GB2133130A - Process and device for the monitoring and control of the defrosting of an evaporator - Google Patents

Process and device for the monitoring and control of the defrosting of an evaporator Download PDF

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Publication number
GB2133130A
GB2133130A GB08333757A GB8333757A GB2133130A GB 2133130 A GB2133130 A GB 2133130A GB 08333757 A GB08333757 A GB 08333757A GB 8333757 A GB8333757 A GB 8333757A GB 2133130 A GB2133130 A GB 2133130A
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United Kingdom
Prior art keywords
evaporator
fluid
instant
difference
parameter
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08333757A
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GB2133130B (en
GB8333757D0 (en
Inventor
Christian Boussicault
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Societe National Elf Aquitaine
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Societe National Elf Aquitaine
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Publication of GB8333757D0 publication Critical patent/GB8333757D0/en
Publication of GB2133130A publication Critical patent/GB2133130A/en
Application granted granted Critical
Publication of GB2133130B publication Critical patent/GB2133130B/en
Expired legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D21/00Defrosting; Preventing frosting; Removing condensed or defrost water
    • F25D21/002Defroster control
    • F25D21/006Defroster control with electronic control circuits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D21/00Defrosting; Preventing frosting; Removing condensed or defrost water
    • F25D21/02Detecting the presence of frost or condensate
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00Sensing or detecting of parameters; Sensors therefor
    • F25B2700/21Temperatures
    • F25B2700/2117Temperatures of an evaporator
    • F25B2700/21171Temperatures of an evaporator of the fluid cooled by the evaporator
    • F25B2700/21172Temperatures of an evaporator of the fluid cooled by the evaporator at the inlet
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00Sensing or detecting of parameters; Sensors therefor
    • F25B2700/21Temperatures
    • F25B2700/2117Temperatures of an evaporator
    • F25B2700/21171Temperatures of an evaporator of the fluid cooled by the evaporator
    • F25B2700/21173Temperatures of an evaporator of the fluid cooled by the evaporator at the outlet

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Defrosting Systems (AREA)
  • Air Conditioning Control Device (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

Process and device for the monitoring and control of an evaporator (1) in particular the evaporator of a heat pump according to which is compared, at predetermined instants, the variation between the upstream (9) and downstream (10) temperatures or pressures of the air current crossing the evaporator, defrosting of the evaporator being initiated when said difference exceeds a reference value. <IMAGE>

Description

SPECIFICATION Process and device for the monitoring and control of an evaporator Background of the Invention Field of the Invention The present invention concerns a process and a device for the monitoring and control of an evaporator with a view to detecting the presence of frost or rime on its surface and to initiate its elimination. It concerns, in particular, the case where the evaporator is that of a heat pump.
Background of the Prior Art The principle of a heat pump is well known to the man skilled in the art and it is simply appropriate to recall herein that heat pumps using air as a source of cold comprise an evaporator where this air exchanges its calories with a refrigerating fluid circulating inside this evaporator and which, due to this fact, is vaporized. During the utilization of such a heat pump for heating, the air used as source of cold is the air taken from outside the premises to be heated. Under certain conditions, the utilization of this external air can lead to the creation of frost on the evaporator, which in restraining the heat exchange between the two fluids, lowers the yield of the installation and necessitates a defrosting operation.This operation, which necessitates the shut down of the pump, must only be carried out when necessary (or useful) for the optimization of the installation. Devices allowing to detect the presence of frost and initiate the defrosting operation are thus provided in these installations.
These devices are usually constituted by sensors allowing to measure the pressure drop undergone by the air during its passage on the evaporator or to measure the evaporation temperature by direct measurement on the evaporator wall. It is also possible to use temporisation systems that initiate the defrosting at predetermined time intervals.
However, these realizations present the drawback bound to the fact that all the measurements made are absolute measurements that take into account neither the initial conditions of the operating conditions nor the external conditions and their variations. Among the external conditions influential on the appearance of frost, can be cited the hygrometric degree of the air and its temperature. Among the conditions of the installation, it is necessary to monitor the air flow rate that, if it is fixed for an installation, and can be consider as constant, varies from one installation to another. All these conditions thus necessitate an adjustment on site of the installation.
Brief Description of the Invention On the contrary, the present invention foresees a device and a process for detecting the presence of frost that allows to overcome these drawbacks and of which the operation is not dependent on the variations of the'different parameters mentioned herein-above and which does not necessitate any adjustment bound to the site where the evaporator is installed.
In order to do this, the invention foresees a monitoring and control process of an evaporator with a view to ensuring the detection and the elimination of the frost on the surface of the evaporator, the said evaporator being associated to a circulation circuit of a refrigerating fluid and in contact with a second fluid, set in motion in such a way as to through cross it, the second fluid being capable of yielding its calories to the first fluid and of provoking its evaporation, which monitoring and control process consists in measuring a parameter P 1 representative of the state of the second liquid upstream from the evaporator and a parameter P2 representing the state of same liquid downstream from the evaporator, these measures being carried out at instants t determined from an initial instant, in calculating for each instant t,, the difference APi existing between the two parameters P 1 and P2 and in comparing each difference AP, with the difference APO measured at the initial instant, this comparison being made in the form of a subtraction of which the result is a parameter 8, and in controlling the defrosting of the evaporator a is superior to a reference value C1.
This process thus allows to control only deliberately the defrosting and since the instructions value is supplied by the first measurement, it allows to be independent of the external conditions.
According to another characteristic, the difference APO is constant at the instant to, to a value CO, and the defrosting is controlled when APO is superior to CO. This value CO is selected according to the characteristics of the device. This stage of the process allows to ensure that the first measurement taken as reference, was not made in the presence of frost or any other undesirable parameter, and preferably, it is repeated several times if necessary and the installation is shut down if, after a number of trial runs, for example four, the difference APO has not become superior to the reference value CO.
Furthermore, according to another characteristic, the control of the evaporator is interrupted when the parameter P2 become superior to a reference value C2.
Preferably, the measured parameter is the temperature or indeed the pressure.
The invention also foresees a device for operating the process defined herein-above and which comprises at least two means allowing to measure a parameter representative of the fluid, each of the said means being situated on one side of the evaporator and being provided with means for generating unbroken signals representative of the said parameter, the processing means of these signals allowing at each instant to establish the difference between the values of the parameters measured by the said sensors and to compare this difference to that initially existing during the starting up of the installation in such a way as to be able to generate a control signal actuating a defrosting device of the evaporator in function of the result of the said comparison.
According to the preferred embodiment, the measuring means a temperature sensors supplying an analogous signal and associated to an analogous digital converter allowing to enter these signals into a microprocessor constituting the said processing treatment of the signals.
Furthermore, according to a preferential characteristic of the invention, the temperature measuring means comprise: - at least two temperature variable resistances in which passes a roughly adjustable intensity current and mounted in series with two reference resistances; - multiplexing means of the signal provided with at least four input channels of which at least two each receive an analogous signal representative of the voltage at the terminals of the variable resistances and of which two among the other each receive a signal representative of the voltage at the terminals of the reference resistances, these multiplexing means also comprising an output channel and selection means to choose at any instant one of the said input channels in order to communicate it with the said output channel;; -transformation means allowing to transform the signals issuing from the multiplexing means into alternate signals at which one of the constitutive parameters is proportional to the voltage of the corresponding signal, the said signals being directly processed by the microprocessor.
According to the invention, the transformation means can generate alternate signals of which the period is proportional to the voltage of the corresponding signal but it can, according to another embodiment, generate signals of which the frequency is proportional to the voltage of the said signal.
According to a preferential embodiment of the invention, the processing means are constituted by a microprocessor allowing to make one comparison per second.
Brief Description of the Drawings The invention will be better understood by reading through the following description of an embodiment, given by way of non-limitative example, said description made with reference to the annexed drawings in which: - Figure 1 represents a first embodiment of the invention.
- Figure 2 represents a second embodiment of the invention.
Detailed Description of the Preferred Embodiment Figure 1 represents schematically the evaporation part of a heat pump to which is associated a frost detection device according to the invention.
The evaporator (1) in which circulates the refrigerating fluid is placed in an air current (2) produced by a ventilator (3). The circulation circuit (4) of the refrigerating fluid comprises a pressurereducer (35). It is closed down by the remainder of the calories exchange installation of the heat pump represented by the rectangle (5) and which comprises, especially and in a usual way, a compressor and a condenser. The circuit (4) comprises a pass loop allowing the by-pass of the condensor and of the pressure-reducer (35). This loop is controlled by a three channel valve (7) associated to a servomotor (30). The ventilator (3) is provided with an electromagnetic switch (8).
Two temperature sondes (9) and (10) are placed in the air current (2), the sonde (9) upstream from the evaporator and the sonde (10) downstream.
Each of these sondes is connected to a microprocessor (4), by the intermediary of cables (12) and (13) and analogous digital converters (31) and (32).
The represented device operates in the following way. The system is put into normal operation; i.e. the refrigerating fluid circulates in the evaporator, the by-pass circuit (6) is shut down, the ventilator (3) supplies and sucks the air current (2) towards and through the evaporator (1), and the evaporator is not frosted. After a certain time t1, it is considered that the permanent state has been reached.
From time t, the monitoring microprocessor begins to operate and carries out, at instants t separated by regular time intervals of about 1 second, calculation of the difference AT between the temperature measured by the sonde 9 and that measured by the sonde 10. The first measurement made ATo is taken as a reference measurement and thus stored in memory. At each instant tj, the microprocessor compares ATi to ATo.
Once ATi becomes superior to ATo increased by a constant K, the microprocessor works out a signal actuating the switch (8) of the ventilator. This signal also acts on the servomotor (30) that actuates the three channel valve (7) in such a way that the refrigerating fluid circulates in the by-pass circuit (6). Simultaneously, the microprocessor monitors the temperature measured by the downstream sonde (10) and once the temperature returns above a limit value the microprocessor works out a new signal which by action of the switch (8) and the servomotor (30) reengages the system in normal operation so that the cycle is repeated as before.
This system thus carries out a monitoring of the installation on starting up which allows to take into account the situation where the evaporator would be frosted up during measurement of ATo, or that bound to faulty operation of the circulation circuit of the refrigerating fluid. In order to do this, the microprocessor compares the interval ATo to a iimit value and initiates the defrosting if ATo is superior to this value.
Indeed, in this case it is considered that the heat exchanger is not well done and that the evaporator is frosted up. This operation can be repeated a certain number of times until the obtention of normal operation but the microprocessor will actuate a total shut down if this normal operation is not obtained after a determined number of defrostings: for example 4.
This phase of the process thus allows to ensure that the value ATo, taken into account throughout the entire monitoring, corresponds to a normal state of the device.
Figure 2 represents a variant of the invention according to which the temperatures are measured by using a device comprising two probes mounted in parallel with two standard resistances, a multiplexer and a digital signal generator. The microprocessor assumes calculation of the temperatures and monitoring of the defrosting.
On Figure 2, the elements identical to those of Figure 1 bear the same reference numerals. On either side of the evaporator are placed temperature sondes (101) and (102) each constituted by a resistance variable in function of the temperature. The two sondes are mounted in series with two reference resistances placed in the housing (103) that also allows the supply of the reference resistances assembly by direct current.
The cables (105) and (106) are four-wire conductors allowing positioning of the sondes and the resistances and also allowing the measurement of the voltage at the terminals of the variable resistances. A multiconductor cable (107) connects the housing (103) to a multiplexer (109). This cable allows to supply the input bus of the multiplexer with voltages at the terminals of the variable resistances and at the terminals of the reference resistances. The output of the multiplexer is connected to an amplifier 10) then to an analogous-digital converter (111) which is connected to the microprocessor 12), itself connected to the multiplexer (109) by a transparent cable (120) of the control instructipns.
The microprocessor carries out the addressing of the multiplexer and the rules of three allowing the calculation of the temperatures and conducts the various operations necessary for detecting the presence of frost on the evaporator.
The analogous converter (111) is preferably a VCO that supplies at its output a frequency proportional to the voltage present at the input.
It is also possible to use an impulse width modulator so that the microprocessor will work from a period, through counting the impulses of which the number is directly proportional to the period.
The represented device can comprise different monitoring elements allowing, for example, to verify that the ventilator is operating or that its access by external air is not hampered by elements such as dead leaves, for example.
This device is particularly well adapted to monitoring the evaporator of a heat pump such as that described in French patent application 80 60 103 "Heating Installation for Premises destined for Habitational or Industrial Use".
Furthermore, the present invention is not limited to the embodiments described, but, on the contrary, covers all the variants.

Claims (10)

1. Process for the monitoring and control of an evaporator in which circulates a first fluid, the said evaporator being in contact with a second fluid set in motion so as to through cross it, the second fluid being capable of transmitting its calories to the first fluid and of provoking its evaporation, the said process allowing to detect the presence of frost on the evaporator and its elimination, and consisting in measuring a parameter P 1 representative of the state of the second fluid upstream of the evaporator and parameter P2 representative of the state of the second fluid downstream of the evaporator, wherein these measurements are made at instances tj, determined from an initial instant, and wherein the process consists, furthermore, in calculating for each instant the difference AP existing between the two parameters P1 and P2, in comparing at each instant t, the difference AP with the difference APO measured at the initial instant, this comparison being made in the form of a subtraction of which the result is a parameter a and in controlling the defrosting of the evaporator when a is above a reference value C1.
2. Process according to claim 1, wherein the difference APo is compared at least once, at the instant to, to a reference value CO and the defrosting is controlled when APO is above value o
3. Process according to claim 1, wherein the defrosting control is interrupted when the parameter P2 returns to above reference value C2.
4. Process according to one of claims 1 to 3, wherein the parameter measured is the pressure.
5. Process according to one of claims 1 to 3, wherein the parameter measured is the temperature.
6. Monitoring and control device of an evaporator associated to a circulation circuit of a first refrigerating fluid and contacted with a second fluid set in motion by a ventilator in such a way as to through cross the evaporator, comprising at least one pair of temperature sensors situated on either side of the evaporator and contacted with the said second fluid, the processing means of the signals issuing from these sensors, the said means allowing at each instant to establish the difference between the temperatures measured by the two detectors, wherein the said means allow, furthermore, to compare this difference to the initial variation existing during the starting up of the installation so as to generate a control signal initiating a defrosting device of the evaporator in function of the circuit of the said comparison.
7. Device according to claim 6, wherein the temperature sensors generate a continuous signal representative of the temperature and wherein the said processing means are constituted by a microprocessor.
8. Device according to claim 7, wherein the temperature sensors are constituted by resistances variable with the temperature, through crossed by a roughly adjustable intensity current and mounted in series with two reference resistances, the said device comprising, among others: - multiplexing means of the signal provided with at least four input channels, of which at least two each receive an analogous signal representative of the voltage at the terminals of the variable resistances and two of which among the others each receive a signal representative of the voltage at the terminals of the reference resistance, this multiplexing means also comprising an output channel and selection means allowing to select at each instant one of the said input channels in order to communicate it with the said output channel.
- transformation means allowing to transform the signals issuing from the multiplexing means into alternate signals of which one of the constitutive parameters is proportional to the voltage of the corresponding signal, the said signals being able to be directly processed by the microprocessor.
9. Device according to claim 8, wherein the transformation means generates alternate signals of which the period is proportional to the voltage of the corresponding signal.
10. Device according to claim 8, wherein the transformation means generates alternate signals of which the frequency is proportional to the voltage of the corresponding signal.
GB08333757A 1982-12-22 1983-12-19 Process and device for the monitoring and control of the defrosting of an evaporator Expired GB2133130B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8221549A FR2538518B1 (en) 1982-12-22 1982-12-22 METHOD AND DEVICE FOR MONITORING AND CONTROLLING AN EVAPORATOR

