 A GB 2160545A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filter
- membrane
- filtration apparatus
- process liquid
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 21
- 238000011065 in-situ storage Methods 0.000 title abstract description 3
- 239000012528 membrane Substances 0.000 claims abstract description 50
- 239000007788 liquid Substances 0.000 claims abstract description 37
- 238000001914 filtration Methods 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000003792 electrolyte Substances 0.000 claims abstract description 9
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 38
- 230000008569 process Effects 0.000 claims description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 7
- 229910001220 stainless steel Inorganic materials 0.000 claims description 7
- 239000010935 stainless steel Substances 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000012982 microporous membrane Substances 0.000 claims 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 210000004379 membrane Anatomy 0.000 description 41
- 230000004907 flux Effects 0.000 description 10
- 239000002002 slurry Substances 0.000 description 9
- 238000009295 crossflow filtration Methods 0.000 description 6
- 238000001471 micro-filtration Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- MSNWSDPPULHLDL-UHFFFAOYSA-K ferric hydroxide Chemical compound [OH-].[OH-].[OH-].[Fe+3] MSNWSDPPULHLDL-UHFFFAOYSA-K 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000008571 general function Effects 0.000 description 1
- 238000009285 membrane fouling Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/62—Regenerating the filter material in the filter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D35/00—Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
- B01D35/06—Filters making use of electricity or magnetism
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2313/00—Details relating to membrane modules or apparatus
- B01D2313/34—Energy carriers
- B01D2313/345—Electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/22—Electrical effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/26—Electrical properties
Abstract
@ A porous electrically conducting filter, e.g. a membrane for filtration equipment, is cleaned by setting up an electrochemical cell comprising the membrane as a first electrode (usually the cathode), a second electrode, and an electrolyte capable of being electrolysed to a gaseous product at the first electrode. When a potential is applied across the cell, the gaseous product of electrolysis (e.g. in the form of microbubbles) cleans the surfaces of the membrane by forcing foulant material therefrom.The electrolyte is constituted by the liquid being filtered (with the possible addition of a salt to increase electrical conductivity, if necessary) thus enabling filter cleaning to be carried out in situ whilstthe liquid being filtered continues to be passed through the filter.
Description
1 GB 2 160 545 A 1
SPECIFICATION
Filter cleaning This invention relates to the electrochemical cleaning of electrically conducting filters.
Filtration is a widely used industrial process and the fouling of filters such as membranes used therein may be a considerable problem, especially in microfiltration and ultrafiltration. Thus, such fouling reduces membrane fluxes, and the resulting need for cleaning treatment increases the complexity of filtration equipment, involves loss of time, and decreases membrane lifetime. Conventionally, such cleaning treatment is carried out by chemical dissolution of foulant material or by backwashing. In a typical exam- 10 ple, the membranes of microfiltration units for breweries and distilleries have to be cleaned every 2 to 4 hours where the actual cleaning treatment operation takes 1 to 2 hours.
The invention provides a more rapid and less plant-intensive method of cleaning filters than described above. It is carried out in situ during operation of filtration equipment and is applicable where the mem- brane is electrically conducting. Thus, in one aspect, the invention provides a method of cleaning a po- 15 rous electrically conducting filter during use of the filter in the treatment, by filtration, of an aqueous process liquid comprising the steps of (i) establishing an electrochemical cell comprising a first electrode constituted by the filter, a counter electrode, and an electrolyte constituted by the process liquid, and 00 operating the cell to electrolyse the electrolyte thereby generating a gaseous product of said elec- 20 trolysis at the filter to effect cleaning thereof.
In the practice of the invention, the process liquid may be caused to flow continuously through the filter and the cell operated periodically, as and when required, to effect cleaning of the filter.
The gaseous product may be generated in the form of microbubbles at the surfaces of the filter; the microbubbles force foulant material away from the surfaces thereby cleaning the filter.
Preferably, the first electrode constitutes the cathode of the cell and the second electrode the anode; when using certain filter materials, however, the first electrode may constitute the anode and the second electrode the cathode.
The invention enables very rapid, direct cleaning of fouled filters to be effected merely by connection of the filter and a counter electrode to a source of potential difference and utilisation of the liquid being 30 filtered as electrolyte. If necessary, the electrical conductivity of the liquid may be increased to facilitate electrolysis by addition of a suitable salt or salts. The counter electrode may, if desired, be constituted by an electrically conducting part of the filtration equipment incorporating the filter. Filter fluxes are main tained and.filter cleaning time reduced or eliminated thereby enabling plant size to be reduced. Also, filter lifetime is increased.
The invention is of particular advantage in downstream processing in the biotechnology industries where fouling is an acute problem. Also, the invention may extend the use of filters to industrial proc esses where fouling has hitherto precluded their large scale use, for example the separation of pulp wastes in the paper industry.
Examples of filters to which the invention is applicable are metallic microporous membranes such as 40 those of stainless steel mesh or sintered stainless steel, microporous graphite membranes and conduct ing ceramic microfiltration and ultrafiltration membranes exemplified by metal oxide membranes such as doped titania or zirconia.
In another aspect, the invention provides a filtration apparatus comprising a first flow chamber having an inlet thereto for inflow of an aqueous process liquid and an outlet 45 therefrom for outflow of concentrated process liquid; a second flow chamber adjacent to the first flow chamber and separated therefrom by a porous electri cally conducting filter, the second flow chamber having an outlet therefrom for outflow of filtered proc ess liquid; a counter electrode positioned to be in contact with the process liquid in use of the apparatus; and 50 means for connecting the filter as a first electrode and the counter electrode to a source of electromo tive force wherein the process liquid constitutes the electrolyte and electrolysis thereof effects cleaning of the filter.
The chamber, if made of electrically conducting material, may conveniently constitute the counter elec trode.
Several ways of carrying out the invention will now be particularly described by way of example. Ref erence will be made to the accompanying drawings wherein Figure 1 is a schematic diagram of a cross-flow flat-sheet filtration apparatus of the invention, Figure 2 is a schematic cross-section of an annular cross-flow filtration apparatus of the invention, Figure 3 is a schematic diagram of another form of cross-flow filtration apparatus of the invention, Figure 4 shows graphically experimental data obtained using the invention to clean a membrane used in the filtration of an iron(III) hydroxide slurry, Figure 5 shows graphically experimental data obtained using the invention to clean a membrane used in the filtration of a titanium dioxide slurry, and 2 GB 2 160 545 A 2 Figure 6 shows graphically experimental data obtained using the invention to clean a membrane used in the filtration of a Baker's yeast slurry.
Referring to Figure 1, a first flow chamber 5 of a filtration apparatus is defined within a module easing 3 and has an inlet 6 for inflow of aqueous process liquid and an outlet 7 for outflow of concentrated process liquid. A second flow chamber 2 is also defined within the module casing 3 and is adjacent to the first chamber 5 and separated therefrom by a flat- sheet microporous filtration membrane 1 of electri cally conducting material. The second chamber 2 has an outlet 8 for outflow of filtered process liquid. A counter electrode 9 is positioned in the first chamber 5 adjacent a wall of the casing 3. The membrane 1 is connectable to the negative pole of a source of potential difference by means not shown and the counter electrode 9 to the positive pole of the source of potential difference by means not shown.
In operation of the apparatus shown in Figure 1, an aqueous process liquid to be filtered is passed continuously into the first chamber 5 via inlet 6 as shown by arrow(s) a and thence through the mem brane 1. Filtered process liquid thereby passes into the second chamber 2 and flows out of the apparatus via outlet 8 as shown by arrow(s) b. The solid content of the process liquid is either retained on the surface of the membrane 1 to constitute foulant material or passes from the first chamber 5 via outlet 7 15 together with process liquid that has not passed through the membrane 1 as shown by arrow(s) c.
When it is desired to remove foulant material from the membrane 1, a potential difference is applied between the membrane 1 and the counter electrode 9. The liquid in the first chamber 5 is electrolysed giving rise to bubbles at the surface of the membrane 1 which force the foulant material therefrom. The foulant material is thence removed from the first chamber 5 in the direction shown by the arrow(s) c. 20 Application of the potential difference may be discontinued as soon as the membrane 1 is sufficiently cleaned of foulant material.
Referring to Figures 2 and 3 respectively, cross-flow filtration apparatus of analogous design and method of operation to those of the apparatus shown in Figure 1 are depicted. Components having the same general function have been given the same reference numberals as in Figure 1 and arrows have 25 been given the same reference letters. Some points of difference between the components of Figure 2 and those of Figure 1 are as follows:
the membrane 1 is tubular, the casing 3 is tubular and has a boss 4, the first chamber 5 is annular and the second chamber 2 cylindrical, the boss 4 is connectable to the positive pole of the source of potential difference so that the casing 3 constitutes the counter electrode, i.e. a separate counter electrode is not necessarily provided in the ap paratus of Figure 2.
Some points of difference between the components of Figure 3 and those of Figure 1 are as follows:- the membrane 1 is tubular, the casing 3 is tubular, the first chamber 5 is cylindrical and the second chamber 2 annular, the counter electrode 9 is of wire and is centrally positioned in the first chamber 5.
Example 1
2L of an aqueous slurry of 16 gL-1 iron(III) hydroxide at pH 12 was continuous filtered in a flow recy cling mode using a cross-flow filtration apparatus as shown in Figure 1 having a stainless steel mesh membrane of effective pore size 8 iL and area 75 cM2. The slurry was passed through the apparatus at 6 psi.
The time taken for 50 mL of liquid to be collected after passage through the membrane was measured 45 continuously. This time is an inverse measure of the membrane flux which was found to decrease as membrane fouling took place. A potential (or pulse) was subsequently applied between the membrane (as cathode) and a second electrode (as anode) for a certain period of time in order to clean the mem brane. The original membrane flux was then restored. The process was repeated several times until the supply of slurry was exhausted.
The results are summarised graphically in Figure 4 where the horizontal axis represents the total vol ume of liquid collected in 50 mL quanta and the vertical axis represents the time taken for 50 mL of liquid to be collected. Point A on the graph indicates the initial time for such collection and points B, C, D and E indicate times for such collection after application of a potential to clean the membrane. Points P, 0, R and S indicate application of a potential, where the conditions of application of the potential at each 55 of these points is summarised in the table below.
POINT VOLTS AMPS TIME (MINS) 60 P 36 31 1112 a 36 32 2 R 36 33 2 65 S 36 20 2 3 GB 2 160 545 A 3 It will be observed from the graph of Figure 4 that the initial membrane flux (point A) was substantially restored following each application of a potential at P, G, R and S.
Example 2
51---of an aqueous slurry containing 1% TiO, at pH 9.75 was filtered in a continuous flow recycling mode 5 using a cross-flow filtration apparatus as shown in Figure 1 having a stainless steel mesh membrane of effective pore size 6-7 iim and area 75 CM2. The slurry was passed through the apparatus at 3 psi.
Testing was carried out as described in Example 1 except that the pulse was 12 V at 5 A for 5 seconds at the begining of the test, increasing gradually to 26 V at 12 A for 5 seconds at the end of the test. Such pulsing allowed the slurry to be concentrated from 1% Ti02 to 25% Ti02 while maintaining an essentially 10 constant membrane flux.
The results are summarised graphically in Figure 5 where the axes are as in Figure 4. For comparison purposes, Figure 5 also shows, identified as "COMPARATIVE", the time for collection of 50 mi- of liquid when membrane cleaning was not carried out. Referring to Figure 5, each peak of the zig-zag curve indi cate application of the pulse and the next succeeding minimum after each peak indicates the effect of the 15 application of the pulse. It will therefore be observed that membrane flux was substantially maintained by periodic application of the pulses. The comparative curve on Figure 5 shows that membrane flux de creases regularly in the absence of the pulses. By the time the liquid has been concentrated to just 2.3% TiO, the flux has decreased to only about one fifth of that maintained by application of pulses.
Example 3
An aqueous dispersion of 5 gL 1 DCL Bakers yeast in phosphate buffer at pH 7 was continuously fil tered using a cross-flow filtration apparatus as shown in Figure 3 having an annular membrane consist ing of a layer of zirconia deposited on a microporous graphite tube. The molecular weight cut-off of the membrane was in the range 104-1 05 and the membrane area was 10 CM2. The dispersion was passed through the cell at 8 psi.
The time taken for 2 mL of liquid to be collected after passage through the membrane was measured continuously. The results are shown in Figure 6 where the horizontal axis represents the total volume of liquid collected and the vertical axis represents the time taken for 2 mL of liquid to be collected. Referring to Figure 6, no potential was applied from point F to point G on the graph. At points G, H, 1, J. K and L 30 pulses of 14 V at 1 A for 15 seconds were applied and it will be seen that the membrane flux was appre ciably improved by these pulses.
Claims (20)
1. A method of cleaning a porous electrically conducting filter during use of the filter in the treatment, by filtration, of an aqueous process liquid comprising the steps of (i) establishing an electrochemical cell comprising a first electrode constituted by the filter, a counter electrode, and an electrolyte constituted by the process: liquid, and (ii) operating the cell to electrolyse the electrolyte thereby generating a gaseous product of said elec- 40 trolysis at the filter to effect cleaning thereof.
