GB2079742A - Optical fibre preform manufacture - Google Patents

Optical fibre preform manufacture Download PDF

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Publication number
GB2079742A
GB2079742A GB8118476A GB8118476A GB2079742A GB 2079742 A GB2079742 A GB 2079742A GB 8118476 A GB8118476 A GB 8118476A GB 8118476 A GB8118476 A GB 8118476A GB 2079742 A GB2079742 A GB 2079742A
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GB
United Kingdom
Prior art keywords
tube
electric field
optical fibre
hot zone
bore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8118476A
Other versions
GB2079742B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Standard Electric Corp
Original Assignee
International Standard Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Standard Electric Corp filed Critical International Standard Electric Corp
Publication of GB2079742A publication Critical patent/GB2079742A/en
Application granted granted Critical
Publication of GB2079742B publication Critical patent/GB2079742B/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04Coating on selected surface areas, e.g. using masks
    • C23C16/045Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/453Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating passing the reaction gases through burners or torches, e.g. atmospheric pressure CVD

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

Internal CVD is assisted by an electric field downstream of hot zone 3 and moving conjointly therewith. The field may be generated by (a) static electricity produced by the friction of brushes 4 (Figure 1) or of a dry gas jet on the outside of the tube 1, or (b) electrodes 7, 8 (Figure 3). <IMAGE>

Description

SPECIFICATION Vapour deposited optical fibre This invention relates to the formation of a coating on the bore of a glass substrate tube to form an internally coated tube for optical fibre waveguide manufacture. In particular it relates to the formation of such a coating by a method in which the coating is formed as a deposition product of a chemical vapour reaction between vapour phase reagents caused to flow down the substrate tube, and caused to react in a localised hot zone traversed along the tube, the deposition product being collected on the internal wall of tube downstream of the hot zone. One example of such a coating process is described in International Patent Application No. WO 80/00440, and in that example collection of the deposition product on the wall of the tube is assisted by thermophoresis.
According to the present invention there is provided a method of forming a coating on the bore of a glass substrate tube for optical fibre waveguide manufacture, wherein vapour phase reagents are caused to flow through the tube while it is rotated about its axis and caused to react to form a deposit in the localised region of a hot zone traversed along the tube, which deposit is collected on the inner wall of the tube downstream of the hot zone to form a glassy coating, wherein a local electric field is produced in the tube downstream of the hot zone and moved synchronously therewith, which electric field assists said collection of the deposit.
There follows a description of the manufacture of an optical fibre waveguide by methods embodying the invention in preferred forms. The description refers to the accompanying drawings in which Figures 1,2, and 3 are schematic diagrams of alternative forms of deposition apparatus.
Referring to Figure 1, a glass substrate tube 1 whose inner wall is to be coated is held horizontally in a lathe (not shown) and is rotated about its axis during the coating process. A heat source 2, for example an oxy-hydrogen burner, produces a localised hot zone 3 in the tube 1. The heat source is mounted on a support 5 which allows itto be smoothly traversed in the axial direction of the tube so that the hot zone 3 can be traversed up and down the tube. Reagents, which may be in the gaseous or vapour state, for the chemical vapour reaction used to provide the required deposit on the bore of the tube are caused to flow through the tube in the direction of the arrow 1 A. These reagents react in the heated zone 3 and produce glass forming reaction products which are collected and fused together to form a glassy coating downstream of the hot zone 3.
Rotation of the tube and controlled translation of the burner ensure that a coating of uniform thickness is laid down.
With the apparatus as therefor described it is found that a significant proportion of the glass forming reaction product which should go to form the coating may be lost, that is it fails to be collected upon the bore of the tube but gets discharged from the tube 1 amongst the spent reagent gases. Deposition efficiency is improved by providing a local electric field downstream of the hot zone 3.
In the apparatus of Figure 1 this electric field is provided by friction-producing means 4 arranged to rub the outer wall of the tube 1 as it is rotated and thereby produce static electricity. The acceleration of the glass-forming reaction products in direction to the inner wall of the tube owing to the resulting electric field is due to the fact that a dielectric body within an inhomogenous electric field is given a force in direction to the location of higher field intensity. From the friction-producing means it is possible to use brushes or other elements made of a suitable material. The friction-producing means 4 is arranged at a fixed spacing downstream of the heated zone. For this purpose it is conveniently mounted on the support 5 on which the heat source 2 is mounted to both.Accordingly, the produced electric field is moved along the longitudinal axis of the substrate tube in synchronism with the hot zone 3.
In the apparatus depicted in Figure 2 the local electric field is similarly built up by producing static electricity on the substrate tube 1, but in this case the substrate tube 1 is not rubbed by physical frictionproducing means, but by a dry gas stream, which is blown at it within a restricted region from a jet 6.
This jet 6 is again mounted in common with the heat force on a joint support 5 so that the electric field produced by way of friction within a region downstream of the hot zone 3, is traversed synchronously with that hot zone along the longitudinal axis of the substrate tube 1. The gas for the dry gas stream flowing out of the jet 6 is conveniently an inert gas, such as nitrogen.
A further possibility for producing the electric field assisting the deposition of glass-forming material, is shown in Figure 3. Here, the electric field is produced with the aid of two electrodes 7 and 8 which are connected to the poles of a source of DC voltage source 9. The one electrode 8 is of rod-shaped design and projects into the substrate tube 1 from the end from which the exhaust gases emerge. The other electrode 7 is arranged outside the substrate tube 1 downstream of the heat source 2 and, for example, is of annular design, so that in the space between the two electrodes there exists an almost radial symmetrical electric field.The inner electrode 8 is connected to the negative pole, and the outer electrode 7 is connected to the positive pole of the source of voltage 9.ln order that the electric field, as in the hitherto described examples of embodiment, can be moved in synchronism with the hot zone 3, both electrodes together with their holding elements 10 and 11, are arranged rigidly with respect to the heat source 2. For this purpose holding elements 10, 11 are firmly connected to the heat source 2 by means of a rod 12. The support common to both the heat source 2 and the holding elements 10 and 11 is not shown in the drawings.
The electric field as built up by the electrodes 7 and 8, now acts in the way of an electrofilter of the type known per se.
In the direct proximity of the inner electrode 8 there exists a high electric field intensity under the influence of which glass-forming particles are charged negatively. The thus charged particles move in direction towards the positive electrode 7 and are thus deposited on the inner wall of the tube.
Once the required deposition has been completed, the temperature of the hot zone is increased so as to soften the glass tube to the extent that its bore collapses under the effects of surface tension. The heat source is traversed and the process continued until the bore has been completely eliminated from the main body of the tube so as to produce an optical fibre waveguide preform with a solid cross-section.
The preform is removed from the lathe and is subsequently mounted in a pulling tower in which it is drawn into optical fibre waveguide.

Claims (10)

1. A method of forming a coating on the bore of a glass substrate tube for optical fibre waveguide manufacture, wherein vapour phase reagents are caused to flow through the tube while it is rotated about its axis and caused to react to form a deposit in the localised region of a hot zone traversed along the tube, which deposit is collected on the inner wall ofthetube downstream of the hot zone to form a glassy coating, wherein a local electric field is produced in the tube downstream of the hot zone and moved synchronously therewith, which electric field assists said collection of the deposit.
2. A method as claimed in claim 1, wherein said electric field is built up by way of producing static electricity on said substrate tube.
3. A method as claimed in claim 2, wherein said static electricity is established by a physical rubbing of the outer wall of the tube.
4. A process as claimed in claim 2, wherein said static electricity is established by directing a dry gas stream against the outer wall ofthetube.
5. A method as claimed in claim 1, wherein said electric field is produced between two electrodes one arranged inside, and the other electrode arranged outside said substrate tube in such a way that between said electrodes there exists a radially directed electric field.
6. A method as claimed in claim 5, wherein said internal electrode is of rod-shaped, and said external electrode is of ring-shaped design.
7. A method of forming a coating on the bore of glass substrate tube for optical fibre waveguide manufacture, which method is substantially as hereinbefore described with reference to Figure 1, 2 or 3 of the accompanying drawings.
8. A coated tube coated by the method claimed in any preceding claim.
9. Asolid cross-section optical fibrewaveguide preform made by collapsing the bore of a coated tube as claimed in claim 8.
10. An optical fibre waveguide drawn from a preform as claimed in claim 9.
GB8118476A 1980-07-19 1981-06-16 Optical fibre preform manufacture Expired GB2079742B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19803027450 DE3027450C2 (en) 1980-07-19 1980-07-19 Process for the inner coating of a glass substrate tube for the production of a glass fiber light guide

Publications (2)

Publication Number Publication Date
GB2079742A true GB2079742A (en) 1982-01-27
GB2079742B GB2079742B (en) 1984-02-15

Family

ID=6107625

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8118476A Expired GB2079742B (en) 1980-07-19 1981-06-16 Optical fibre preform manufacture

Country Status (6)

Country Link
AT (1) AT380867B (en)
BE (1) BE889655A (en)
CH (1) CH652112A5 (en)
DE (1) DE3027450C2 (en)
FR (1) FR2486927A1 (en)
GB (1) GB2079742B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3206175A1 (en) * 1982-02-20 1983-08-25 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Process for the production of a preform from which optical fibres can be drawn
EP0129291A1 (en) * 1983-06-15 1984-12-27 Koninklijke Philips Electronics N.V. Method of and device for manufacturing optical fibres
EP0134507A1 (en) * 1983-07-20 1985-03-20 Licentia Patent-Verwaltungs-GmbH Process of depositing a layer on a body
US6003342A (en) * 1991-10-25 1999-12-21 The Furukawa Electric Co., Ltd. Apparatus for production of optical fiber preform
EP1001050A2 (en) * 1998-11-16 2000-05-17 Forschungszentrum Karlsruhe GmbH Process for internal coating of capillaries and use of such capillaries
WO2006096659A2 (en) * 2005-03-07 2006-09-14 Sub-One Technology, Inc. Method and system for coating sections of internal surfaces

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3319448A1 (en) * 1983-05-28 1984-11-29 Standard Elektrik Lorenz Ag, 7000 Stuttgart METHOD FOR PRODUCING LIGHTWAVE GUIDES
KR0168009B1 (en) * 1996-09-13 1999-10-15 김광호 A cooling device
US20080210290A1 (en) * 2006-04-14 2008-09-04 Dau Wu Plasma inside vapor deposition apparatus and method for making multi-junction silicon thin film solar cell modules and panels

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2444100C3 (en) * 1974-09-14 1979-04-12 Philips Patentverwaltung Gmbh, 2000 Hamburg Process for the production of internally coated glass tubes for drawing optical fibers
US3982916A (en) * 1975-12-24 1976-09-28 Bell Telephone Laboratories, Incorporated Method for forming optical fiber preform
DE2930781A1 (en) * 1979-07-28 1981-02-12 Licentia Gmbh Glass optical waveguide fibre - with non-symmetrical profile of refractive index used to separate two light waves polarised in orthogonal directions

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3206175A1 (en) * 1982-02-20 1983-08-25 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Process for the production of a preform from which optical fibres can be drawn
EP0129291A1 (en) * 1983-06-15 1984-12-27 Koninklijke Philips Electronics N.V. Method of and device for manufacturing optical fibres
EP0134507A1 (en) * 1983-07-20 1985-03-20 Licentia Patent-Verwaltungs-GmbH Process of depositing a layer on a body
US6003342A (en) * 1991-10-25 1999-12-21 The Furukawa Electric Co., Ltd. Apparatus for production of optical fiber preform
EP1001050A2 (en) * 1998-11-16 2000-05-17 Forschungszentrum Karlsruhe GmbH Process for internal coating of capillaries and use of such capillaries
EP1001050A3 (en) * 1998-11-16 2001-04-18 Forschungszentrum Karlsruhe GmbH Process for internal coating of capillaries and use of such capillaries
WO2006096659A2 (en) * 2005-03-07 2006-09-14 Sub-One Technology, Inc. Method and system for coating sections of internal surfaces
WO2006096659A3 (en) * 2005-03-07 2007-03-01 Sub One Technology Inc Method and system for coating sections of internal surfaces
US7608151B2 (en) 2005-03-07 2009-10-27 Sub-One Technology, Inc. Method and system for coating sections of internal surfaces

Also Published As

Publication number Publication date
FR2486927B1 (en) 1985-02-22
BE889655A (en) 1982-01-18
AT380867B (en) 1986-07-25
DE3027450A1 (en) 1982-02-18
GB2079742B (en) 1984-02-15
ATA316281A (en) 1985-12-15
FR2486927A1 (en) 1982-01-22
DE3027450C2 (en) 1982-06-03
CH652112A5 (en) 1985-10-31

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Legal Events

Date Code Title Description
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee