GB2046798A - Sputtered platinum on zirconia exhaust gas oxygen sensor - Google Patents
Sputtered platinum on zirconia exhaust gas oxygen sensor Download PDFInfo
- Publication number
- GB2046798A GB2046798A GB8011187A GB8011187A GB2046798A GB 2046798 A GB2046798 A GB 2046798A GB 8011187 A GB8011187 A GB 8011187A GB 8011187 A GB8011187 A GB 8011187A GB 2046798 A GB2046798 A GB 2046798A
- Authority
- GB
- United Kingdom
- Prior art keywords
- platinum
- thimble
- electrode
- sputtering
- exhaust gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/09—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the vapour phase
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
- C23C14/185—Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9058—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of noble metals or noble-metal based alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Abstract
A method of sputtering a platinum exhaust gas electrode on to a vitrified zirconia thimble for an electrochemical- type exhaust gas oxygen sensor. Porous high surface area platinum films are deposited that have more consistent properties. A platinum target is spaced 3.0-4.5 cm from the thimble and more than 6 cm from the sputtering anode. A pressure of 10-20 millitorr (1.33322-2.66644 Pa) is used during sputtering at a DC power of 13-22 Watts/cm<2> of target area.
Description
SPECIFICATION
Exhaust electrode process for exhaust gas oxygen sensor
This invention relates to solid electrolyte, electrochemical-type exhaust gas oxygen sensors.
It more particularly relates to a sputtering process for depositing a platinum exhaust electrode on to a vitrified zirconia thimble for such a sensor.
A typical automotive-type solid electrolyte exhaust gas oxygen sensor is disclosed in
USPN 3,844,920 Burgett et al. It has a zirconia sensing element shaped as a tapered thimble. One end is open and has a circumferential flange. The other end is closed, and forms the most active part of the element. The interior and exterior of the thimble have separate porous electrode coatings of platinum.
The inner electrode is exposed to a source of oxygen, such as air or mixed metal oxide, for establishing a reference potential. This electrode has generally been formed by painting a coating of a platinum ink on to the zirconia thimble, drying the coating, and then firing the coated thimble at an elevated temperature.
The outer electrode also termed the exhaust electrode is exposed to exhaust gas for establishing a potential determined by exhaust gas oxygen concentration. The outer electrode can be a porous thick film of platinum, like the inner electrode. However, it is preferred that this outer electrode be a thin film, applied by evaporation, sputtering, chemical vapor deposition or other such thin film deposition technique. On the other hand, it has been difficult to reproduce consistently desirable properties, such as porosity and electrical parameters, in the thin film electrodes. As a result, yields of electrodes with satisfactory electrode properties have been limited, and various ancillary procedures have been developed to improve them. For example, United States Patent No.
3,978,006 Topp et al discloses heating the solid electrolyte body after electrode deposition, to form pores in the electrode coating if it is not porous as deposited. United States
Patent No. 4,1 36,000 Davis et al discloses treating the sensor element and electrodes chemically and electrolytically to enhance sensor properties. Moreover, it is known that zirconia-type exhaust gas sensors, particularly those with a sputtered exhaust electrode, are likely to change electrical characteristics after a short time in operation. Generally, there is an improvement, such as a reduction in switching response time. Consequently, it has been proposed to operate such sensors functionally in an actual or simulated exhaust gas stream until they are sufficiently stabilized, before installing them in an actual working system.Such treatments, of course, add to the cost of manufacture. Moreover, the yield
of higher performance sensors is still inher
ently limited by the quality of the electrode
film originally deposited. The method of the
present invention enables one to sputter plati
num films on to the zirconia surface in such a
manner that the film is consistently porous as
deposited and has a consistently high surface
area as deposited, which contributes to a
greater yield of high quality sensors. Sensors
with low lean-to-rich switching response times
are produced, without further chemical and
electrolytic treatments. Rich-to-lean switching
response times are initially not nearly as low
as lean-to-rich switching response times. How
ever, they are generally readily reduced to
acceptably low levels after only a short actual
or simulated aging.Hence, a high yield of
significantly fast reacting sensors is obtained
from minimal actual aging of the sensors. In
fact, sensors with exhaust electrodes produced
in accordance with this invention are suscepti
ble to aging by a simple furnace treatment, as
is disclosed and claimed in our co-pending
United States patent application Serial No.
030,747. In addition, a sizeable proportion of
sensors having exhaust electrodes produced
with this invention do not even need any
aging treatments for activation or stabilization.
Their electrical properties as formed are more
than adequate and remain substantially stable
during initial sensor use.
An object of this invention is to provide an
improved sputtering process for depositing a
platinum exhaust electrode on to a zirconia
solid electrolyte body for an electrochemical
type exhaust gas oxygen sensor.
The invention comprehends sputtering plati
num on to a vitrified zirconia solid electrolyte
body which is widely spaced from the plati
num target. The target is more than 3.7
centimeters away from the workpiece, in a
preferred example. The platinum is DC sput
tered (that is sputtered with the aid of a direct
electric current) from the target under a rela
tively high pressure of 10-20 millitorr
(1.33322-2.66644 Pa) and a sputtering
power of 13-22 watts/cm2 of target area.
Vitrified zirconia thimbles having a pre-de
posited inner platinum electrode can have the
outer electrode applied thereto in accordance
with this invention. These thimbles are about
3-5 cm long and are of zirconia partially or fully stabilized in its cubic form by the inclu
sion of about 4-8 mole percent yttria. Each
thimble has a taper on its outer surface of
about 3 degrees~38 minutes. In a particular
example, the thimble has an axial length of
3.66 cm. Its wider end has a circumferential
shoulder and a diameter 0.82 cm immediately
below the shoulder. Its narrower end is closed
and rounded, having an external spherical
radius of curvature of 3 mm. Its diameter
adjacent the rounded end is 0.4 cm. It is
believed that it is important to control deposi
tion on and near the rounded end tip.This appears to be the most active part of the sensing element. The inner electrode is formed on the thimbles first, preferably in the form of a platinum ink thick film fired to the zirconia surface. The thimbles are then cleaned to receive the thin film outer exhaust electrode in accordance with this invention.
As is usual for any thin film deposition process, the zirconia surface should be well cleaned before depositing the platinum electrode on to it in accordance with this invention. It is expected that any normal and accepted high quality cleaning procedures can be used. One cleaning procedure that can be used includes ultrasonically degreasing the zirconia with Freon (registered Trade Mark), and then heating the degreased thimble to about 600'C in air for about an hour. The zirconia thimbles are then placed on a stainless steel pallet, and the pallet placed in a vacuum chamber. The vacuum chamber is then pumped down to a pressure of approximately 100 millitorr (13.3322 Pa). While at or below this low pressure, the zirconia thimbles are heated again, to a temperature of about 200 C for about 10-15 minutes.While the zirconia thimbles are still warm, the vacuum chamber is backfilled with dry nitrogen to a pressure greater than 1 torr (133.322 Pa) in about 1 second. The chamber is then immediately pumped down again to a pressure below 2 X 10-6torr(266.644 > C 10-6
Pa). A flow of argon at 75-100 cc per minute is then started through the vacuum chamber while pumping continues. The flow of argon and the pumping continues and the vacuum valving is adjusted until pressure in the chamber equilibrates at 10-20 millitorr (1.33322-2.66644 Pa). This argon pressure is similarly dynamically maintained during the sputtering process. Chamber atmosphere is thus continually refreshed during sputtering.
In the process of the present invention it is possible to simultaneously sputter electrode films on to large groups of such zirconia thimbles, such as groups of over 200 thimbles. The pallet with its thimbles is placed directly on a horizontal planar steel pallet carrier. The thimble axes are parallel to each other and oriented vertically. Their open ends rest on the pallet. The pallet carrier is disposed 0.5-1.5 cm above the anode. However, it is not known if any separation is needed at all. The thimble closed ends face upwardly toward a planar platinum target surface of a cathode, which surface is spaced 3.8 cm above the thimble closed ends. The sputtering target is a platinum sheet bonded to a supporting copper backing plate. The target is assembled with a cathode that includes water cooling means and a magnet array.An argon pressure of 10-20 millitorr (1.33322-2.66644 Pa) is dynamically maintained in the sputtering chamber. A DC voltage of approximately 500 to 800 V is applied between the target and the anode. The sputtering power supply is adjusted to provide a
DC power between the target and the anode of approximately 13-22 watts/cm2 of target area. No special means are used in the pallet, pallet carrier, or anode to heat or cool the thimbles during sputtering.
Sputtering is continued under the above conditions, whilst maintaining the aforementioned 10-20 millitorr (1.33322-2.66644
Pa) argon pressure, until a platinum weight of 10 mg is deposited on to each element. This will produce a porous crystalline platinum deposit 1.0-1.5 micrometers thick on the rounded end, 0.65-1.0 micrometers thick about 0.5 cm distant from that end, and 0.3-0.75 micrometers thick about 2 cm distant from the rounded end. Coating thicknesses such as these are obtained by sputtering for 3-5 minutes under the foregoing conditions. It is believed that electrode porosity and perhaps surface area, and the resultant sensor electrical characteristics are a function of electrode thickness. Also, the temperature that the ceramic self-heats to during deposition is important.The techniques of this invention should provide an apparent electrode surface area at least double its geometric surface area. By apparent surface area is meant the surface area in the film coated part of the element as determined by conventional gas adsorption techniques. By geometric surface area is meant surface area as determined from a drawing of the element. In many instances the process of this invention will provide a fourfold increase in apparent surface area as deposited over the underlying zirconia surface, if the latter is not particularly rough.
