GB2117021A - Flameproofing compositions - Google Patents
Flameproofing compositions Download PDFInfo
- Publication number
- GB2117021A GB2117021A GB08207570A GB8207570A GB2117021A GB 2117021 A GB2117021 A GB 2117021A GB 08207570 A GB08207570 A GB 08207570A GB 8207570 A GB8207570 A GB 8207570A GB 2117021 A GB2117021 A GB 2117021A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphate
- leather
- composition
- flameproofing
- diluent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
- D06M13/298—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing halogen atoms
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
A flameproofing composition comprising a (monohalogenated alkyl) phosphate and an emulsifying agent. The composition is for flameproofing leather.
Description
SPECIFICATION
Flameproofing compositions
The invention relates to flameproofing compositions for flameproofing such material as natural and synthetic leather, particularly natural leather, with (mono-halogenated alkyl) phosphates.
Recent attention has been brought to bear on the problem of increasing the safety factor in flameproofing or upholstered articles such as domestic furnitue or aircraft seatings, particularly where the upholstery covers combustible polyurethane and is likely to be contacted with smouldering or burning material such as lighted cigarettes.
Recently devised tests for measuring the effectiveness of flameproofing of upholstery material are described in the British Standard
Association's Draft for Development DD 58 of 1978, and include the "smouldering cigarette" test, in which a lit cigarette is placed in contact with the material and allowed to burn until it extinguishes naturally. To pass the test, the unhoistered material must not show progressive smouldering after the cigarette has ceased to burn.
Vegetable tanned leather is seldom used for upholstery for, although it has good fireproofing properties, the leather is hard and tends to be heavier than chrome tanned leather. Chrome tanned leather is particularly useful in upholstery because of its soft handle and light weight but it has unsatisfactory fireproofing properties. Attempts have been made to impregnate chrome leather with borax-type materials but the handle and appearance of the resultant leather is affected in such a way as to render the leather stiff, raspy and hard and therefore unsuitable for furniture. Soft handle and light weight are particularly important features for leather used in aircraft seat upholstery.
Other leather articles for which improved flameproofing would be desirable include leather protective clothing, for example that worn by motor cyclists, and industrial leather gloves.
According to the invention there is provided a flameproofing composition comprising a (monohalogenated alkyl) phosphate and an emulsifying agent capable of emulsifying the phosphate in an aqueous diluent. Optionally a carrier and optionally a diluent selected from water and water-miscible organic solvents may be present.
Preferably the flameproofing composition comprises 3095% (mon-halogenated alkyl) phosphate, 570% emulsifying agent plus optionally a carrier and up to 50% diluent (including any thickener present). More preferably the composition comprises 5090% phosphate, 1050% emulsifying agent and up to 30%
diluent. Most preferably the composition comprises 6585% phosphate, 1 5-35% emulsifier and up to 20% diluent.
Further according to the invention there is provided a process for improving the flame retardency of leather comprising applying a flameretardant or flameproofing effective amount of a (mono-halogenated alkyl) phosphate to leather.
Preferably at least 5%, more preferably at least 10% of phosphate (by dry weight of the leather) is applied. The phosphate can be applied to the leather by treating the leather in a bath containing the flameproofing composition according to the invention described above, diluted with further diluent, e.g. water, where necessary.
Alternatively the (monohalogenated alkyl/phosphate can be applied to leather by immersing in or spraying with a solution of a (mono-halogenated alkyl) phosphate in a solvent selected from lower alkyl alcohols, lower alkyl esters and lower alkyl ketones preferably so that at least 5% (by dry weight of leather treated) of phosphate remains in the leather.
Preferably the (mon-halogenated alkyl) phosphate used in a composition of process according to the invention is a tris (monohalogenated lower alkyl) phosphate where the lower alkyl groups are the same or different and are C,~4alkyl. More preferably the phosphate is tris (1 -chloro-2-propyl) phosphate.
Preferred emulsifying agents are anionic in nature and include aliphatic sulphonates, for example Sandozin NEA (a trade mark), a modified alkyl polyglycol (for example sulphonated lauryl alcohol 2EtO), carboxylated surfactants, for example Sandopan 2N (a trade mark), alkaryl sulphonic acids, for example dodecyl benzene sulphonic acid of fatty acid soaps, for example oleic acid soaps. More preferably mixtures or anionic emulsifying agents are used.
Because the phosphate is extremely difficult to emulsify alone, a carrier may be used to assist in the emulsification process. Such a carrier is an organic liquid which is a solvent for the phosphate and is substantially immiscible with water.
Depending upon its volatility, the carrier may be removed by drying after treatment, or may remain in the leather, where it may constribute to its flame retardant or flameproof properties. Preferred carriers are chlorinated hydrocarbons, more preferably polychlorinated paraffins e.g. Cerechlor 50 LV (a trade mark) or lower alkyl ester such as butyl acetate, lower alkyl being C,~4alkyl.
The diluent is preferably water, but may also be a water-miscible or at least partly water-soluble organic solvent for example a lower alcohol, glycol, ester or ketone. The solvent should preferably be at least as volatile as water, so that flammable residues will not be left in the leather.
Mixtures of water and organic solvents may also be used as diluent.
When a composition according to the invention is used in treatment of leather, it is preferably mixed with water so as to give an emulsion of the phosphate (plus carrier if present) in water. The amount of water with which it is mixed is not critical and will depend upon the nature of the leather to be treated, and the equipment used.
Typically, however, the composition may be diluted with from 1 to 10, preferably 2 to 5 times its own weight of water.
In the application process, the leather is preferably contacted with the emulsion obtained by diluting the composition, and the emulsion is then acidified, e.g. with formic acid, until the anionic emulsifiers are converted to their protonated (free acid) forms. At this point they no longer function as emulsifiers, the emulsion breaks, and the separated phosphate and carrier are taken up by the leather. The application process according to the invention can be incorporated into an anionic dyeing process or a fat liquoring process. Such an anionic dyeing process or fat liquoring process comprises treating the leather at a pH of 7 and progressively reducing the pH to pH 3.5 to 4.0 for exhaustion of the dye of fat liquor onto leather.Although it is preferable to include a composition according to the invention in an anionic system it is envisaged that the composition can be used in cationic, amphoteric and non-ionic systems, albeit less effectively.
A particular substrate onto which the phosphate can be applied is chrome tanned natural leather.
The invention also provides leather, preferably chrome-tanned leather, containing at least 5%, preferably at least 10% by dry weight of the leather of a (mono-halogenated alkyl) phosphate.
The invention will now be illustrated with reference to the accompanying Examples in which all temperatures are in degrees Centigrade and all percentages are in percentages by weight unless indicated to the contrary.
In the following Examples the starting material tris(1-chloro-2-propyl)phosphate is known and can be made according to known methods.
EXAMPLE 1
An emulsion of tris)1-chloro-2- propyl)phosphate is prepared with the following composition:
33% chlorinated paraffin (Cereclor 50 LV, a trade mark)
34% tris(1-chloro-2-propyl)phosphate 12% Sandozin NEW (a trade mark)
3% Sandopan 2N conc. (a trade mark) 17% demineralised water
1% hexylene glycol
3 parts of the above composition are diluted with 10 parts water and heated to 50--600C. A sample of chrome tanned leather (10 parts dry weight at 200C) is added to the bath. After 2 hours formic acid is added to reduce the pH of the liquor to 3.5. 45 Minutes are aliowed for this adjustment and exhaustion appears visibly satisfactory.After setting out and drying in conventional manner, tests show that the treatment is effective in the smouldering cigarette test, the amount of tris( 1 -chloro-2propyl)phosphate itself used being 10% calculated on the dry weight of leather treated.
The above treatment can form a part of a normal anion active dyeing or fatliquoring process comprising treating the leather at pH of 7 and progressively reducing the pH to pH 3.5-4.0 for exhaustion of an anionic dye of fatliquor onto the leather.
EXAMPLE 2
An emulsion of tris(1-chloro-2- propyl)phosphate is prepared by mixing 70 parts by weight of tris( 1 -chloro-2-propyl)phosphate and 10 parts of Sandozin NEA (a trade mark). 2
Parts of polyvinyl alcohol and 1 8 parts of demineralised water are also mixed together and the mixture of phosphate and Sandozin NEA is run slowly into polyvinyl alcohol and water mixture.
The emulsion so formed is applied to the leather according to the method of Example 1 except that the amount of emulsion used is 1 5-20% calculated on the dry weight of leather treated, since the % of phosphate in the composition is 70% compared to 34% in Example 1. The amount of phosphate deposited on the leather is the same as that of Example 1 i.e.
around 10% calculated on the dry weight of leather treated.
Claims (14)
1. A flameproofing composition comprising a (mono-halogenated alkyl) phosphate and an emulsifying agent capable of emulsifying the phosphate in an aqueous diluent.
2. A flameproofing composition as claimed in
Claim 1 including an aqueous diluent.
3. A flameproofing composition as claimed in
Claim 2 in which the diluent is water together with a polyvinyl alcohol.
4. A flameproofing composition as claimed in any one of the preceding claims in which 30 to 95% (mono-halogenated alkyl) phosphate, 5 to 70% emulsifying agent (optionally with a carrier) and up to 50% diluent is present.
5. A flameproofing composition as claimed in
Claim 4 in which 50 to 90% phosphate, 10 to 50% emulsifying agent, optionally up to 30% diluent is present.
6. A flameproofing composition as claimed in
Claim 5 in which 65 to 85% phosphate, 1 5 to 35% emulsifying agent and up to 20% diluent is present.
7. A flameproofing composition as claimed in any one of the preceding claims in which the phosphate is tris-(mono-halogenated alkyl) phosphate.
8. Aflameproofing composition as claimed in
Claim 7 in which the phosphate is (tris-1 -chloro- 2-propyl)phosphate.
9. A flameproofing composition as claimed in any one of the preceding claims in which the emulsifying agent is selected from an aliphatic sulphonate, a modified alkyl glycol, a carboxylated surfactant, an alkaryl sulphonate or a fatty acid soap.
10. A process for improving the flame retardancy of a leather substrate comprising applying to the substrate a flame retardant or flameproof effective amount of a (monohalogenated alkyl) phosphate.
1 A process as claimed in Claim 10 comprising applying to the substrate a flame retardant or flameproof effective amount of a composition as claimed in any one of Claims 1 to 9.
12. A process as claimed in Claim 11 comprising applying at least 5%, by dry weight of substrate to be treated, of the phosphate.
1 3. A process as claimed in Claim 12 comprising applying at least 10% of the phosphate.
14. A process as claimed in any one of Claims 10 to 1 3 in which the leather substrate is natural leather.
1 5. Leather when treated with a (monohalogenated alkyl) phosphate.
1 6. Chrome leather when treated with a composition as claimed in any one of Claims 1 to 9.
1 7. A process substantially as herein described with reference to Example 1 or Example 2 for treating a leather substrate.
1 8. A composition substantially as hereinbefore described with reference to Example 1 or
Example 2.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB08207570A GB2117021B (en) | 1982-03-16 | 1982-03-16 | Flameproofing compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB08207570A GB2117021B (en) | 1982-03-16 | 1982-03-16 | Flameproofing compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2117021A true GB2117021A (en) | 1983-10-05 |
GB2117021B GB2117021B (en) | 1986-02-05 |
Family
ID=10529019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08207570A Expired GB2117021B (en) | 1982-03-16 | 1982-03-16 | Flameproofing compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2117021B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0280115A1 (en) * | 1987-02-12 | 1988-08-31 | Daikin Industries, Limited | Oil proof composition for paper |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB700292A (en) * | 1949-11-25 | 1953-11-25 | Glenn L Martin Co | Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compounds |
GB1390791A (en) * | 1971-02-23 | 1975-04-16 | Stauffer Chemical Co | Flame retarding textiles and paper |
GB1480248A (en) * | 1973-07-03 | 1977-07-20 | Ciba Geigy Ag | Organic phosphates their manufacture and their use as flame retardants |
GB1570318A (en) * | 1976-02-23 | 1980-06-25 | Velsicol Chemical Corp | Flame retardant finishers for textile materials |
GB1570317A (en) * | 1976-02-23 | 1980-06-25 | Velsicol Chemical Corp | Flame retardant finishes for textile materials |
GB1597736A (en) * | 1976-12-09 | 1981-09-09 | Velsicol Chemical Corp | Flame retardant finishes for textile materials |
GB2084622A (en) * | 1980-10-03 | 1982-04-15 | Sandoz Products Ltd | Flameproofing compositions |
-
1982
- 1982-03-16 GB GB08207570A patent/GB2117021B/en not_active Expired
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB700292A (en) * | 1949-11-25 | 1953-11-25 | Glenn L Martin Co | Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compounds |
GB1390791A (en) * | 1971-02-23 | 1975-04-16 | Stauffer Chemical Co | Flame retarding textiles and paper |
GB1480248A (en) * | 1973-07-03 | 1977-07-20 | Ciba Geigy Ag | Organic phosphates their manufacture and their use as flame retardants |
GB1570318A (en) * | 1976-02-23 | 1980-06-25 | Velsicol Chemical Corp | Flame retardant finishers for textile materials |
GB1570317A (en) * | 1976-02-23 | 1980-06-25 | Velsicol Chemical Corp | Flame retardant finishes for textile materials |
GB1597736A (en) * | 1976-12-09 | 1981-09-09 | Velsicol Chemical Corp | Flame retardant finishes for textile materials |
GB2084622A (en) * | 1980-10-03 | 1982-04-15 | Sandoz Products Ltd | Flameproofing compositions |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0280115A1 (en) * | 1987-02-12 | 1988-08-31 | Daikin Industries, Limited | Oil proof composition for paper |
Also Published As
Publication number | Publication date |
---|---|
GB2117021B (en) | 1986-02-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |