GB2112388A - Carboxylic acid amides containing amino groups, and mixtures containing these amides and epoxy resins - Google Patents
Carboxylic acid amides containing amino groups, and mixtures containing these amides and epoxy resins Download PDFInfo
- Publication number
- GB2112388A GB2112388A GB08235554A GB8235554A GB2112388A GB 2112388 A GB2112388 A GB 2112388A GB 08235554 A GB08235554 A GB 08235554A GB 8235554 A GB8235554 A GB 8235554A GB 2112388 A GB2112388 A GB 2112388A
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- formula
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- epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/54—Amino amides>
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The compounds of the formula I <IMAGE> wherein Y is an aromatic, cycloaliphatic or aliphatic radical, to which the two carbonyl groups shown in the formula are bound in adjacent positions with respect to each other, and R is an arylene, aralkylene, cycloalkylene or cycloalkylalkylene group, can be produced by reaction of a compound of the formula IIa or IIb <IMAGE> with an amine of the formula III <IMAGE> They are used as latent curing agents for epoxy resins. Mixtures thereof with epoxy resins have excellent stability on storage.
Description
SPECIFICATION
Carboxylic acid amides containing amino groups, and mixtures containing these amides and epoxy resins
The invention relates to special carboxylic acid amides containing amino groups, which amides are latent curing agents for epoxy resins, and to mixtures containing the said amides and epoxy resins.
Amines, amine derivatives and substituted amines as latent curing agents for epoxy resins are already known, for example from the U.S.
Patent Specification No. 3,759,914. Latent curing agents prepared from acid anhydrides and linear aliphatic polyamines are described for example in the U.S. Patent Specification Nos. 3,261,882, 3,488,742 and 3,636,657. Reference is made in particular to the reaction product of phthalic anhydride and diethylenetriamiiie mentioned in these Patent Specifications.
The novel compounds according to the invention form a new class of latent curing agents having improved performance characteristics. In admixture with epoxy resins, they are stable for several months at room temperature and at slightly higher temperature; but they cure in a relatively short time at elevated temperatures, for example in 10 to 60 minutes at 100 to 150 C, the epoxy resin to form a product having very good properties, regardless of whether a freshly prepared mixture is used or a mixture which has been stored for several months. This result is surprising since the amides according to the invention contain free amino groups, of which it could have been expected that they would react at room temperature with epoxy groups.The improved performance characteristics are based in particular on better resistance to high temperatures and to vvater, as well as on the higher glass transition lemperature of the cured epoxy compounds. The mixtures of the amides according to the invention with epoxy resins can therefore be used for a wide range of purposes, for example in the preparation of prepreg materials for the production and repair of composite structures.
The compounds according to the invention correspond to the formula I
wherein Y is an aromatic, cycloaliphatic or aliphatic radical, to which the two carbonyl groups shown in the formula are bound in adjacent positions with respect to each other, and
R is an arylene, aralkylene, cycloalkylene or cycloalkylalkyene group.
Preferably, Y in the formula I is the radical of phthalic acid, tetrahydrophthalic acid, methyltetrahydrophthalic acid hexahydrophthalic acid, succinic acid, dodecylsuccinic acid or maleic acid, each unsubstituted or substituted by one or more lower alkyl groups having 1 to 4 C atoms, especially by one or more methyl groups; in particular Y is the radical of phthalic acid.
In the formula I, R is preferably the phenylene group, which can be substituted by alkyl groups having 1 to 4 C atoms, or it is the xylene group or the cyclohexyiene group. Particularly suitable are the following compounds reduced by the 2 amino groups: m-xylylenediamine, m-phenylenediamine, p,p'-methylenedianiline, bis-(p-amino phenyl)-sulfone, 1 ,2-diaminocyclohexane, 1 ,4- diaminocyclohexane, bis-(p-aminocyclohexyl) methane, 1 ,3-bis-(aminomethyl)-cyclohexane, bis-(4-amino-3-methyl-cyclohexyl)-methane, 2,2- bis-(4-aminocyclohexyl)-propane, 3,5,5-tri- methyl-3-aminomethylcyclohexylamine (isophoronediamine) and 6-amino-1 -(4-amino- phenyl )- ,3,3-trimethyl-indane.Especially preferred are the radicals of m-xylylenediamine, 1 ,2-diaminocyclohexane, bis-(p-aminocyclohexyl)-methane and 1 ,3-bis-(aminomethyl)-cyclo- hexane.