2. A method as claimed in claim 1 wherein the process liquid is caused to flow continuously through the filter and the cell is operated periodically to effect cleaning of the filter.
3. A method as claimed in claim 1 or claim 2 wherein the first electrode is the cathode of the cell and the counter electrode the anode.
4. A method as claimed in any of the preceding claims wherein one or more salts is additionally provided in solution in the process liquid to facilitate the electrolysis.
5. A method as claimed in any of the preceding claims wherein the filter is a metallic microporous membrane.
6. A method as claimed in claim 5 wherein the membrane is of stainless steel mesh or sintered stain- 50 less steel.
7. A method as claimed in any of claims 1 to 4 wherein the filter is a microporous graphite membrane.
8. A method as claimed in any of claims 1 to 4 wherein the filter is a ceramic membrane.
9. A method as claimed in claim 8 wherein the ceramic is a metal oxide.
10. A method as claimed in claim 9 wherein the metal oxide is doped titania or doped zirconia.
11. A method of cleaning a porous electrically conducting filter substantially as described herein with reference to any of the examples.
i GB 2 160 545 A 4
12. A filtration apparatus comprising a first flow chamber having an inlet thereto for inflow of an aqueous process liquid and an outlet therefrom for outflow of concentrated process liquid; a second flow chamber adjacent to the first flow chamber and separated therefrom by a porous electri cally conducting filter, the second flow chamber having an outlet therefrom for outflow of filtered proc- 5 ess liquid; a counter electrode positioned to be in contact with the process liquid in use of the apparatus; and means for connecting the filter as a first electrode and the counter electrode to a source of electromo tive force wherein the process liquid constitutes the electrolyte and the electrolysis thereof effects clean ing of the filter.
13. A filtration apparatus as claimed in claim 12 wherein the material of the first chamber is electri cally conducting and constitutes the counter electrode.
14. A filtration apparatus as claimed in claim 12 or claim 13 wherein the filter is a metallic micropo rous membrane.
15. A filtration apparatus as claimed in claim 14 wherein the membrane is of stainless steel mesh or 15 sintered stainless steel.
16. A filtration apparatus as claimed in claim 12 or claim 13 wherein the filter is a microporous graphite membrane.
17. A filtration apparatus as claimed in claim 12 or claim 13 wherein the filter is a ceramic membrane.
18. A filtration apparatus as claimed in claim 17 wherein the ceramic is a metal oxide.
19. A filtration apparatus as claimed in claim 18 wherein the metal oxide is doped titania or doped zirconia.
20. A filtration apparatus substantially as described herein with reference to Figure 1, Figure 2 or Figure 3.
Printed in the UK for HMSO, D8818935, 11185, 7102. Published by The Patent Office, 25 Southampton Buildings, London, WC2A lAY, from which copies may be obtained.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB848415887A GB8415887D0 (en) | 1984-06-21 | 1984-06-21 | Membrane cleaning |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8513917D0 GB8513917D0 (en) | 1985-07-03 |
| GB2160545A true GB2160545A (en) | 1985-12-24 |
| GB2160545B GB2160545B (en) | 1988-01-20 |
Family
ID=10562790
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB848415887A Pending GB8415887D0 (en) | 1984-06-21 | 1984-06-21 | Membrane cleaning |
| GB08513917A Expired GB2160545B (en) | 1984-06-21 | 1985-06-03 | Electrolytic cleaning of filters in situ |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB848415887A Pending GB8415887D0 (en) | 1984-06-21 | 1984-06-21 | Membrane cleaning |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4624760A (en) |
| EP (1) | EP0165744B1 (en) |
| JP (1) | JPS6111107A (en) |
| AT (1) | ATE37204T1 (en) |
| AU (1) | AU573844B2 (en) |
| CA (1) | CA1256396A (en) |
| DE (1) | DE3564968D1 (en) |
