GB2155476B - Esters of the family of n-phosphonomethylglycine and their use in the preparation of known herbicides - Google Patents
Esters of the family of n-phosphonomethylglycine and their use in the preparation of known herbicidesInfo
- Publication number
- GB2155476B GB2155476B GB08502164A GB8502164A GB2155476B GB 2155476 B GB2155476 B GB 2155476B GB 08502164 A GB08502164 A GB 08502164A GB 8502164 A GB8502164 A GB 8502164A GB 2155476 B GB2155476 B GB 2155476B
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- esters
- phosphonomethylglycine
- family
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002148 esters Chemical class 0.000 title 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- -1 Phosphonic acid diesters Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 238000007327 hydrogenolysis reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000003008 phosphonic acid esters Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/44—Amides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Phosphonic acid diesters having the formula: <IMAGE> in which R represents a hydrogenolysable group, preferably an aralkyl group, and R<1> represents a hydrolysable group, are obtained by a process wherein phosphonic acid esters of the formula (R<1>O)2P(O)H are reacted with formaldehyde and compounds of the formula R-NH-CH2-COOH, R and R<1> having the meanings given above. Compounds of the formula <IMAGE> may be obtained by hydrogenolysis of the above compounds.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8402988A FR2560198B1 (en) | 1984-02-23 | 1984-02-23 | ESTERS OF THE N-PHOSPHONOMETHYLGLYCIN FAMILY AND THEIR USE FOR THE PREPARATION OF KNOWN HERBICIDES |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8502164D0 GB8502164D0 (en) | 1985-02-27 |
| GB2155476A GB2155476A (en) | 1985-09-25 |
| GB2155476B true GB2155476B (en) | 1988-01-20 |
Family
ID=9301450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08502164A Expired GB2155476B (en) | 1984-02-23 | 1985-01-29 | Esters of the family of n-phosphonomethylglycine and their use in the preparation of known herbicides |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP0153261B1 (en) |
| JP (1) | JPS60193995A (en) |
| KR (1) | KR850007065A (en) |
| AT (1) | ATE40376T1 (en) |
| AU (1) | AU584600B2 (en) |
| BR (1) | BR8500765A (en) |
| CA (1) | CA1256447A (en) |
| DD (1) | DD232050A5 (en) |
| DE (1) | DE3567874D1 (en) |
| DK (1) | DK84185A (en) |
| ES (1) | ES8607975A1 (en) |
| FI (1) | FI75831C (en) |
| FR (1) | FR2560198B1 (en) |
| GB (1) | GB2155476B (en) |
| HU (1) | HU197022B (en) |
| IE (1) | IE850203L (en) |
| IL (1) | IL74169A (en) |
| PL (1) | PL147957B1 (en) |
| PT (1) | PT79998B (en) |
| RO (1) | RO90931B (en) |
| YU (1) | YU45234B (en) |
| ZA (1) | ZA85726B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2560198B1 (en) * | 1984-02-23 | 1987-05-07 | Rhone Poulenc Agrochimie | ESTERS OF THE N-PHOSPHONOMETHYLGLYCIN FAMILY AND THEIR USE FOR THE PREPARATION OF KNOWN HERBICIDES |
| FR2579210B1 (en) * | 1985-03-21 | 1987-09-11 | Rhone Poulenc Agrochimie | PREPARATION OF PHOSPHONATE GROUP HERBICIDES AND INTERMEDIATES FROM BENZOXAZINES |
| DE4326887A1 (en) * | 1993-08-11 | 1995-02-16 | Hoechst Ag | Process for the preparation of N-substituted aminoalkylenephosphonic esters |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1436843A (en) * | 1972-07-21 | 1976-05-26 | Ici Ltd | Preparation of n-phosphonomethyl-glycine |
| BR7309524D0 (en) * | 1972-12-11 | 1974-08-29 | Monsanto Co | PROCESS FOR OBTAINING NEW N-ORGAN-N-PHOSPHONOMETHYLYLGLYCIN N-OXIDE, HERBICIDE COMPOSITION BASED ON THE SAME, HERBICIDE PROCESS, PROCESS TO INCREASE THE DEPOSITION OF CARBON HYDRATES IN PLANTS AND PLANTS TO REDUCE PLANTS AND PROCESSES APPLICATION OF COMPOSITE TITLES |
| US3835000A (en) * | 1972-12-21 | 1974-09-10 | Monsanto Co | Electrolytic process for producing n-phosphonomethyl glycine |
| HU173170B (en) * | 1974-06-27 | 1979-03-28 | Chinoin Gyogyszer Es Vegyeszet | Process for producing n-phosphonomethyl-glycine |
| DE2860342D1 (en) * | 1977-08-11 | 1981-02-12 | Ciba Geigy Ag | Glycylmethyl-phosphinic acid derivatives, their preparation and their use |
| EP0055695A1 (en) * | 1980-12-30 | 1982-07-07 | Ciba-Geigy Ag | Process for preparing N-phosphonomethyl glycine |
| US4422982A (en) * | 1982-06-30 | 1983-12-27 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| FR2560198B1 (en) * | 1984-02-23 | 1987-05-07 | Rhone Poulenc Agrochimie | ESTERS OF THE N-PHOSPHONOMETHYLGLYCIN FAMILY AND THEIR USE FOR THE PREPARATION OF KNOWN HERBICIDES |
-
1984
- 1984-02-23 FR FR8402988A patent/FR2560198B1/en not_active Expired
-
1985
- 1985-01-25 IL IL74169A patent/IL74169A/en unknown
- 1985-01-29 CA CA000473047A patent/CA1256447A/en not_active Expired
- 1985-01-29 GB GB08502164A patent/GB2155476B/en not_active Expired
- 1985-01-29 IE IE850203A patent/IE850203L/en unknown
- 1985-01-30 ZA ZA85726A patent/ZA85726B/en unknown
- 1985-01-30 AU AU38163/85A patent/AU584600B2/en not_active Ceased
- 1985-02-21 JP JP60033630A patent/JPS60193995A/en active Pending
- 1985-02-21 KR KR1019850001078A patent/KR850007065A/en not_active Application Discontinuation
- 1985-02-21 EP EP85420029A patent/EP0153261B1/en not_active Expired
- 1985-02-21 BR BR8500765A patent/BR8500765A/en unknown
- 1985-02-21 PT PT79998A patent/PT79998B/en not_active IP Right Cessation
- 1985-02-21 DE DE8585420029T patent/DE3567874D1/en not_active Expired
- 1985-02-21 PL PL1985252061A patent/PL147957B1/en unknown
- 1985-02-21 AT AT85420029T patent/ATE40376T1/en active
- 1985-02-22 HU HU85673A patent/HU197022B/en not_active IP Right Cessation
- 1985-02-22 ES ES540626A patent/ES8607975A1/en not_active Expired
- 1985-02-22 YU YU273/85A patent/YU45234B/en unknown
- 1985-02-22 DD DD85273479A patent/DD232050A5/en unknown
- 1985-02-22 DK DK84185A patent/DK84185A/en not_active Application Discontinuation
- 1985-02-22 FI FI850733A patent/FI75831C/en not_active IP Right Cessation
- 1985-02-23 RO RO117743A patent/RO90931B/en unknown
Also Published As
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| GB2155476B (en) | Esters of the family of n-phosphonomethylglycine and their use in the preparation of known herbicides | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19930129 |