GB191111709A - Manufacture of Asymmetrical Aromatic Arseno-compounds. - Google Patents
Manufacture of Asymmetrical Aromatic Arseno-compounds.Info
- Publication number
- GB191111709A GB191111709A GB191111709DA GB191111709A GB 191111709 A GB191111709 A GB 191111709A GB 191111709D A GB191111709D A GB 191111709DA GB 191111709 A GB191111709 A GB 191111709A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- oxybenzene
- amino
- arseno
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000003118 aryl group Chemical group 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- BUSBFZWLPXDYIC-UHFFFAOYSA-N arsonic acid Chemical class O[AsH](O)=O BUSBFZWLPXDYIC-UHFFFAOYSA-N 0.000 abstract 2
- JRIGVWDKYXCHMG-UHFFFAOYSA-N (5-arsoroso-2-hydroxyphenyl)azanium;chloride Chemical compound Cl.NC1=CC([As]=O)=CC=C1O JRIGVWDKYXCHMG-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- GPSSQIRGCXEBSH-UHFFFAOYSA-N oxoarsenic Chemical class [As]=O GPSSQIRGCXEBSH-UHFFFAOYSA-N 0.000 abstract 1
- 229950008475 oxophenarsine Drugs 0.000 abstract 1
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 1
- 239000004291 sulphur dioxide Substances 0.000 abstract 1
- 230000001225 therapeutic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/66—Arsenic compounds
- C07F9/70—Organo-arsenic compounds
- C07F9/74—Aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Steroid Compounds (AREA)
Abstract
11,709. Imray, 0., [Farbwerke vorm. Meister, Lucius, & Br³ning]. May 15. Asymmetrical arseno compounds of the general formula R1-As=As-R2, where R1 and R2 represent different aromatic residues, are produced by reduction of a mixture in equimolecular proportions of two different arsonic acids or arsenoxides, or of an arsonic acid with an arsenoxide not derived therefrom. In examples are prepared 4-aminobenzenearseno-3-amino-4-oxybenzene, phenylglycinearseno-3-amino-4-oxybenzene, and 3:5-dichlor-4-oxybenzenearseno-3- amino-4-oxybenzene. The products have therapeutic properties. Phenylglycinearsinedichloride hydrochloride is prepared by the action of sulphur dioxide upon a hydrochloric acid solution of phenylglycinearsonic acid in presence of a little hydriodic acid. 3:5-Dichlor-4-oxybenzenearsenoxide is obtained by the reduction of the corresponding dichlorphenolarsonic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB191111709T | 1911-05-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB191111709A true GB191111709A (en) | 1912-02-01 |
Family
ID=32499505
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB191111709D Expired GB191111709A (en) | 1911-05-15 | 1911-05-15 | Manufacture of Asymmetrical Aromatic Arseno-compounds. |
| GB191314409D Expired GB191314409A (en) | 1911-05-15 | 1913-06-21 | Manufacture of Asymmetrical Arseno-compounds. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB191314409D Expired GB191314409A (en) | 1911-05-15 | 1913-06-21 | Manufacture of Asymmetrical Arseno-compounds. |
Country Status (1)
| Country | Link |
|---|---|
| GB (2) | GB191111709A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2695306A (en) * | 1932-05-06 | 1954-11-23 | George E Miller | Process of methylating sodium ortho arsenite |
-
1911
- 1911-05-15 GB GB191111709D patent/GB191111709A/en not_active Expired
-
1913
- 1913-06-21 GB GB191314409D patent/GB191314409A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB191314409A (en) | 1913-09-18 |
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