GB174306A - Improved manufacture of red oxide of iron - Google Patents
Improved manufacture of red oxide of ironInfo
- Publication number
- GB174306A GB174306A GB1581321A GB1581321A GB174306A GB 174306 A GB174306 A GB 174306A GB 1581321 A GB1581321 A GB 1581321A GB 1581321 A GB1581321 A GB 1581321A GB 174306 A GB174306 A GB 174306A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iron
- oxide
- witherite
- chloride
- ferrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 abstract 8
- 238000000034 method Methods 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 abstract 2
- 229910001626 barium chloride Inorganic materials 0.000 abstract 2
- 229960002089 ferrous chloride Drugs 0.000 abstract 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000004277 Ferrous carbonate Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 abstract 1
- 229960004652 ferrous carbonate Drugs 0.000 abstract 1
- 235000019268 ferrous carbonate Nutrition 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 150000002506 iron compounds Chemical class 0.000 abstract 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 abstract 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 abstract 1
- 235000021110 pickles Nutrition 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 230000000717 retained effect Effects 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/06—Ferric oxide [Fe2O3]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Iron (AREA)
Abstract
Red oxide of iron, in a form suitable for use as a pigment, is obtained by roasting in air a mixture of ferrous chloride with excess of barium carbonate. A solution of ferrous chloride, for example galvanizer's waste pickle, neutralized, is mixed with witherite, which is ground so that it passes through a 30-mesh sieve, but is retained by one of 150-mesh. The witherite is present in an excess of from 50 to 100 per cent over the theoretical quantity. The solution is evaporated to dryness, and the product roasted at 300 DEG C. until the reaction is complete. The mass is treated with water, which dissolves the barium chloride, and forms a suspension of iron oxide, from which the unchanged witherite quickly settles. The oxide is filtered, washed, and dried, and barium chloride obtained from the filtrate by evaporation. The process may be modified by adding to the original mixture a finely-divided iron compound, which is decomposed under the conditions of the process. Hydrated ferric oxide, ferrous carbonate, and iron pyrites are suitable compounds. Two examples of the working of the process are given.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1581321A GB174306A (en) | 1921-06-08 | 1921-06-08 | Improved manufacture of red oxide of iron |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1581321A GB174306A (en) | 1921-06-08 | 1921-06-08 | Improved manufacture of red oxide of iron |
Publications (1)
Publication Number | Publication Date |
---|---|
GB174306A true GB174306A (en) | 1922-01-09 |
Family
ID=10065943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1581321A Expired GB174306A (en) | 1921-06-08 | 1921-06-08 | Improved manufacture of red oxide of iron |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB174306A (en) |
-
1921
- 1921-06-08 GB GB1581321A patent/GB174306A/en not_active Expired
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