Adhesion of the sputtered film to its underlying zirconia surface can be increased by heating the electroded element in air for about 1 hour at 800 C. Such a heating does appear to reduce apparent surface area significantly, and may open some large pores in the film, 0.5-5 micrometers in width. The number and.size of these openings appear to depend on the time and temperature of heating and the thickness of the film. The reduction in apparent surface area during this heating does not seem to be significantly detrimental to sensor performance. On the other hand, it seems important that the film have a high porosity and surface area as deposited. Otherwise, sensor performance is adversely affected by this heating.
The electrode film is then preferably given a porous ceramic coating on all its parts except where electrical connection is to be made. The porous ceramic coating can be catalytic or non catalytic, as desired, without significant initial operating effects on the resultant sensor. For example, it can be a gamma alumina coating prepared and applied as disclosed in
USPN 4,116,883 (Rhodes). However, it is preferable to flame spray a magnesium-aluminate spinel coating on to the electrode film after the heat treatment to increase electrode adhesion. It is recognized that applying the porous overcoating by flame spraying can apparently significantly physically alter the electrode film. However, it nonetheless appears that the essential functional characteristics of the electrode film remain substantially unchanged by the flame spraying.Consequently, the as-deposited characteristics of the electrode film remain fundamentally important.
As previously mentioned, the platinum target, or cathode, is spaced at least 3.5-4.0 cm, preferably about 3.8 cm above the closed ends of the zirconia thimbles and about 7.6 cm above the anode. This larger than the normal spacing is believed to provide improved electrode porosity and better process controllability. The indicated spacing appears to be critical. If a spacing closer than 3.0 cm is used between the zirconia closed ends and the target, less porous films appear to result.
A spacing greater than 4.5 cm appears unnecessary and objectionable. It requires higher power settings and argon pressures to obtain a satisfactory coating rate. Platinum deposition in unwanted areas of the apparatus is more likely to occur. Still further, the characteristics of the electrode film are less likely to be reproducible. The nature of the platinum target is no more critical to this invention than it is to any other sputtering of platinum. The target can be obtained from any commercial source, and preferably provides a high purity platinum surface. However, it is recognized that in some instances it may prove to be desirable to include minor amounts of other metals in the platinum target along with the pure platinum, as, for example, a few percent, up to about 5 percent, of palladium and/or rhodium.Because of cost, a platinum target is preferred in which the platinum or platinum alloy is only a surface coating.
A power setting of at least 13 watts/cm2 of target area is required. Lesser power settings apparently result in deposition rates too slow to produce significant porosity and surface area. Conversely, power settings in excess of 22 watts/cm2 of target area seem to be too severe on system components. Also, the higher power settings may produce platinum deposition in unwanted areas within the vacuum chamber. In any event, sensor performance is less reproducible with less than 13 watts/cm2 of target area. Pressures of 10-20 millitorr (1.33322-2.66644 Pa) are preferred. This higher pressure range is preferred even though higher power settings are employed. At pressures less than 10 millitorr (1.33322 Pa), the coating appears to be less porous, perhaps because the rate of deposition is too low. At pressures above 20 millitorr (2.66644 Pa), deposition rate also decreases.
Also, deposition may begin to occur on unwanted areas within the vacuum chamber.
The sputtering technique of this invention provides improved electrodes as deposited.
For example, lean-to-rich switching response times of less than 600 milliseconds can be consistently produced under commercial production conditions. Rich-to-lean switching response times of less than 1200 milliseconds are consistently produced, as deposited. However, after only a relatively short functioning of an hour or so in exhaust gas the rich-tolean switching response times consistently drop below 600 milliseconds. Controllability is at about 15 parts air to 1 part fuel, i.e. on the lean side and within about 0.5 air/fuel ratios.
Thus, even if the sensor is not fast-acting as formed, it can be consistently operationally aged to provide a fast-acting sensor. Further, the sensor characteristics obtained using electrodes produced by this invention are more reproducible. Higher yields of fast-acting sensors can be obtained by functional aging.
In addition, it has also been discovered that a simple furnace treatment in nitrogen can artificially age sensors having electrodes made in accordance with this invention. The furnace treatment is described and claimed in the aformentioned co-pending United States patent application Serial No. 030,747. DC magnetron sputtering is disclosed herein. However, the principles of this invention should also be applicable to ordinary DC sputtering and to RF sputtering. Still further, the electrode of this invention may be more durable if a platinum cermet stripe is first applied to the outer zirconia surface and fired. If narrow, the stripe need not be porous, and can be of any commercially available platinum ink that adheres well to zirconia when fired, and to which the sputtered platinum deposited over it will adhere.
It should also be noted that platinum was sputtered under an argon atmosphere in the hereinbefore described specific example of this invention. However, as revealed in our copending United States patent application Serial No. 030,748, a 10-20 millitorr (1.33322-2.66644 Pa) atmosphere predominantly of nitrogen and/or oxygen can be used. This co-pending United States patent application discloses that such an atmosphere provides significantly improved results over argon when sputtering platinum in accordance with this invention. An atmosphere of 67-75% nitrogen and the balance argon is preferred.
Recent tests indicate the method of this invention may be useful in producing electrodes consisting essentially of palladium.
However, it appears that a predominantly nitrogen and/or oxygen sputtering atmosphere is not preferred for sputtering such electrodes, and may even be undesirable.
Claims (3)
1. A method of sputtering a platinum ex haust gas electrode on to a vitrified zirconia solid electrolyte body for an electrochemicaltype exhaust gas oxygen sensor, in which a platinum target spaced at least 3.0 cm from the body is used in the sputtering, the platinum is sputtered at a pressure of 10-20 millitorr (1.33322-2.66644 Pa), and a sputtering power of 13-22 watts/cm2 of target area is used, so that the platinum electrode is deposited as a porous film which has an apparent surface area at least double the geometric area of the zirconia surface on which it lies.
2. A method according to claim 1, of sputtering a platinum exhaust gas electrode on to a vitrified zirconia solid electrolyte body in the shape of a thimble for an electrochemical-type exhaust gas oxygen sensor, in which the platinum target is a generally planar platinum target oriented normal to the axis of the zirconia thimble and spaced 3.0-4.5 cm from a closed end on the thimble, whereby the platinum electrode is consistently and reproducibly porous as deposited and has an appear ent surface area as deposited at least four times its geometric surface area.
3. A method according to claim 2, of sputtering a platinum exhaust gas electrode on to a vitrified zirconia thimble for an electrochemical-type exhaust gas oxygen sensor, in which the thimble is 3-5 cm long, the generally planar platinum target is oriented normal to the thimble and is spaced 3.5-4.0 cm from a closed end on the thimble, and the platinum as DC magnetron sputtered for a duration sufficient to produce an electrode thickness of more than 0.65 micrometer on said end and 0.3-0.5 micrometer on thimble side walls, the platinum electrode deposited having an apparent surface area as deposited at least four times its geometric surface area.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3077579A | 1979-04-17 | 1979-04-17 | |
US06/089,264 US4244798A (en) | 1979-10-29 | 1979-10-29 | Exhaust electrode process for exhaust gas oxygen sensor |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2046798A true GB2046798A (en) | 1980-11-19 |
GB2046798B GB2046798B (en) | 1983-03-30 |
Family
ID=26706455
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8011187A Expired GB2046798B (en) | 1979-04-17 | 1980-04-02 | Sputtered platinum on zirconia exhaust gas oxygen sensor |
Country Status (5)
Country | Link |
---|---|
CA (1) | CA1124678A (en) |
DE (1) | DE3014870A1 (en) |
FR (1) | FR2454622A1 (en) |
GB (1) | GB2046798B (en) |
IT (1) | IT1145366B (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3978006A (en) * | 1972-02-10 | 1976-08-31 | Robert Bosch G.M.B.H. | Methods for producing oxygen-sensing element, particularly for use with internal combustion engine exhaust emission analysis |
US3844920A (en) * | 1973-11-21 | 1974-10-29 | Gen Motors Corp | Air fuel ratio sensor |
US4040929A (en) * | 1975-09-15 | 1977-08-09 | Universal Oil Products Company | Oxygen sensor having thin film electrolyte |
US4136000A (en) * | 1978-03-13 | 1979-01-23 | Bendix Autolite Corporation | Process for producing improved solid electrolyte oxygen gas sensors |
-
1980
- 1980-01-24 CA CA344,294A patent/CA1124678A/en not_active Expired
- 1980-04-02 GB GB8011187A patent/GB2046798B/en not_active Expired
- 1980-04-15 IT IT48417/80A patent/IT1145366B/en active
- 1980-04-17 DE DE19803014870 patent/DE3014870A1/en active Granted
- 1980-04-17 FR FR8008599A patent/FR2454622A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2454622B1 (en) | 1982-07-30 |
FR2454622A1 (en) | 1980-11-14 |
DE3014870A1 (en) | 1980-11-06 |
CA1124678A (en) | 1982-06-01 |
IT8048417A0 (en) | 1980-04-15 |
DE3014870C2 (en) | 1990-03-22 |
GB2046798B (en) | 1983-03-30 |
IT1145366B (en) | 1986-11-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19950402 |