The products of the formula I can be produced according to the invention by reaction of a compound of the formula Ila or llb
with an amine of the formula Ill H2N-R-NH2 (III) A condensation reaction occurs with cleavage
of the anhydride ring and imide ring, respectively,
and formation of water and ammonia, respectively.
There is advantageously used an excess of amine,
namely, from a little over the stoichiometrically
calculated amount up to a very considerable
excess, that is, up to a 100 molar-percentage excess. The reaction product is easily obtained by distilling off the excess amine under reduced pressure.
The reaction is advantageously performed according to the general process described by
Spring and Woods in the Journal of the Chemical Society, 1945, pp. 625-628. This is an aqueous
process at temperatures of 20-500C, which is
best carried out by mixing the components at
300C and performing the reaction at below 50 CC.
The reaction is usually performed at normal
pressure; however, it can also be carried out
under reduced pressure.
It is also possible to carry out the reaction by
the method described in the U.S. Patent
Specification No. 3,639,657, even though some
of the thus produced curing agents are inclined to
react much too fast with epoxy resins. In order to
avoid this disadvantage, the process is modified by performing the reaction in a dioxane solution, and afterwards thoroughly purifying the product.
The resulting products are in general vitreous solid substances having a low melting point.
The reaction of the acid anhydrides with the diamines does not always yield pure diamides; there are formed usually also monoamides. These can either be separated or be left in admixture with the diamides.
The reaction products can be mixed by known mixing methods (stirring, kneading, rolling, and so forth) with an epoxy resin. The epoxy resins used are those which contain in the average molecule more than one epoxy group. Examples are: polyglycidyl ethers of polyhydric phenols, such as bisphenol A. F and S, cresol novolaks and phenol novolaks, glycidylated hydantoins, aromatic amines and aminophenols, polyglycidyl esters, and certain cycloaliphatic epoxy resins. Tetraglycidylated methylenedianiline is preferred.
Resins based on diglycidyl ethers of bisphenol A are likewise preferred for use in the fields of adhesives, coatings and filament windings.
With regard to the epoxy resin the compounds according to the invention can be used in amounts which are 50 to 1 50%, preferably 100%, of the stoichiometric amount.
When reacted with polyepoxides, for example diepoxides, at eievated temperatures, the compounds yield highly crosslinked products which are infusible and insoluble. With simultaneous shaping, by casting or moulding, shaped cast products, moulded articles or laminates can be produced. Furthermore, the resin/curing agent mixtures can be applied to substrates, and then cured in the form of a coating, a lacquer coating or adhesive bond.
Such system are frequently employed in the aerospace industry. They can be used to preimpregnate fibres of various types, for example graphite, glass or Kevlar fibres, which can then be utilised as honeycomb skins. These systems are also suitable for producing laminates. The laminates can be prepared by known techniques, such as by moulding or by the autoclave method, and their layer thicknesses can vary within a wide range.
There can be added to the mixtures of compounds of the formula I with epoxy resins further customary modifiers, such as extenders, fillers, reinforcing agents, pigments, dyes, organic solvents, fire-retarding substances, thixotropic agents, flow control agents and similar substances. Extenders, reinforcing agents and pigments which may be mentioned are: coal tar, bitumen, glass fibres, boron fibres, carbon fibres, cellulose, polyethylene powder, polypropylene powder, mica, asbestos, quartz powder, gypsum, antimony trioxide, montmorillonite derivatives (such as "Bentone", silica aerogel (Aerosil"(D), lithopone, barite, titanium dioxide, carbon black, graphite, iron oxide, and metal powders, such as aluminium or iron powder.Flow control agents are for example: silicones, cellulose acetate butyrate, polyvinyl butyral, waxes, stearates, and similar products which are in part also used as mould release agents.
To adhesives containing an epoxy resin and a compound of the formula I, there can be added rubber substances, such as acrylonitrile-butadiene rubber containing carbonyl terminal groups, or modifying resins, such as triglycidilated p-aminophenol, accelerators, such as boron trifluoride monoethylamine complexes or imidazole complexes, or further curing agents, such as dicyandiamide.
The term 'parts' in the following Examples denotes parts by weight, and % is per cent by weight.
Example 1
To a solution (boiling at 1 10-1200C under nitrogen in reflux condenser) of m-xylylenediamine in dioxane is added dropwise a 20% solution of phthalic anhydride in dioxane, the amount added being such that to 1 mol of the anhydride there are 4 mols of the amine The addition is completed after 80 minutes, and the mixture is held at 1 10-1200Cfor2 hours.
Formed water and dioxane are removed in vacuo until the solution has become viscous. There are successively added hot heptane, toluene, hexane and ethyl ether until a solid substance in a yield of about 70% is obtained. The analysis (thin-layer chromatography, infra-red and NMR spectroscopy, amine titration, elementary analysis and electrical conductivity) shows that the product obtained is the amide of the formula IV (m.p.
124--1270C):
The resulting product contains no salt-like compounds, such as amine carboxylate.
A mixture of 100 parts of (IV) with 54 parts of tetraglycidyiated methylenedianiline and 54 parts
of triglycidylated p-aminophenol remains
sufficiently storage-stable for 4 months at room
temperature.
Example 2
By the process described in J. Chem. Soc.,
1945, pp. 625-628, bis-(p-aminocyclohexyl)
methane is reacted in an aqueous medium with
phthalimide to give bis-(p-aminocyclohexyl)
methane phthalamide, the procedure being such
that there is added to an aqueous emulsion of the
amine, produced by vigorous stirring, within 10 minutes at room temperature, finely ground
phthalimide in an amount of 1 mol to 2.4 mols of amine; the mixture is then stirred for a further 40 minutes, subsequently poured into a separating funnel, and extracted with chloroform. The extract is dried over magnesium sulfate, filtered and freed from chloroform. The product is afterwards washed with hexane and then with an hydros ethyl ether; the washing agent residues are distilled off in a vacuum oven.
A glassy product is obtained in a yield of 28% with a melting range of 75 to 900C. The analysis (NMR spectrum) shows a reaction product consisting of 2 mols of amine with one mol of imide.
Example 3
In the same manner as that described in
Example 2, phthalimide is reacted with 1,3-bis (aminomethyl)-cyclohexane to obtain a glassy product having a melting range of 54-660C.
According to IR and NMR spectra, the product is the diamide consisting of 1 molecule of phthalic acid and 2 molecules of the amine.
Example 1
In the manner described in Example 2, phthalimide is reacted with 1 ,2-diaminocyclo- hexane. A slightly brownish coloured product having a melting range of 69-750C is obtained.
the IR and NMR spectra show that the product is a diamide consisting of 1 molecule of phthalic acid and 2 molecules of the amine.
Example 5
The same product as in Example 4 is obtained also by reaction of phthalic anhydride with 1,2diaminocyclohexane, whereby 2 mols of the amine are reacted with 1 mol of the an hydride for 45 minutes at 1250C, without the use of a solvent.
In the same manner as described in the
Examples, it is possible to react also the other aforementioned amines with the corresponding imides or acid anhydrides to obtain compounds according to the invention.
Application examples
A homogeneous paste consisting of 100 parts of the compound according to Example 1 as curing agent, 54 parts of tetraglycidylated methyienedianiline (ArralditB MY 720) and 54 parts of triglycidylated p-aminophenol (Araldit(B) 0510) is subjected to a differential thermoanalysis (DSC: differential scanning calorimetry).
It is found that at 11 40C a heat of reaction of 293.16 kJ per mol is developed. This value shows that the reaction is virtually complete at temperatures below 1 500C. The mixture is stored at room temperature, and is examined at regular intervals of time to determine its stability in storage. It is shown that the heat of reaction during 11 weeks decreases only slightly (from 293 kJ to 279 kJ/mol, which is 96.5% of the initial value). It is still 84% of its initial value after
16 weeks. Colour and flow properties are practically unchanged after five months, and all tests show a shelf life at room temperature of four months.
The mixture is moulded in a moulding press for 30 minutes at 1 500C under a pressure of 412
MPa to obtain round discs of 2.5 cm diameter.
After a postcuring at 1 500C, the glass transition temperature is determined as being 1 20 to 1 300C (DCS method). The water adsorption at 71 0C with 95% relative humidity is 5.5%.
Similar values are obtained with the use of compounds according to Examples 2 to 5 and epoxy resin mixtures according to this Example, or epoxy resins based on bisphenol-A or cycloaliphatic epoxy resins.