Publications (3)

Publication Number Publication Date
GB8333757D0 GB8333757D0 (en) 1984-01-25
GB2133130A true GB2133130A (en) 1984-07-18
GB2133130B GB2133130B (en) 1986-04-16

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GB08333757A Expired GB2133130B (en) 1982-12-22 1983-12-19 Process and device for the monitoring and control of the defrosting of an evaporator

Country Status (12)

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JP (1) JPS59137772A (en)
BE (1) BE898505A (en)
CA (1) CA1216045A (en)
CH (1) CH655781A5 (en)
DE (1) DE3346563A1 (en)
ES (1) ES8406704A1 (en)
FR (1) FR2538518B1 (en)
GB (1) GB2133130B (en)
IT (1) IT1170050B (en)
NL (1) NL8304412A (en)
PT (1) PT77872B (en)
SE (1) SE8307021L (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998054523A1 (en) * 1997-05-30 1998-12-03 Ranco Incorporated Of Delaware Ice bank system
EP3764032A4 (en) * 2018-03-08 2021-12-01 LG Electronics Inc. Refrigerator

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Publication number Priority date Publication date Assignee Title
US4538420A (en) * 1983-12-27 1985-09-03 Honeywell Inc. Defrost control system for a refrigeration heat pump apparatus
US4563877A (en) * 1984-06-12 1986-01-14 Borg-Warner Corporation Control system and method for defrosting the outdoor coil of a heat pump
DE3642701C2 (en) * 1986-12-13 1998-06-04 Aeg Hausgeraete Gmbh Warning device for a refrigerator and / or freezer
DE4005728A1 (en) * 1990-02-23 1991-08-29 Behr Gmbh & Co Vehicle refrigeration circuit - has electrically-controlled thermostatic expansion valve controlled by line temp. between compressor and condenser
ES2069496B1 (en) * 1993-08-10 1995-11-01 Asturiana De Zinc Sa TUB FOR ELECTROLYSIS FACILITIES.
DE102005054104A1 (en) * 2005-11-12 2007-05-24 Stiebel Eltron Gmbh & Co. Kg Compression refrigerator e.g. ventilation system, controlling method, for e.g. heating room, involves determining control value by combining two control values and adjusting throttle body to determined control value
CN105783387B (en) * 2016-04-29 2018-08-28 合肥美的电冰箱有限公司 Defrosting control method, defrosting control device and refrigerator
WO2021144869A1 (en) * 2020-01-15 2021-07-22 三菱電機株式会社 Heat pump device

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GB834985A (en) * 1957-07-24 1960-05-18 Ranco Inc Control mechanism for refrigerating systems
GB904711A (en) * 1959-01-02 1962-08-29 Parnall & Sons Ltd Improved means for de-frosting refrigerating apparatus
GB975197A (en) * 1962-04-12 1964-11-11 Stone J & Co Ltd Improvements relating to means for controlling the defrosting of refrigerating units
GB1229003A (en) * 1967-11-24 1971-04-21
GB1261810A (en) * 1968-07-26 1972-01-26 Galt Equipment Ltd Temperature control unit
GB1404210A (en) * 1971-12-23 1975-08-28 Philips Nv Controlling refrigerator defrosting-apparatus
GB2064083A (en) * 1979-11-12 1981-06-10 Volvo Ab Device for preventing icing of evaporators
GB1595741A (en) * 1977-01-31 1981-08-19 Carrier Corp Defrost control for heat pumps

