GB200834A - Improvements in and relating to a process of preparing cellulose derivatives - Google Patents

Improvements in and relating to a process of preparing cellulose derivatives

Info

Publication number
GB200834A
GB200834A GB18187/23A GB1818723A GB200834A GB 200834 A GB200834 A GB 200834A GB 18187/23 A GB18187/23 A GB 18187/23A GB 1818723 A GB1818723 A GB 1818723A GB 200834 A GB200834 A GB 200834A
Authority
GB
United Kingdom
Prior art keywords
water
etherification
alkali
soluble
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18187/23A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LYON LILIENFELD
Original Assignee
LYON LILIENFELD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LYON LILIENFELD filed Critical LYON LILIENFELD
Publication of GB200834A publication Critical patent/GB200834A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B11/00Preparation of cellulose ethers
    • C08B11/02Alkyl or cycloalkyl ethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

Cellulose ethers of a high degree of etherification are obtained by a multistage process with small amounts of alkalies and alkylating agents by the further alkylation or aralkylation of alkyl or aralkyl derivatives of cellulose prepared by treating cellulose or a conversion product or derivative thereof with alkylating or aralkylating agent in the presence of less than 2 mols (preferably less than 1.5 mols) of caustic alkali to 1 mol of C6H10O5, the water content being less than 0.5 part to 1 part of air-dried raw material, or the material being substantially free from water. When the quantity of water is not too small the product is at least partly soluble in aqueous alkalies, while if the water content is very small they are at least partly soluble in cold water and may be soluble in glacial or strong acetic acid, and also in hydrochloric acid. The product of the first stage of etherification is treated as it is for the next stage, or may be first isolated from the reaction mixture. By suitably choosing the conditions of the further etherification, products may be obtained which are soluble in or swell in very cold water which are advantageous when the product (say threads) is required to absorb water-soluble substance such as dyes. For this purpose the conditions are large quantity of water, small quantity of alkali and low reaction temperature. Or hard brittle ethers suitable for instance for lacquers and varnishes, may be obtained by using small quantities of water, large quantities of alkali and higher temperatures. Examples describe the production of the alkali cellulose containing the requisite proportions of alkali and water for the initial material the cellulose being mixed in a disintegrator edge runner machine &c. with the alkali solution or with solid and dissolved alkali or with solid alkali with or without water and excess being removed by for instance hydraulic presses, or the excess water may be removed to the necessary degree by drying. The alkyl or aralkyl esters of inorganic acids are preferably used for the etherification, such as ethyl or methyl chloride, ethyl bromide, dialkyl sulphates, benzyl chloride and ethyl iodide those agents with low boiling points requiring autoclaves while the others may be used in open vessels with or without reflux condensers. Examples describe the use of ethyl chloride. If it is desired to separate the product of the first etherification, the reaction mixture may be washed with hot water and dried, the ether being almost insoluble in hot water. Those of the intermediates (first products of etherification) which dissolve in alkalies may be converted into films or threads by treatment of the solution with acids or other precipitants known in the viscose art. The intermediates may be treated for further etherification in one or more stages so as to produce ethers of different degrees of etherification by using different quantities of alkalies and etherifying agents; products which dissolve or swell in cold water are obtained by using smaller quantities of these agents and products insoluble in and unaffected by water by using larger quantities. The ethers produced when ethyl chloride is used for the final etherification, are soluble in volatile solvents such as alcohol, benzol, alcohol-benzol mixtures, glacial acetic acid, chloroform, chloroform-alcohol mixture, and methyl-acetate-methyl-alcohol mixture and yield flexible films. The ether produced, in an example in which the final etherification is effected with di-ethyl sulphate is soluble in volatile solvents such as glacial acetic acid, benzol-alcohol mixture, chloroform-methyl-alcohol mixture, methyl-acetate-methyl-alcohol mixture. Specifications 177,089, 177,810, 200,816, 203,346, and 203,347 are referred to. The Specification, as open to inspection under Sect. 91 (3) (a) includes also the preparation of the intermediate products by treating a cellulose having a low water content or substantially free from water and a low alkali content with an etherifying-agent. This subject-mater does not appear in the Specification as accepted.
GB18187/23A 1922-07-13 1923-07-13 Improvements in and relating to a process of preparing cellulose derivatives Expired GB200834A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT200834X 1922-07-13

Publications (1)

Publication Number Publication Date
GB200834A true GB200834A (en) 1925-01-13

Family

ID=3669097

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18187/23A Expired GB200834A (en) 1922-07-13 1923-07-13 Improvements in and relating to a process of preparing cellulose derivatives

Country Status (1)

Country Link
GB (1) GB200834A (en)

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