| GB (2) | GB8415887D0 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2247469A (en) * | 1990-08-31 | 1992-03-04 | Atomic Energy Authority Uk | Counter electrode for electrochemical filter cleaning |
| GB2290086A (en) * | 1994-06-09 | 1995-12-13 | Atomic Energy Authority Uk | Electrolytic cleaning of filters in-situ wherein a voltage of reverse polarity is applied |
| WO1996010453A3 (en) * | 1994-10-01 | 1996-07-04 | Imas Uk Ltd | A filter, apparatus including the filter and a method of use of the apparatus |
| US5545311A (en) * | 1994-06-09 | 1996-08-13 | United Kingdom Atomic Energy Authority | Filter cleaning |
| GB2308131A (en) * | 1995-12-14 | 1997-06-18 | Aea Technology Plc | Electrolytic cleaning of filter in-situ using insulating fluid-permeable sheet between electrodes |
| EP0779090A1 (en) * | 1995-12-14 | 1997-06-18 | AEA Technology plc | In situ filter cleaning |
| US5958242A (en) * | 1995-12-14 | 1999-09-28 | Aea Technology Plc | In situ filter cleaning |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8901581D0 (en) * | 1989-01-25 | 1989-03-15 | Alcan Int Ltd | Filter cleaning |
| FR2655642B1 (en) * | 1989-12-11 | 1992-02-28 | Anjou Rech | WATER TREATMENT PLANT BY A TANGENTIAL FILTER LOOP. |
| FI86380C (en) * | 1990-09-10 | 1992-08-25 | Kemira Oy | FOER REFRIGERATION FOR FILTER. |
| GB9213135D0 (en) * | 1992-06-20 | 1992-08-05 | Atomic Energy Authority Uk | A filter |
| US5431823A (en) * | 1994-08-18 | 1995-07-11 | Electric Fuel(E.F.L.) Ltd. | Process for supporting and cleaning a mesh anode bag |
| DE19741498B4 (en) | 1997-09-20 | 2008-07-03 | Evonik Degussa Gmbh | Production of a ceramic stainless steel mesh composite |
| GB9808517D0 (en) * | 1998-04-23 | 1998-06-17 | Aea Technology Plc | Electrical sensor |
| US6071404A (en) * | 1998-08-31 | 2000-06-06 | Tsui; Tommy | Water treating device |
| DE10034386A1 (en) * | 2000-07-14 | 2002-01-24 | Creavis Tech & Innovation Gmbh | Method and device for electrofiltration |
| DE10122801A1 (en) * | 2001-05-10 | 2002-11-14 | Isco Inc | Method and device for taking waste water samples |
| JP4149838B2 (en) | 2003-03-04 | 2008-09-17 | オリンパス株式会社 | Capsule medical device |
| US7247210B2 (en) * | 2004-02-23 | 2007-07-24 | Ecolab Inc. | Methods for treating CIP equipment and equipment for treating CIP equipment |
| US7220358B2 (en) * | 2004-02-23 | 2007-05-22 | Ecolab Inc. | Methods for treating membranes and separation facilities and membrane treatment composition |
| US7392811B2 (en) * | 2004-02-23 | 2008-07-01 | Ecolab Inc. | Delivery head for multiple phase treatment composition, vessel including a delivery head, and method for treating a vessel interior surface |
| JP5093835B2 (en) * | 2006-03-31 | 2012-12-12 | 三井造船株式会社 | Ballast water membrane treatment method and membrane treatment apparatus using membrane module |
| US9162904B2 (en) | 2011-03-04 | 2015-10-20 | Tennant Company | Cleaning solution generator |
| NL2011516C2 (en) * | 2013-09-27 | 2015-03-30 | Metalmembranes Com B V | Microbial filter device and method for providing such device. |
| RU2600641C9 (en) * | 2015-10-08 | 2017-02-13 | Олег Васильевич Федотов | Method of liquid treatment with simultaneous cleaning of filter element |
| CN106040005B (en) * | 2016-07-13 | 2018-03-27 | 四川民生管业有限责任公司 | Rolled membrane module |
| CN113415858B (en) * | 2021-07-23 | 2022-12-02 | 广西碧清源环保投资有限公司 | Ceramic membrane and filtration system with electrolysis function |
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| GB1158545A (en) * | 1965-10-25 | 1969-07-16 | Serck R & D Ltd | Improvements in and relating to the Prevention of Bacterial Growth on Metallic Filtering Elements |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE634457A (en) * | 1963-06-28 | |||
| GB1089458A (en) * | 1964-12-24 | 1967-11-01 | Medicor Muevek | Method of eliminating cloggings in narrow apertures and/or capillary systems in conducting liquids, and apparatus for the execution thereof |
| NL6603696A (en) * | 1965-04-28 | 1966-10-31 | ||
| US3912624A (en) * | 1974-03-26 | 1975-10-14 | Universal Oil Prod Co | Cleaning of membrane surfaces |
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| US4256551A (en) * | 1978-11-02 | 1981-03-17 | Imperial Chemical Industries Limited | Electrolytic process |
| JPS5836604B2 (en) * | 1979-04-18 | 1983-08-10 | 株式会社日立製作所 | High temperature electrodialysis method and equipment |
| US4231865A (en) * | 1979-08-07 | 1980-11-04 | The United States Of America As Represented By The Secretary Of The Interior | Backwashing reverse-osmosis and ultrafiltration membranes by electro-osmosis |
| DE3046294A1 (en) * | 1980-12-09 | 1982-07-08 | Promaco Project Managing Co. Inc., Panama-Sity, Panama | Special steel and platinised noble metal dialysis electrodes - resist periodic current reversals to clean membranes |
| US4548693A (en) * | 1981-02-25 | 1985-10-22 | Olin Corporation | Reticulate electrode for electrolytic cells |
| US4493756A (en) * | 1983-06-21 | 1985-01-15 | Pall Corporation | Process for cleaning metal filters |
-
1984
- 1984-06-21 GB GB848415887A patent/GB8415887D0/en active Pending
-
1985
- 1985-06-03 GB GB08513917A patent/GB2160545B/en not_active Expired
- 1985-06-06 DE DE8585304013T patent/DE3564968D1/en not_active Expired
- 1985-06-06 EP EP85304013A patent/EP0165744B1/en not_active Expired
- 1985-06-06 AT AT85304013T patent/ATE37204T1/en not_active IP Right Cessation
- 1985-06-07 US US06/742,709 patent/US4624760A/en not_active Expired - Lifetime
- 1985-06-13 AU AU43661/85A patent/AU573844B2/en not_active Ceased
- 1985-06-17 CA CA000484139A patent/CA1256396A/en not_active Expired
- 1985-06-19 JP JP60133897A patent/JPS6111107A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1158545A (en) * | 1965-10-25 | 1969-07-16 | Serck R & D Ltd | Improvements in and relating to the Prevention of Bacterial Growth on Metallic Filtering Elements |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2247469A (en) * | 1990-08-31 | 1992-03-04 | Atomic Energy Authority Uk | Counter electrode for electrochemical filter cleaning |
| EP0474365A1 (en) * | 1990-08-31 | 1992-03-11 | United Kingdom Atomic Energy Authority | Filter cleaning |
| GB2247469B (en) * | 1990-08-31 | 1994-08-03 | Atomic Energy Authority Uk | Filter cleaning |
| GB2290086A (en) * | 1994-06-09 | 1995-12-13 | Atomic Energy Authority Uk | Electrolytic cleaning of filters in-situ wherein a voltage of reverse polarity is applied |
| US5545311A (en) * | 1994-06-09 | 1996-08-13 | United Kingdom Atomic Energy Authority | Filter cleaning |
| GB2290086B (en) * | 1994-06-09 | 1997-12-17 | Atomic Energy Authority Uk | Filter cleaning |
| WO1996010453A3 (en) * | 1994-10-01 | 1996-07-04 | Imas Uk Ltd | A filter, apparatus including the filter and a method of use of the apparatus |
| US6117341A (en) * | 1994-10-01 | 2000-09-12 | Imas Technology Ltd. | Filter, apparatus including the filter and a method of use of the apparatus |
| GB2308131A (en) * | 1995-12-14 | 1997-06-18 | Aea Technology Plc | Electrolytic cleaning of filter in-situ using insulating fluid-permeable sheet between electrodes |
| EP0779090A1 (en) * | 1995-12-14 | 1997-06-18 | AEA Technology plc | In situ filter cleaning |
| GB2308131B (en) * | 1995-12-14 | 1999-03-31 | Aea Technology Plc | In situ filter cleaning |
| US5958242A (en) * | 1995-12-14 | 1999-09-28 | Aea Technology Plc | In situ filter cleaning |
Also Published As
| Publication number | Publication date |
|---|---|
| US4624760A (en) | 1986-11-25 |
| CA1256396A (en) | 1989-06-27 |
| EP0165744B1 (en) | 1988-09-14 |
| GB8513917D0 (en) | 1985-07-03 |
| EP0165744A1 (en) | 1985-12-27 |
| AU4366185A (en) | 1986-01-02 |
| GB8415887D0 (en) | 1984-07-25 |
| JPS6111107A (en) | 1986-01-18 |
| AU573844B2 (en) | 1988-06-23 |
| GB2160545B (en) | 1988-01-20 |
| DE3564968D1 (en) | 1988-10-20 |
| ATE37204T1 (en) | 1988-09-15 |
| JPH0516891B2 (en) | 1993-03-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 732E | Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977) | ||
| 732E | Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20030603 |