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CA844775A (en) * 1967-11-09 1970-06-16 H. Ting Youn Defrost control apparatus
AU410820B2 (en) * 1968-12-02 1971-02-15 An improved differential fluid flow detector
SE7406316L (en) * 1974-05-10 1975-11-11 Projectus Ind Produkter Ab PROCEDURE AND DEVICE FOR DEFROSTING EVAPORATORS FOR HEAT PUMPS.
JPS53148053A (en) * 1977-05-30 1978-12-23 Matsushita Electric Ind Co Ltd Control method of defrosting
JPS5486839A (en) * 1977-12-23 1979-07-10 Hitachi Ltd Heating/cooling device
US4209994A (en) * 1978-10-24 1980-07-01 Honeywell Inc. Heat pump system defrost control
US4338790A (en) * 1980-02-21 1982-07-13 The Trane Company Control and method for defrosting a heat pump outdoor heat exchanger
US4332141A (en) * 1980-08-25 1982-06-01 Honeywell Inc. Defrost control system for refrigeration system
US4328680A (en) * 1980-10-14 1982-05-11 General Electric Company Heat pump defrost control apparatus

Patent Citations (8)

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Publication number Priority date Publication date Assignee Title
GB834985A (en) * 1957-07-24 1960-05-18 Ranco Inc Control mechanism for refrigerating systems
GB904711A (en) * 1959-01-02 1962-08-29 Parnall & Sons Ltd Improved means for de-frosting refrigerating apparatus
GB975197A (en) * 1962-04-12 1964-11-11 Stone J & Co Ltd Improvements relating to means for controlling the defrosting of refrigerating units
GB1229003A (en) * 1967-11-24 1971-04-21
GB1261810A (en) * 1968-07-26 1972-01-26 Galt Equipment Ltd Temperature control unit
GB1404210A (en) * 1971-12-23 1975-08-28 Philips Nv Controlling refrigerator defrosting-apparatus
GB1595741A (en) * 1977-01-31 1981-08-19 Carrier Corp Defrost control for heat pumps
GB2064083A (en) * 1979-11-12 1981-06-10 Volvo Ab Device for preventing icing of evaporators

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998054523A1 (en) * 1997-05-30 1998-12-03 Ranco Incorporated Of Delaware Ice bank system
US5987897A (en) * 1997-05-30 1999-11-23 Ranco Incorporated Of Delaware Ice bank system
AU727544B2 (en) * 1997-05-30 2000-12-14 Ranco Incorporated Of Delaware Ice bank system
EP3764032A4 (en) * 2018-03-08 2021-12-01 LG Electronics Inc. Refrigerator
US11530866B2 (en) 2018-03-08 2022-12-20 Lg Electronics Inc. Refrigerator

Also Published As

Publication number Publication date
PT77872B (en) 1986-04-09
SE8307021D0 (en) 1983-12-19
JPS59137772A (en) 1984-08-07
ES528223A0 (en) 1984-08-01
GB2133130B (en) 1986-04-16
ES8406704A1 (en) 1984-08-01
FR2538518A1 (en) 1984-06-29
SE8307021L (en) 1984-06-23
FR2538518B1 (en) 1986-04-04
DE3346563A1 (en) 1984-06-28
CA1216045A (en) 1986-12-30
NL8304412A (en) 1984-07-16
GB8333757D0 (en) 1984-01-25
CH655781A5 (en) 1986-05-15
IT8324344A0 (en) 1983-12-22
IT1170050B (en) 1987-06-03
PT77872A (en) 1984-01-01
BE898505A (en) 1984-04-16

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PCNP Patent ceased through non-payment of renewal fee