GB2051761A - Method and apparatus for the removal of oxidizable pollutants from gases - Google Patents
Method and apparatus for the removal of oxidizable pollutants from gases Download PDFInfo
- Publication number
- GB2051761A GB2051761A GB8018433A GB8018433A GB2051761A GB 2051761 A GB2051761 A GB 2051761A GB 8018433 A GB8018433 A GB 8018433A GB 8018433 A GB8018433 A GB 8018433A GB 2051761 A GB2051761 A GB 2051761A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- adsorbent
- line
- temperature
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000007789 gas Substances 0.000 title claims description 84
- 239000003344 environmental pollutant Substances 0.000 title claims description 10
- 231100000719 pollutant Toxicity 0.000 title claims description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 112
- 230000003647 oxidation Effects 0.000 claims abstract description 45
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 45
- 239000003463 adsorbent Substances 0.000 claims abstract description 27
- 230000003197 catalytic effect Effects 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 15
- 230000001172 regenerating effect Effects 0.000 claims abstract description 3
- 230000008929 regeneration Effects 0.000 claims description 62
- 238000011069 regeneration method Methods 0.000 claims description 62
- 238000000746 purification Methods 0.000 claims description 37
- 238000001179 sorption measurement Methods 0.000 claims description 33
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 238000002485 combustion reaction Methods 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 238000010517 secondary reaction Methods 0.000 claims description 8
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 40
- 229930195733 hydrocarbon Natural products 0.000 description 24
- 150000002430 hydrocarbons Chemical class 0.000 description 24
- 239000004215 Carbon black (E152) Substances 0.000 description 18
- 239000000126 substance Substances 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 12
- 239000012535 impurity Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 238000005265 energy consumption Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000002156 adsorbate Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000009877 rendering Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- -1 MgAI204 Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000012476 oxidizable substance Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK234879A DK156814C (da) | 1979-06-06 | 1979-06-06 | Anlaeg til fjernelse af oxiderbare bestanddele fra forurenede gasser, isaer fra forurenet luft |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB2051761A true GB2051761A (en) | 1981-01-21 |
Family
ID=8111760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8018433A Withdrawn GB2051761A (en) | 1979-06-06 | 1980-06-05 | Method and apparatus for the removal of oxidizable pollutants from gases |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS55165131A (enrdf_load_stackoverflow) |
| DE (1) | DE3021174A1 (enrdf_load_stackoverflow) |
| DK (1) | DK156814C (enrdf_load_stackoverflow) |
| FR (1) | FR2458308A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2051761A (enrdf_load_stackoverflow) |
| NL (1) | NL8003288A (enrdf_load_stackoverflow) |
| SE (1) | SE8003958L (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0514941A1 (en) * | 1991-05-24 | 1992-11-25 | Haldor Topsoe A/S | Process for the separation of sulphur oxides from offgases |
| FR2687330A1 (fr) * | 1992-02-18 | 1993-08-20 | Inst Francais Du Petrole | Procede de traitement d'air de ventilation contenant du styrene. |
| EP0630681A1 (de) * | 1993-06-24 | 1994-12-28 | MANNESMANN Aktiengesellschaft | Verfahren zur Entfernung unerwünschter Beimengungen eines Gases |
| US6019952A (en) * | 1996-12-17 | 2000-02-01 | L.U.T. Labor- Und Umwelttechnik Jena Gmbh | Process for oxidative exhaust gas cleaning |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5935726B2 (ja) * | 2013-03-07 | 2016-06-15 | マツダ株式会社 | 脱臭処理装置 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3150922A (en) * | 1961-01-16 | 1964-09-29 | Calumet & Hecla | Method of purifying exhaust gases of internal combustion engines |
| FR1400504A (fr) * | 1964-04-14 | 1965-05-28 | Texaco Development Corp | Perfectionnements aux catalyseurs et procédés pour le traitement de gaz d'échappement de moteurs |
| GB1120070A (en) * | 1965-01-08 | 1968-07-17 | Grace W R & Co | Improvements in or relating to the oxidation of exhaust gases from internal combustion engines |
| JPS5065465A (enrdf_load_stackoverflow) * | 1973-10-15 | 1975-06-03 | ||
| US4025605A (en) * | 1975-05-07 | 1977-05-24 | Air Products And Chemicals, Inc. | Method for removing low concentrations of oxidizable organic contaminants from an oxygen-containing inert gas |
| GB1582441A (en) * | 1976-04-09 | 1981-01-07 | Lamberg Ind Res Ass | Treatment of gaseous effluent |
-
1979
- 1979-06-06 DK DK234879A patent/DK156814C/da not_active IP Right Cessation
-
1980
- 1980-05-28 SE SE8003958A patent/SE8003958L/ not_active Application Discontinuation
- 1980-05-29 FR FR8011902A patent/FR2458308A1/fr active Granted
- 1980-06-04 DE DE19803021174 patent/DE3021174A1/de not_active Withdrawn
- 1980-06-05 NL NL8003288A patent/NL8003288A/nl active Search and Examination
- 1980-06-05 GB GB8018433A patent/GB2051761A/en not_active Withdrawn
- 1980-06-06 JP JP7567480A patent/JPS55165131A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0514941A1 (en) * | 1991-05-24 | 1992-11-25 | Haldor Topsoe A/S | Process for the separation of sulphur oxides from offgases |
| FR2687330A1 (fr) * | 1992-02-18 | 1993-08-20 | Inst Francais Du Petrole | Procede de traitement d'air de ventilation contenant du styrene. |
| EP0557155A1 (fr) * | 1992-02-18 | 1993-08-25 | Institut Francais Du Petrole | Procédé de traitement d'air de ventilation contenant du styrène |
| EP0630681A1 (de) * | 1993-06-24 | 1994-12-28 | MANNESMANN Aktiengesellschaft | Verfahren zur Entfernung unerwünschter Beimengungen eines Gases |
| US6019952A (en) * | 1996-12-17 | 2000-02-01 | L.U.T. Labor- Und Umwelttechnik Jena Gmbh | Process for oxidative exhaust gas cleaning |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2458308A1 (fr) | 1981-01-02 |
| JPS55165131A (en) | 1980-12-23 |
| JPH0347884B2 (enrdf_load_stackoverflow) | 1991-07-22 |
| DK156814C (da) | 1990-02-26 |
| DE3021174A1 (de) | 1980-12-11 |
| DK156814B (da) | 1989-10-09 |
| DK234879A (da) | 1980-12-07 |
| NL8003288A (nl) | 1980-12-09 |
| SE8003958L (sv) | 1980-12-07 |
| FR2458308B1 (enrdf_load_stackoverflow) | 1985-02-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |