GB191227955A - Improvements in, or connected with, the Manufacture of Hydrogen. - Google Patents
Improvements in, or connected with, the Manufacture of Hydrogen.Info
- Publication number
- GB191227955A GB191227955A GB191227955DA GB191227955A GB 191227955 A GB191227955 A GB 191227955A GB 191227955D A GB191227955D A GB 191227955DA GB 191227955 A GB191227955 A GB 191227955A
- Authority
- GB
- United Kingdom
- Prior art keywords
- heated
- dried
- heating
- nitrate
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
Abstract
27,955. Johnson, J. Y., [Badische Anilin & Soda Fabrik]. Dec. 4. Catalytic materials. - Catalytic masses, containing finely-divided iron oxide, for use in producing hydrogen from mixtures of carbon monoxide and steam are prepared (1) by starting with finely-divided iron which becomes more or less oxidized, giving rise, for example, to a mixture of oxides. Or a compound of iron which gives rise to iron oxide may be used. The substance used can be supported on carriers or used as a fine powder, or in a fine porous condition, but preferably is used in the form of porous lumps, briquettes, &c. An oxide, hydroxide, or a salt difficult of solution, e.g. iron carbonate, may be precipitated from a solution of an iron salt, or produced by heating, a suitable salt, such as iron oxalate or nitrate. The product is, if desired, after moistening and adding a suitable organic or inorganic diluent or binding-agent, formed into lumps, which are then heated, before or after introduction into the contact furnace. The porosity of the lumps may be increased by the addition, before heating, of substances which evolve gases on heating, and the decomposition of such substances can often be accelerated by passing gases such as air, carbon dioxide, furnace gas, or water-gas over the compounds during heating. The following examples of the production of the catalytic masses are given: (1) Solutions of sodium carbonate and ferrous sulphate are mixed, the precipitate is filtered off and mixed wet with slaked lime, or with an agent decomposable upon heating, such as calcium nitrate, or a mixture of that salt and ammonium nitrate; the mass is dried to a paste, kneaded, rolled out, and cut into cubes, which are dried and heated. (2) Finely-divided iron oxide, such as crocus martis, and a solution of aluminium or magnesium nitrate are somewhat similarly treated, the heating being effected in a current of air. (3) A mixture of caustic lime, water, and caustic potash is stirred into a melted ferric-nitrate crystals, and the product is mixed with the precipitate of the first example; the mixture is dried, kneaded, rolled, cut, dried again, and heated with or without passage of a current of air or carbon dioxide. (4) Ferric nitrate is heated and stirred until the nitric acid is almost completely driven off ; the residue is sieved and mixed with calcined magnesia and moistened with potassium carbonate solution. The mass is briquetted, dried, and heated. (5) Potassium carbonate and iron oxide, obtained by carefully heating the oxalate, are stirred into a stiff wheat-starch paste, and the mass is kneaded, briquetted, dried, and heated. Gum tragacanth, gum arabic, or dextrin, may be used instead of starch. (6) A paste of ferric-oxide hydrate, ferric oxalate, and calcium nitrate solution is pressed into suitable shapes and dried slowly at 500‹ C. in a current of air. The oxalate may be omitted. (7) Ferric oxide, obtained as in the fourth example, is mixed into a paste with aluminium nitrate solution. The paste is then suitably moulded and heated until the nitrous gases are driven off.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB191227955T | 1912-12-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB191227955A true GB191227955A (en) | 1913-11-13 |
Family
ID=32575535
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB191227955D Expired GB191227955A (en) | 1912-12-04 | 1912-12-04 | Improvements in, or connected with, the Manufacture of Hydrogen. |
GB191308864D Expired GB191308864A (en) | 1912-12-04 | 1913-04-15 | Improvements in or connected with Catalysts and in the Manufacture of Hydrogen. |
GB191416494D Expired GB191416494A (en) | 1912-12-04 | 1914-07-10 | Improvements in, or connected with, the Manufacture of Hydrogen. |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB191308864D Expired GB191308864A (en) | 1912-12-04 | 1913-04-15 | Improvements in or connected with Catalysts and in the Manufacture of Hydrogen. |
GB191416494D Expired GB191416494A (en) | 1912-12-04 | 1914-07-10 | Improvements in, or connected with, the Manufacture of Hydrogen. |
Country Status (1)
Country | Link |
---|---|
GB (3) | GB191227955A (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2181486B1 (en) * | 1972-04-26 | 1977-08-26 | Bastide Paul | |
FR3085284B1 (en) | 2018-09-04 | 2021-05-07 | Ifp Energies Now | PROCESS FOR PREPARING A CATALYST OR A COLLECTION MASS FROM MELTED SALTS |
FR3104463B1 (en) | 2019-12-17 | 2021-12-17 | Ifp Energies Now | HYDROGENOLYSIS CATALYST OBTAINED FROM MOLTEN SALTS AND AN ORGANIC ADDITIVE |
FR3104462B1 (en) | 2019-12-17 | 2022-06-10 | Ifp Energies Now | CATALYST FOR THE HYDROGENATION OF AROMATIC COMPOUNDS OBTAINED FROM MOLTEN SALTS AND AN ORGANIC ADDITIVE |
FR3104461B1 (en) | 2019-12-17 | 2022-06-17 | Ifp Energies Now | SELECTIVE HYDROGENATION CATALYST OBTAINED FROM MOLTEN SALTS AND AN ORGANIC ADDITIVE |
FR3112088B1 (en) | 2020-07-03 | 2022-09-30 | Ifp Energies Now | METHOD FOR PREPARING A CATALYST FOR SELECTIVE HYDROGENATION OBTAINED FROM MOLTEN SALTS AND A NICKEL-COPPER ALLOY |
FR3112087B1 (en) | 2020-07-03 | 2022-09-30 | Ifp Energies Now | METHOD FOR PREPARING A CATALYST FOR THE HYDROGENATION OF AROMATIC COMPOUNDS OBTAINED FROM MOLTEN SALTS AND A NICKEL-COPPER ALLOY |
FR3125438A1 (en) | 2021-07-22 | 2023-01-27 | IFP Energies Nouvelles | METHOD FOR PREPARING A CATALYST FROM MOLTEN SALTS AND A PARTICULAR SUPPORT |
-
1912
- 1912-12-04 GB GB191227955D patent/GB191227955A/en not_active Expired
-
1913
- 1913-04-15 GB GB191308864D patent/GB191308864A/en not_active Expired
-
1914
- 1914-07-10 GB GB191416494D patent/GB191416494A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB191308864A (en) | 1914-04-15 |
GB191416494A (en) | 1915-06-03 |
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