Claims (11)
1. A compound of the formula I
wherein Y is an aromatic, cycloaliphatic or
aliphatic radical, to which the two carbonyl
groups shown in the formula are bound in
adjacent positions with respect to each other, and
R is an aryiene, aralkylene, cycloalkylene or cycloalkylalkylene group.
2. A compound according to Claim 1, wherein
Y in the formula I is the radical of phthalic acid,
tetra- or hexahydrophthalic acid, succinic acid, dodecylsuccinic acid or maleic acid.
3. A compound according to Claim 1, wherein
R in the formula I is the m-xylylene group, 1,2- or
1,4-cyclohexylene group, bis-(cyclohexylene)
methane group, 1 ,3- or 1 ,4-bis-methylene-cyclo
hexane group, bis-(3-methyl-cyclohex-l ,4-ylene- methane group or 3,5,5-trimethyl-3-methylene
cyclohexyl group.
4. A compound according to Claim 1, wherein
R is the m- or p-phenylene group, the p,p'diphenylmethane group, the bis(p-phenyl)-sulfone group or the 1 -(p-phenylene-1 ,3,3-trimethyl- indan-6-yl group.
5. A compound according to Claims 2 and 3 or 2 and 4.
6. A compound of formula I substantially as described with reference to any of Examples 1 to 5.
7. A process for producing a compound of the formula I according to any one of claims 1 to 6, which process comprises reacting a compound of the formula Ila or llb
with a compound of formula Ill H2N-R-NH2 (Ill), wherein Y and R have the meanings defined in
Claims 1 to 5.
8. A process of producing a compound of formula I substantially as described with reference to any of Examples 1 to 5.
9. A compound of formula I when produced by a process claimed in claim 7 or 8.
10. A curable mixture which contains a compound according to any one of Claims 1 to 6 and a polyepoxy compound.
11. A curable mixture according to claim 10 substantially as described with reference to any of the Application Examples.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US33185681A | 1981-12-17 | 1981-12-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2112388A true GB2112388A (en) | 1983-07-20 |
GB2112388B GB2112388B (en) | 1985-10-30 |
Family
ID=23295660
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08235554A Expired GB2112388B (en) | 1981-12-17 | 1982-12-14 | Carboxylic acid amides containing amino groups and mixtures containing these amides and epoxy resins |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS58110552A (en) |
CH (1) | CH650767A5 (en) |
DE (1) | DE3246267A1 (en) |
FR (1) | FR2518541B1 (en) |
GB (1) | GB2112388B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0161736A1 (en) * | 1984-02-08 | 1985-11-21 | E.I. Du Pont De Nemours And Company | Chlorosulfonated polyethylene coating composition |
EP0174725A1 (en) * | 1984-08-09 | 1986-03-19 | E.I. Du Pont De Nemours And Company | Chlorosulfonated ethylene vinyl acetate polymer coating composition |
EP0329266A2 (en) * | 1988-02-19 | 1989-08-23 | Texaco Development Corporation | Amidoamine and oxamidoamine co-curatives in epoxy thermoset adhesive |
WO1991009835A1 (en) * | 1989-12-28 | 1991-07-11 | Hoechst Aktiengesellschaft | Biscationic acid amide and acid imide derivatives and process for preparing them |
US5117058A (en) * | 1990-11-09 | 1992-05-26 | Baker Hughes Incorporated | Cationic amide/ester compositions as demulsifiers |
EP0654465A1 (en) * | 1993-11-15 | 1995-05-24 | Ciba-Geigy Ag | Polyaminopolyamides |
EP1219656A1 (en) * | 2000-12-26 | 2002-07-03 | Mitsubishi Gas Chemical Company, Inc. | Composition for coating having a gas barrier property, coating and coated film having a gas barrier property used the same |
US7336106B2 (en) | 2004-03-31 | 2008-02-26 | Micron Technology, Inc. | Phase detector and method having hysteresis characteristics |
US7425598B2 (en) * | 2001-09-05 | 2008-09-16 | Mitsubishi Gas Chemical Company, Inc. | Adhesive of epoxy resin and curing agent with xylylene diamine structure |
CN117025117A (en) * | 2023-08-11 | 2023-11-10 | 青岛德聚胶接技术有限公司 | High-temperature-resistant and deformation-resistant chip epoxy adhesive film and preparation method thereof |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4024466C2 (en) * | 1990-07-30 | 1995-04-20 | Dainippon Ink & Chemicals | Thermally curable mixtures of polyfunctional formamides and aromatic mono-, di- or polyglycidyl ethers and their use |
US6111030A (en) * | 1994-01-21 | 2000-08-29 | Rheox, Inc. | Epoxy, polysulfide and cyanoacrylate composites utilizing activatable amino-polyamide curatives |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2041772A1 (en) * | 1970-08-22 | 1972-02-24 | Bayer Ag | Amide group-containing aliphatic diamines and a process for their preparation |
-
1982
- 1982-12-10 CH CH720982A patent/CH650767A5/en not_active IP Right Cessation
- 1982-12-14 DE DE19823246267 patent/DE3246267A1/en not_active Withdrawn
- 1982-12-14 GB GB08235554A patent/GB2112388B/en not_active Expired
- 1982-12-16 FR FR8221101A patent/FR2518541B1/en not_active Expired
- 1982-12-17 JP JP22172282A patent/JPS58110552A/en active Pending
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0161736A1 (en) * | 1984-02-08 | 1985-11-21 | E.I. Du Pont De Nemours And Company | Chlorosulfonated polyethylene coating composition |
EP0174725A1 (en) * | 1984-08-09 | 1986-03-19 | E.I. Du Pont De Nemours And Company | Chlorosulfonated ethylene vinyl acetate polymer coating composition |
EP0329266A2 (en) * | 1988-02-19 | 1989-08-23 | Texaco Development Corporation | Amidoamine and oxamidoamine co-curatives in epoxy thermoset adhesive |
EP0329266A3 (en) * | 1988-02-19 | 1989-10-11 | Texaco Development Corporation | Amidoamine and oxamidoamine co-curatives in epoxy thermoset adhesive |
US5329046A (en) * | 1989-12-28 | 1994-07-12 | Hoechst Aktiengesellschaft | Biscationic acid amide and imide derivatives and processes for their preparation |
WO1991009835A1 (en) * | 1989-12-28 | 1991-07-11 | Hoechst Aktiengesellschaft | Biscationic acid amide and acid imide derivatives and process for preparing them |
US5117058A (en) * | 1990-11-09 | 1992-05-26 | Baker Hughes Incorporated | Cationic amide/ester compositions as demulsifiers |
EP0654465A1 (en) * | 1993-11-15 | 1995-05-24 | Ciba-Geigy Ag | Polyaminopolyamides |
EP1219656A1 (en) * | 2000-12-26 | 2002-07-03 | Mitsubishi Gas Chemical Company, Inc. | Composition for coating having a gas barrier property, coating and coated film having a gas barrier property used the same |
AU782542B2 (en) * | 2000-12-26 | 2005-08-11 | Mitsubishi Gas Chemical Company, Inc. | Composition for coating having a gas barrier property, coating and coated film having a gas barrier property used the same |
US7267877B2 (en) | 2000-12-26 | 2007-09-11 | Mitsubishi Gas Chemical Company, Inc. | Composition for coating having a gas barrier property, coating and coated film having a gas barrier property used the same |
US7271224B2 (en) | 2000-12-26 | 2007-09-18 | Mitsubishi Gas Chemical Company, Inc. | Composition for coating having a gas barrier property, coating and coated film having a gas barrier property used the same |
US7425598B2 (en) * | 2001-09-05 | 2008-09-16 | Mitsubishi Gas Chemical Company, Inc. | Adhesive of epoxy resin and curing agent with xylylene diamine structure |
US7336106B2 (en) | 2004-03-31 | 2008-02-26 | Micron Technology, Inc. | Phase detector and method having hysteresis characteristics |
CN117025117A (en) * | 2023-08-11 | 2023-11-10 | 青岛德聚胶接技术有限公司 | High-temperature-resistant and deformation-resistant chip epoxy adhesive film and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
GB2112388B (en) | 1985-10-30 |
JPS58110552A (en) | 1983-07-01 |
FR2518541B1 (en) | 1986-09-12 |
CH650767A5 (en) | 1985-08-15 |
DE3246267A1 (en) | 1983-06-30 |
FR2518541A1 (en) | 1983-06-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |