GB2001647A - Process for the preparation of methacrylic acid and the esters and nitrile thereof - Google Patents
Process for the preparation of methacrylic acid and the esters and nitrile thereofInfo
- Publication number
- GB2001647A GB2001647A GB787831052A GB7831052A GB2001647A GB 2001647 A GB2001647 A GB 2001647A GB 787831052 A GB787831052 A GB 787831052A GB 7831052 A GB7831052 A GB 7831052A GB 2001647 A GB2001647 A GB 2001647A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nitrile
- esters
- preparation
- methacrylic acid
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000002148 esters Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000002825 nitriles Chemical class 0.000 title abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000009997 thermal pre-treatment Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Propionic acid (or the nitrile or an ester thereof) is reacted with methylal at an elevated temperature in the presence of a catalyst comprising zirconium dioxide. The process can be carried out for example at temperatures of at least 200 DEG C, particularly 200 to 350 DEG C. The catalyst may also contain aluminium oxide and/or silicon dioxide. The catalyst is preferably pre-treated with a phosphate and/or subjected to a thermal pre- treatment.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19772733496 DE2733496A1 (en) | 1977-07-25 | 1977-07-25 | PROCESS FOR THE PREPARATION OF METHACRYLIC ACID AND ESTERS AND THE NITRILE OF THIS ACID |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2001647A true GB2001647A (en) | 1979-02-07 |
| GB2001647B GB2001647B (en) | 1982-01-20 |
Family
ID=6014792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB787831052A Expired GB2001647B (en) | 1977-07-25 | 1978-07-25 | Process for the preparation of methacrylic acid and the esters and nitrile thereof |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5424817A (en) |
| DE (1) | DE2733496A1 (en) |
| FR (1) | FR2400499A2 (en) |
| GB (1) | GB2001647B (en) |
| IT (1) | IT7868764A0 (en) |
| NL (1) | NL7807885A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4444904A (en) * | 1983-05-26 | 1984-04-24 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition containing zirconium by an organic solution method |
| FR2938536A1 (en) * | 2008-11-18 | 2010-05-21 | Arkema France | PROCESS FOR THE PRODUCTION OF A METHYL METHACRYLATE DERIVED FROM BIOMASS |
| US8748545B2 (en) | 2008-09-16 | 2014-06-10 | Arkema France | Process for producing bio-resourced polymer-grade acrylic acid from glycerol |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4581471A (en) * | 1983-04-12 | 1986-04-08 | The British Petroleum Company P.L.C. | Process for the production of unsaturated carboxylic acids and/or esters |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2734074A (en) * | 1956-02-07 | Electric heater | ||
| US2821543A (en) * | 1955-01-10 | 1958-01-28 | Celanese Corp | Production of unsaturated aliphatic esters |
| US3014958A (en) * | 1960-01-15 | 1961-12-26 | Du Pont | Preparation of unsaturated esters |
| DE1793031A1 (en) * | 1968-07-25 | 1972-01-05 | Basf Ag | Process for the production of unsaturated monocarboxylic acids |
| US3933888A (en) * | 1972-10-06 | 1976-01-20 | Rohm And Haas Company | Production of unsaturated acids, esters and nitriles, and catalyst therefor |
| DE2457993C2 (en) * | 1974-12-07 | 1982-11-11 | Röhm GmbH, 6100 Darmstadt | Process for the production of methacrylic acid and esters and the nitrile of this acid |
| US4118588A (en) * | 1976-04-10 | 1978-10-03 | Basf Aktiengesellschaft | Manufacture of methacrylic acid and methyl methacrylate |
| FR2348906A1 (en) * | 1976-04-20 | 1977-11-18 | Roehm Gmbh | Methacrylic acid, ester or nitrile prepn. - from propionic acid, esters or nitrile by alumina-catalysed reaction with methylal |
-
1977
- 1977-07-25 DE DE19772733496 patent/DE2733496A1/en not_active Withdrawn
-
1978
- 1978-07-20 FR FR7821479A patent/FR2400499A2/en active Pending
- 1978-07-24 IT IT7868764A patent/IT7868764A0/en unknown
- 1978-07-25 NL NL7807885A patent/NL7807885A/en not_active Application Discontinuation
- 1978-07-25 JP JP9005678A patent/JPS5424817A/en active Pending
- 1978-07-25 GB GB787831052A patent/GB2001647B/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4444904A (en) * | 1983-05-26 | 1984-04-24 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition containing zirconium by an organic solution method |
| EP0126194A1 (en) * | 1983-05-26 | 1984-11-28 | Exxon Research And Engineering Company | Process for synthesizing a multicomponent acidic catalyst composition containing zirconium by an organic solution method |
| US8748545B2 (en) | 2008-09-16 | 2014-06-10 | Arkema France | Process for producing bio-resourced polymer-grade acrylic acid from glycerol |
| FR2938536A1 (en) * | 2008-11-18 | 2010-05-21 | Arkema France | PROCESS FOR THE PRODUCTION OF A METHYL METHACRYLATE DERIVED FROM BIOMASS |
| WO2010058119A1 (en) * | 2008-11-18 | 2010-05-27 | Arkema France | Method for manufacturing a biomass-derived methyl methlyacrylate |
Also Published As
| Publication number | Publication date |
|---|---|
| IT7868764A0 (en) | 1978-07-24 |
| FR2400499A2 (en) | 1979-03-16 |
| DE2733496A1 (en) | 1979-02-15 |
| GB2001647B (en) | 1982-01-20 |
| NL7807885A (en) | 1979-01-29 |
| JPS5424817A (en) | 1979-02-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |