GB2096631A - Fluorosilicone rubber composition process and polymer - Google Patents
Fluorosilicone rubber composition process and polymer Download PDFInfo
- Publication number
- GB2096631A GB2096631A GB8210206A GB8210206A GB2096631A GB 2096631 A GB2096631 A GB 2096631A GB 8210206 A GB8210206 A GB 8210206A GB 8210206 A GB8210206 A GB 8210206A GB 2096631 A GB2096631 A GB 2096631A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymer
- composition
- carbon atoms
- vinyl
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 229920000642 polymer Polymers 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims description 15
- 229920005560 fluorosilicone rubber Polymers 0.000 title description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 21
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims abstract description 8
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims abstract description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 50
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 41
- 239000003054 catalyst Substances 0.000 claims description 29
- 229920005601 base polymer Polymers 0.000 claims description 28
- 229910052697 platinum Inorganic materials 0.000 claims description 25
- 239000000945 filler Substances 0.000 claims description 17
- -1 lithopone Chemical compound 0.000 claims description 13
- 229920002379 silicone rubber Polymers 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229910021485 fumed silica Inorganic materials 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 239000004945 silicone rubber Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- 239000004965 Silica aerogel Substances 0.000 claims description 2
- 239000010425 asbestos Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 239000007799 cork Substances 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 150000002432 hydroperoxides Chemical class 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052895 riebeckite Inorganic materials 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 229910021489 α-quartz Inorganic materials 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims 1
- 150000003058 platinum compounds Chemical class 0.000 abstract description 4
- 239000003431 cross linking reagent Substances 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 abstract description 3
- 229940045985 antineoplastic platinum compound Drugs 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 239000013638 trimer Substances 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000004971 Cross linker Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
- 150000004678 hydrides Chemical class 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 238000011067 equilibration Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- URZHQOCYXDNFGN-UHFFFAOYSA-N 2,4,6-trimethyl-2,4,6-tris(3,3,3-trifluoropropyl)-1,3,5,2,4,6-trioxatrisilinane Chemical compound FC(F)(F)CC[Si]1(C)O[Si](C)(CCC(F)(F)F)O[Si](C)(CCC(F)(F)F)O1 URZHQOCYXDNFGN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical class C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000003057 platinum Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- LUVCTYHBTXSAMX-UHFFFAOYSA-N tris(2-chloroethyl) phosphite Chemical compound ClCCOP(OCCCl)OCCCl LUVCTYHBTXSAMX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 229910019032 PtCl2 Inorganic materials 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- DZKBJRBCLDHGOV-UHFFFAOYSA-N [SiH3][N] Chemical compound [SiH3][N] DZKBJRBCLDHGOV-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000005724 cycloalkenylene group Chemical group 0.000 description 1
- ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical class C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 description 1
- QRBVERKDYUOGHB-UHFFFAOYSA-L cyclopropane;dichloroplatinum Chemical compound C1CC1.Cl[Pt]Cl QRBVERKDYUOGHB-UHFFFAOYSA-L 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25328281A | 1981-04-09 | 1981-04-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB2096631A true GB2096631A (en) | 1982-10-20 |
Family
ID=22959621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8210206A Withdrawn GB2096631A (en) | 1981-04-09 | 1982-04-06 | Fluorosilicone rubber composition process and polymer |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS57182353A (enrdf_load_stackoverflow) |
DE (1) | DE3213053A1 (enrdf_load_stackoverflow) |
FR (1) | FR2503724A1 (enrdf_load_stackoverflow) |
GB (1) | GB2096631A (enrdf_load_stackoverflow) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0239812A3 (en) * | 1986-03-04 | 1988-09-21 | Toray Silicone Company, Ltd. | Method for preparing cured organopolysiloxane compositions |
EP0252652A3 (en) * | 1986-07-02 | 1989-04-12 | Dow Corning Corporation | Method for preparing vinyl terminated fluorine-containing polydiorganosiloxane |
EP0252665A3 (en) * | 1986-07-02 | 1989-04-19 | Dow Corning Corporation | Heat stable fluorinated polyorganosiloxane compositions |
EP0251483A3 (en) * | 1986-06-04 | 1989-06-28 | Dow Corning Corporation | Pressure sensitive adhesive release liner and fluorosilicone compounds, compositions and method therefor |
EP0311262A3 (en) * | 1987-09-14 | 1989-07-12 | Shin-Etsu Chemical Co., Ltd. | Curable silicone composition |
EP0263649A3 (en) * | 1986-10-09 | 1989-07-19 | Dow Corning Corporation | Heat curable fluorosilicone coating composition |
US5073422A (en) * | 1987-11-12 | 1991-12-17 | Shin-Etsu Chemical Co., Ltd. | Pressure-sensitive adhesive structure |
EP0469928A3 (en) * | 1990-08-03 | 1992-04-29 | Shin-Etsu Chemical Co., Ltd. | Curable silicone composition and its cured product |
EP0611785A3 (en) * | 1993-02-15 | 1995-05-17 | Shinetsu Chemical Co | Linear organopolysiloxanes and process for their preparation. |
GB2290990A (en) * | 1994-07-11 | 1996-01-17 | Gen Electric | Fluorosilicone coatings |
WO2006007917A1 (en) * | 2004-07-20 | 2006-01-26 | Maflon S.R.L. | Composition of fluorinated silicones, particularly but not exclusively for adhesive-releasing coatings, and preparation thereof |
CN100396715C (zh) * | 2006-04-17 | 2008-06-25 | 广州天赐有机硅科技有限公司 | 一种支链型苯基硅油及制备方法 |
CN103435806A (zh) * | 2013-07-17 | 2013-12-11 | 烟台德邦先进硅材料有限公司 | 一种支链型苯基硅油及其制备方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4711818A (en) * | 1986-05-27 | 1987-12-08 | Xerox Corporation | Fusing member for electrostatographic reproducing apparatus |
JP4835880B2 (ja) | 2009-03-12 | 2011-12-14 | 信越化学工業株式会社 | 液状硬化性フロロシリコーン組成物の製造方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2800494A (en) * | 1954-10-22 | 1957-07-23 | Dow Corning | Unsaturated fluorocarbon silanes and their hydrolysis products |
US4029629A (en) * | 1975-10-06 | 1977-06-14 | General Electric Company | Solvent resistant room temperature vulcanizable silicone rubber composition |
-
1982
- 1982-04-06 GB GB8210206A patent/GB2096631A/en not_active Withdrawn
- 1982-04-07 DE DE19823213053 patent/DE3213053A1/de not_active Withdrawn
- 1982-04-08 FR FR8206171A patent/FR2503724A1/fr not_active Withdrawn
- 1982-04-09 JP JP5840482A patent/JPS57182353A/ja active Granted
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0239812A3 (en) * | 1986-03-04 | 1988-09-21 | Toray Silicone Company, Ltd. | Method for preparing cured organopolysiloxane compositions |
EP0251483A3 (en) * | 1986-06-04 | 1989-06-28 | Dow Corning Corporation | Pressure sensitive adhesive release liner and fluorosilicone compounds, compositions and method therefor |
EP0252652A3 (en) * | 1986-07-02 | 1989-04-12 | Dow Corning Corporation | Method for preparing vinyl terminated fluorine-containing polydiorganosiloxane |
EP0252665A3 (en) * | 1986-07-02 | 1989-04-19 | Dow Corning Corporation | Heat stable fluorinated polyorganosiloxane compositions |
EP0263649A3 (en) * | 1986-10-09 | 1989-07-19 | Dow Corning Corporation | Heat curable fluorosilicone coating composition |
EP0311262A3 (en) * | 1987-09-14 | 1989-07-12 | Shin-Etsu Chemical Co., Ltd. | Curable silicone composition |
US4985526A (en) * | 1987-09-14 | 1991-01-15 | Shin-Etsu Chemical Co., Ltd. | Curable silicone composition |
US5073422A (en) * | 1987-11-12 | 1991-12-17 | Shin-Etsu Chemical Co., Ltd. | Pressure-sensitive adhesive structure |
EP0469928A3 (en) * | 1990-08-03 | 1992-04-29 | Shin-Etsu Chemical Co., Ltd. | Curable silicone composition and its cured product |
US5204436A (en) * | 1990-08-03 | 1993-04-20 | Shin-Etsu Chemical Co., Ltd. | Curable silicone composition and its cured product |
EP0611785A3 (en) * | 1993-02-15 | 1995-05-17 | Shinetsu Chemical Co | Linear organopolysiloxanes and process for their preparation. |
GB2290990A (en) * | 1994-07-11 | 1996-01-17 | Gen Electric | Fluorosilicone coatings |
US5616403A (en) * | 1994-07-11 | 1997-04-01 | General Electric Company | Fluorosilicone coatings |
US5753318A (en) * | 1994-07-11 | 1998-05-19 | General Electric Company | Fluorosilicone coatings |
GB2290990B (en) * | 1994-07-11 | 1999-02-24 | Gen Electric | Fluorosilicone coatings |
US5919526A (en) * | 1994-07-11 | 1999-07-06 | General Electric Company | Fluorosilicone coatings |
US6074703A (en) * | 1994-07-11 | 2000-06-13 | General Electric Company | Fluorosilicone coatings |
WO2006007917A1 (en) * | 2004-07-20 | 2006-01-26 | Maflon S.R.L. | Composition of fluorinated silicones, particularly but not exclusively for adhesive-releasing coatings, and preparation thereof |
CN100396715C (zh) * | 2006-04-17 | 2008-06-25 | 广州天赐有机硅科技有限公司 | 一种支链型苯基硅油及制备方法 |
CN103435806A (zh) * | 2013-07-17 | 2013-12-11 | 烟台德邦先进硅材料有限公司 | 一种支链型苯基硅油及其制备方法 |
CN103435806B (zh) * | 2013-07-17 | 2015-09-02 | 烟台德邦先进硅材料有限公司 | 一种支链型苯基硅油及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
JPS57182353A (en) | 1982-11-10 |
DE3213053A1 (de) | 1982-11-11 |
FR2503724A1 (fr) | 1982-10-15 |
JPS632299B2 (enrdf_load_stackoverflow) | 1988-01-18 |
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